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Journal articles
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Paper Machine Water Efficiency, Paper360º July/August 2020

Paper Machine Water Efficiency, Paper360º July/August 2020

Journal articles
Magazine articles
Open Access
Numerical analysis of slot die coating of nanocellulosic materials, TAPPI Journal November 2020

ABSTRACT: Nanocellulosic coatings as a food packaging material are of commercial interest due to their nontoxic nature, renewability, and excellent barrier properties. Complex shear-thinning rheology poses challenges in designing and sizing equipment to pump, mix, and process the suspension and actual coating process. This study aims to determine the effectiveness of computational fluid dynamics (CFD) in predicting nanocellulosic suspension flow in light of existing rheological data. We employ and compare three distinct rheological models to characterize the rheology and flow of nanocellulose suspensions through a slot die coater, where the model parame-ters are established from existing slot rheometry measurements. A volume-of-fluid (VoF) based finite volume meth-od is employed to simulate the flow in a slot die operated in an unconventional metering mode. Results with the Casson model predict the presence of unyielded regions in the flow, which was not captured using the power law model. These stagnation regions will incur coatability issues stemming from flow intermittencies and lead to poten-tial defects in the coating layer, including fracture. The results suggest that a rheological model that includes yield stress should be considered while modeling such flows. A need for better rheological data to model nanocellulosic flows, especially at high consistencies and shear rates, is also highlighted.

Journal articles
Magazine articles
Open Access
Critical parameters for tall oil separation I: The importance of ration of fatty acids to rosin acids, TAPPI Journal September 2019

ABSTRACT: Tall oil is a valuable byproduct in chemical pulping of wood, and its fractions have a large spectrum of applications as chemical precursors, detergents, and fuel. High recovery of tall oil is important for the economic and environmental profile of chemical pulp mills. The purpose of this study was to investigate critical parameters of tall oil separation from black liquor. To investigate this in a controlled way, we developed a model test system using a “synthetic” black liquor (active cooking chemicals OH- and HS- ions), a complete process for soap skimming, and determination of recovered tall oil based on solvent extraction and colorimetric analysis, with good reproducibility. We used the developed system to study the effect of the ratio of fatty acids to rosin acids on tall oil separation. When high amounts of rosin acids were present, tall oil recovery was low, while high content of fatty acids above 60% significantly promoted tall oil separation. Therefore, manipulating the content of fatty acids in black liquor before the soap skimming step can significantly affect the tall oil solubility, and hence its separation. The findings open up chemical ways to improve the tall oil yield.

Journal articles
Magazine articles
Open Access
A new technique for the measurement of show-through mottle of fine paper, TAPPI Journal September 2019

ABSTRACT: Mottling within print-through and show-through is caused by the variability of the local optical properties of the sheet. This mottling is visually disturbing and a mark of poor paper quality. The ability to predict print-through mottle of printed paper by measuring show-through mottle on the unprinted sheet would be a valuable asset for paper machine control.We examined the relationship between print-through mottle and show-through mottle. We worked with nine samples of 60 lb. uncoated fine paper (90 g/m2), from various North American paper companies, that were printed on an offset press, 400K (400% Black), on both sides. A show-through mottle instrumental determination technique was developed using an existing Fast Fourier Transform-based algorithm. The nine samples examined were ranked similarly by the visual evaluation of print-through mottle and by the instrumental determination of show-through mottle. We thus established that show-through on the unprinted sheet can be used as a reliable predictor of print-through, therefore saving time and money for papermakers. We also found a significant two-sidedness in show-through for some of the samples.

Journal articles
Magazine articles
Open Access
Three-dimensional pore structure visualization and character

Three-dimensional pore structure visualization and characterization of paper using X-ray computed tomography, TAPPI JOURNAL September 2017

Journal articles
Magazine articles
Recycling at Paper Mills: The Benefits of Water-Based Barrier Coatings, Paper360º January/February 2021

Recycling at Paper Mills: The Benefits of Water-Based Barrier Coatings, Paper360º January/February 2021

Journal articles
Magazine articles
World BioEconomy Forum: Major Opportunities for the Pulp and Paper Industries, Paper360º March/April 2019

World BioEconomy Forum: Major Opportunities for the Pulp and Paper Industries, Paper360º March/April 2019

Journal articles
Magazine articles
Open Access
On increasing wet-web strength with adhesive polymers, TAPPI JOURNAL February 2020

ABSTRACT: Fiber-fiber adhesion, called “bonding” in the old paper physics literature, is a critical component of the overall strength of dry paper. With freshly formed very wet pulp fiber webs, all evidence suggests there are no fiber-fiber crossings with significant adhesive joint strength. With water removal, a point will be reached where fiber-fiber adhesion starts to contribute to the overall wet-web strength.The literature reveals very few examples of polymers that increase fiber-fiber joint strength in freshly formed webs. Here, we summarize the literature and explain why it is so difficult to promote fiber-fiber wet adhesion with polymers. Nevertheless, ongoing research in areas as diverse as tissue engineering scaffolds and biomimetic adhesives gives clues to future developments. Advances in paper machine engineering have lessened the importance of wet-web strength. By contrast, a critical issue in many of the evolving nanocellulose technologies is the strength of objects first formed by aqueous processing, the green strength—the strength of wet bodies before drying. For exam-ple, 3-D printed nanocellulose objects and ultralow density cellulosic aerogels can be destroyed by capillary forces during drying. There is a need for adhesives that strengthen freshly formed, wet lignocellulosic joints.

Journal articles
Magazine articles
RISI’s European CEO of the Year: Ksenia Sosnina, Ilim Group, Paper360º March/April 2020

RISI’s European CEO of the Year: Ksenia Sosnina, Ilim Group, Paper360º March/April 2020

Journal articles
Magazine articles
Open Access
Evaluation of folding effects on coating damage, TAPPI Journal November 2024

ABSTRACT: Barrier coatings on paperboard need to maintain integrity during converting and end-use for effective barrier performance. Folding is one of the most common deformations during converting; however, factors that affect damage during folding are not well defined. This is partly because methods to fold specimens and characterize damage are not standardized and the results are generally not transferable. In this work, we describe a method to fold paper specimens precisely and reproducibly. The keys to folding include using a defined geometry and controlled deformation. Multiple methods can be used to quantify damage; in this case, we use differences in permeability as a measure of how the coating becomes more open. Damage is sensitive to the degree of compression after the initial folding. Using a shim for support provides a defined amount of compression and minimizes the sensitivity to the applied pressure.