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A new method of studying the fundamental mechanisms involved in pigment liberation from recycle papers, TAPPI Journal October 2022
ABSTRACT: Deinking flotation is the most efficient and widely used method of removing ink particles from printed papers to improve the recyclability. A prerequisite for successful deinking flotation is detachment of pigments from paper fibers, a subprocess known as liberation. The degree of liberation is usually determined via hyperwashing tests, which are costly and time consuming. Furthermore, they provide no information on the fundamental mechanisms controlling liberation. In the present work, we developed a new method in which ?-potentials of the particles in a pulp are measured and analyzed. If pigments are not liberated from paper fibers, a frequency distribution plot gives a single peak, while two peaks appear when they are liberated. One can readily determine the degrees of liberation from the peak positions and peak heights. In addition, the ?-potential data can be used to construct disjoining pressure isotherms using the DLVO theory that are useful to better understand the fundamental mechanisms involved and the roles of different reagents used to improve pigment liberation.
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Effects of orders of addition in nanocellulose•cationic starch• colloidal silica systems for papermaking, TAPPI Journal October 2022
ABSTRACT: Two orders of addition were compared when preparing paper handsheets from recycled copy paper furnish in combination with nanofibrillated cellulose (NFC), cationic starch, colloidal silica, and cationic retention aid (cPAM; cationic polyacrylamide). Faster dewatering and higher fine-particle retention were obtained at equal optimized dosages of additives when the colloidal silica was added last, after addition of the cPAM. The same order of addition also provided a higher gain in the paper’s tensile strength. However, higher paper stiffness was achieved when the colloidal silica was instead added to the NFC, after its pretreatment with cationic starch. Results were consistent with the principle that papermaking additives added shortly before sheetforming tend to have the largest effects on drainage and retention. The results also demonstrated a sensitivity to the relative dosages of positively and negatively charged additives.
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Does the kappa number method accurately reflect lignin content in nonwood pulps?, TAPPI Journal November 2018
Does the kappa number method accurately reflect lignin content in nonwood pulps?, TAPPI Journal November 2018
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Partnerships for Technology Challenges, 2018 PEERS
Partnerships for Technology Challenges, 2018 PEERS
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Editorial: TAPPI Journal Best Research Paper for 2023 focuses on black liquor concentration using graphene oxide membranes, TAPPI Journal February 2024
ABSTRACT: TAPPI and the TAPPI Journal (TJ) Editorial Board would like congratulate the authors of the 2023 TAPPI Journal Best Research Paper Award and Honghi Tran Prize: Sam Rae, Ella V. Richards, Max Kleiman-Lynch, Brent D. Keller, and Brandon I. Macdonald. Their paper, “Pilot scale black liquor concentration using pressure driven membrane separation,” appeared on p. 223 of the April 2023 issue. This kraft recovery cycle research was recognized by the TAPPI Journal Editorial Board for its innovation, creativity, scientific merit, and clear expression of ideas.
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Quantification of hardwood black liquor contamination in pine black liquor, TAPPI Journal February 2024
ABSTRACT: The presence of hardwood black liquor contamination in pine black liquor can negatively impact brownstock washer and evaporator operation, as well as reduce soap separation and yield. It is also believed to negatively impact commercial kraft lignin production. It was desired to develop a method of quantitatively determining the amount of low-level hardwood liquor contamination in pine black liquor. A method employing pyrolysis-gas chromatography mass spectrometry (py-GCMS) was developed to perform the desired measurement. Laboratory cooks with carefully controlled blends of pine and hardwood chips were prepared, and the resulting liquor was measured using this technique. Additionally, samples of pine and hardwood black liquors were blended in known quantities and analyzed. All these samples were submitted as blind samples. The resulting analysis suggests the py-GCMS method was able to accurately determine the level of hardwood contamination between 1% to 10% hardwood liquor using a low-level calibration curve prepared with coniferyl alcohol and sinapyl alcohol as standards.
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Effects of varying total titratable alkali and causticizing efficiency targets on kraft pulp mill productivity, TAPPI Journal March 2024
ABSTRACT: The kraft mill causticizing area is often overlooked and undervalued when it comes to mill optimization; however, the operation of the causticizing plant has downstream effects on the entire liquor cycle. Setting the right targets for the causticizing plant can have a tremendous effect on mill operating costs, as well as push the production bottleneck from one unit operation to another. The key performance parameters associated with the causticizing plant itself are liquor total titratable alkali (TTA) and causticizing efficiency. Individual facilities choose their TTA and causticizing efficiency targets based on their goals, the limits of their equipment, and past experiences. This gives a variety of operating strategies in practice, but what are the implications for optimizing total titratable alkali and causticizing efficiency, and what level of optimization can be achieved through implementation of modern technology? This paper reviews the results of several different operational strategies and models the effects of these different approaches on kraft mill liquor cycle.
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Combustion behavior of kraft black liquor droplets from hot
Combustion behavior of kraft black liquor droplets from hot water pretreated hardwood and softwood chips, November 2016 TAPPI JOURNAL
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Novel CaCO3-polymer nanocomposite fillers for the improvemen
Novel CaCO3-polymer nanocomposite fillers for the improvement of bagasse-based papers, November 2016 TAPPI JOURNAL
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The Paper360° TOP 75, Paper360º September/October 2019
The Paper360° TOP 75, Paper360º September/October 2019