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Magazine articles
Flow rheology of light foams generated from aqueous solutions of polyvinyl alcohol, TAPPI Journal January 2023
ABSTRACT: Recent studies have shown that foam-assisted application of additives into a wet web has advantages over the conventional way of adding the chemicals into the pulp suspension before forming, e.g., increased mechanical retention as well as high dosage giving increased wet strength without impairing the sheet uniformity. To engineer processes utilizing this new technology, the complex flow behavior of applied foams must be quantified. At the minimum, the foam viscosity and the slip velocity at the solid surfaces need to be known to build practical models that can be used in analyzing and upscaling unit processes of the foam-assisted application.In this study, the rheological behavior was quantified for foams having polyvinyl alcohol (PVOH), a widely used strength additive chemical, as the surfactant. The foam density was varied between 100 g/L and 300 g/L, and the concentration of the PVOH solution was varied between 0.5% and 6.0% (w/w). The foams were generated with a commercial foam generator, and the rheological properties of the foams were measured by using a horizontal pipe bank. At the outlet from the generator, the volumetric flow rate, the absolute pressure, and the bubble size distribution of the foam were measured. In the measurement pipe section, the viscous pressure gradient and the slip velocity were measured, after which the foam was discharged to ambient air pressure. The viscosity and the dynamic surface tension of the PVOH solutions were quantified with commercial laboratory devices. In the viscosity analysis, the apparent shear rate was calculated from the volumetric flow rate, and the resulting apparent viscosity was translated to real material viscosity data by applying the Weissenberg-Rabinowitsch correction. The results indicated that PVOH foams can be described with high accuracy as shear-thinning power-law fluids where the detailed behavior depends on the foam density and the PVOH concentration. Slip flow, as usual, increased with increasing wall shear stress, but it was also dependent on the PVOH concentration, the air content, and the bubble size. For both the foam viscosity and the slip flow, a correlation was found that described the quantitative behavior of all the studied foams with good accuracy.
Magazine articles
Forklift emissions - some solutions, TAPPI JOURNAL, December 1993, Vol. 76(12)
Forklift emissions - some solutions, TAPPI JOURNAL, December 1993, Vol. 76(12)
Magazine articles
Corrosion in lower furnace of kraft recovery boilersâ??in-situ characterization of corrosive environments, Solutions! & TAPPI JOURNAL, February 2004, Vol. 3(2) (179KB)
Corrosion in lower furnace of kraft recovery boilers–in-situ characterization of corrosive environments, Solutions! & TAPPI JOURNAL, February 2004, Vol. 3(2) (179KB)
Magazine articles
Treatment efficiency of eucalypt kraft pulp bleaching effluents: influence of dissolved organic matter, SOLUTIONS! & TAPPI JOURNAL, April 2002 (128KB)
Treatment efficiency of eucalypt kraft pulp bleaching effluents: influence of dissolved organic matter, SOLUTIONS! & TAPPI JOURNAL, April 2002 (128KB)
Journal articles
Magazine articles
SCC susceptibility of chromized type 409 stainless steel in alkaline chloride solutions at ambient temperature and pressure, TAPPI Journal August 2023
ABSTRACT: Biomass hydrothermal liquefaction (HTL) is operated in a harsh reaction medium that contains hot pressurized water, inorganic acidic or basic catalyst, and inorganic/organic corrosive components released during the conversion. Candidate alloys for this application require suitable resistance to both corrosion and stress corrosion cracking (SCC) to withstand the HTL process conditions (250°C•374°C and 4•22 MPa). Ferritic iron-chromium (Fe-Cr) steels are more prone to corrosion but less susceptible to SCC compared to austenitic iron-chromium-nickel (Fe-Cr-Ni) steels. Chromizing can significantly reduce corrosion of Type 409 stainless steel (Fe-11Cr) in a simulated aqueous HTL solution. The objective of this study is to determine the SCC susceptibility of chromized Type 409 stainless steel, relative to the bare (non-chromized) case. The slow strain rate testing (SSRT) technique was used for this purpose. For simplicity of experimentation, SSRT was conducted using simulated HTL water containing 800 ppm potassium chloride (KCl), 1 M potassium carbonate (K2CO3), and 10 wt% acetic acid at ambient temperature and pressure. Complementary potentiodynamic polarization measurements and surface analysis by X-ray photoelectron spectros-copy (XPS) were also made to help interpret the SSRT results. The SSRT results show no significant difference in SCC susceptibility, regardless of the starting surface. Thus, chromizing, while significantly reducing the corrosion of Type 409 stainless steel, does not adversely affect SCC susceptibility, at least under the conditions tested.
Magazine articles
Corrosion of titanium in alkaline hydrogen peroxide bleaching solution, TAPPI JOURNAL, June 1995, Vol. 78(6)
Corrosion of titanium in alkaline hydrogen peroxide bleaching solution, TAPPI JOURNAL, June 1995, Vol. 78(6)
Journal articles
Magazine articles
Graft copolymerization of acrylic acid of kraft lignin to enhance aniline adsoprtion from aqueous solution, TAPPI JOURNAL January 2019
Graft copolymerization of acrylic acid of kraft lignin to enhance aniline adsoprtion from aqueous solution, TAPPI JOURNAL January 2019
Journal articles
Magazine articles
Deinking process water flotation
Deinking process water flotation: An innovative solution to improve deinking and papermaking processes efficiency, TAPPI JOURNAL November 2017
Journal articles
Magazine articles
Lignocellulose fibers elaborating super-swollen three-dimensional cellulose hydrogels from solution in N, N-dimethylacetamide/lithium chloride, TAPPI JOURNAL February 2018
Lignocellulose fibers elaborating super-swollen three-dimensional cellulose hydrogels from solution in N, N-dimethylacetamide/lithium chloride, TAPPI JOURNAL February 2018
Journal articles
Magazine articles
On the usage of online fiber measurements for predicting bleached eucalyptus kraft pulp tensile index — an industrial case, TAPPI Journal July 2022
ABSTRACT: Cellulose pulp’s physical-mechanical properties are determined by laboratory tests obtained from prepared handsheets. However, this procedure is time intensive and presents a lead time until the results are available, hindering its utilization for monitoring and decision-making in a pulp mill. In this context, developing real-time solutions for physical-mechanical properties prediction is fundamental. This work applied a mathematical modeling approach to develop a soft sensor for tensile index monitoring. The mathematical model considers online morphology measurements obtained from the last bleaching stage outlet stream and important process variables for tensile index prediction. The results obtained are satisfactory compared to laboratory results, presenting a mean absolute percentual error of 2.5%, which agrees with the laboratory testing method’s reproducibility.