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Quantification of hardwood black liquor contamination in pine black liquor, TAPPI Journal February 2024
ABSTRACT: The presence of hardwood black liquor contamination in pine black liquor can negatively impact brownstock washer and evaporator operation, as well as reduce soap separation and yield. It is also believed to negatively impact commercial kraft lignin production. It was desired to develop a method of quantitatively determining the amount of low-level hardwood liquor contamination in pine black liquor. A method employing pyrolysis-gas chromatography mass spectrometry (py-GCMS) was developed to perform the desired measurement. Laboratory cooks with carefully controlled blends of pine and hardwood chips were prepared, and the resulting liquor was measured using this technique. Additionally, samples of pine and hardwood black liquors were blended in known quantities and analyzed. All these samples were submitted as blind samples. The resulting analysis suggests the py-GCMS method was able to accurately determine the level of hardwood contamination between 1% to 10% hardwood liquor using a low-level calibration curve prepared with coniferyl alcohol and sinapyl alcohol as standards.
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Alkyl ketene dimer (AKD) sized paper reversion due to oxidative photodegradation, TAPPI Journal January 2024
ABSTRACT: Alkyl ketene dimer (AKD) is a sizing agent used in papermaking to increase the resistance of paper-board towards water penetration. The acquired hydrophobic property of the paper can be reversed due to the instability of the sizing agent. It is broadly known that AKD size reversion is due to migration, poor orientation, masking, or hydrolysis of the sizing agent. Unfortunately, the environmental parameters that cause this chemical instability are not well understood. Thus, the conditions that initiate or catalyze AKD size reversion and the mechanisms of AKD size reversion under different environmental conditions need to be investigated. In this study, six different experimental setups were used to investigate how temperature, daylight, fluorescent light, oxygen, and ultraviolet (UV) light affect AKD size reversion. Cobb values and pyrolysis gas chromatography-mass spectrometry (py-GCMS) results show that AKD size reversion is due to the degradation of the chemical in the presence of light and oxygen; temperature variations were found to accelerate reversion in the presence of light and oxygen. The oxidative photodegradation mechanism of the sizing agent is explored, and a possible mechanism is proposed.
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Comparing a linear transfer function-noise model and a neural network to model boiler bank fouling in a kraft recovery boiler, TAPPI Journal, July 2024
ABSTRACT: Boiler bank fouling reduces heat transfer efficiency in kraft recovery boilers. Here, we model the relationships between boiler parameters and boiler bank pressure drop, an indicator of fouling, based on recovery boiler operating data. We compared two models: an autoregressive integrated exogenous (ARIX) model and a feedforward neural network. The ARIX model better simulates boiler bank pressure drop compared to the neural network (R2 of 0.64 vs. 0.58). Based on the ARIX model, we identified six boiler parameters that significantly influence boiler bank fouling and their relative contributions. Finally, we demonstrate how the models can simulate boiler bank pressure drop given artificial perturbations in boiler parameters.
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Editorial: Special issues in March and May TAPPI Journal focus on the latest pulp manufacture and engineering research, TAPPI Journal March 2024
ABSTRACT: This issue, organized by Editor-in-Chief Peter Hart, features content from the 2023 PEERS/IBBC Conference that has been peer reviewed for publication in TAPPI Journal. The papers encompass a range of topics:œ Two papers, from researchers Suarez et al. at WestRock, examine pulp from nonwoods like wheat straw and sugar-cane bagasse using a holistic life cycle analysis approach to project environmental performance in packaging products. The results can help mills make decisions about which fibers ensure a low carbon footprint.
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Improvements in oil and grease resistance (OGR) test methodology for waterborne barrier coatings, TAPPI Journal November 2022
ABSTRACT: Paper-based food packaging is becoming more popular due to consumer demands for sustainable packaging options. Waterborne paper coatings that provide performance properties (i.e., resistance to oil and grease) not inherent to paper and board substrates offer improved sustainability profiles over earlier paper treatment options, including fluorocarbon treatment and coating with extruded plastics. The continued development of new paper coating technologies requires re-evaluation of current test methods and development of new methods to ensure lab evaluations can serve as accurate predictors of real-world performance. This paper provides an overview of commonly used oil and grease resistance (OGR) test methods within the paper coatings industry, and then describes improvements and developments made to two key methods: the 3M Kit test and an internally developed oil breakthrough test. The combined use of these adapted methods provides a more efficient testing workflow and a more complete understanding of the OGR performance of barrier coatings.
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Three-dimensional pore structure visualization and character
Three-dimensional pore structure visualization and characterization of paper using X-ray computed tomography, TAPPI JOURNAL September 2017
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Effect of surface treatment with biodegradable materials on
Effect of surface treatment with biodegradable materials on properties of linerboard made from old corrugated containers (OCC), TAPPI Journal September 2017
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Modeling the influence of forming fabric structure on vacuum
Modeling the influence of forming fabric structure on vacuum box dewatering, TAPPI JOURNAL August 2017
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Paper coated with sonochemically synthesized zinc oxide nanoparticles: Enhancement of properties for preservation of documents, TAPPI JOURNAL January 2017
Paper coated with sonochemically synthesized zinc oxide nanoparticles: Enhancement of properties for preservation of documents, TAPPI JOURNAL January 2017
Journal articles
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An easy and reliable method for syringyl:guaiacyl ratio mea
An easy and reliable method for syringyl:guaiacyl ratio measurement, TAPPI JOURNAL March 2017