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Understanding the risks and rewards of using 50% vs. 10% strength peroxide in pulp bleach plants, TAPPI Journal November 2018
Authors: Alan W. Rudie and Peter W. Hart | ABSTRACT: The use of 50% concentration and 10% concentration hydrogen peroxide were evaluated for chemical and mechanical pulp bleach plants at storage and at point of use. Several dangerous occurrences have been documented when the supply of 50% peroxide going into the pulping process was not stopped during a process failure. Startup conditions and leaking block valves during maintenance outages have also contributed to explosions. Although hazardous events have occurred, 50% peroxide can be stored safely with proper precautions and engineering controls. For point of use in a chemical bleach plant, it is recommended to dilute the peroxide to 10% prior to application, because risk does not outweigh the benefit. For point of use in a mechanical bleach plant, it is recommended to use 50% peroxide going into a bleach liquor mixing system that includes the other chemicals used to maintain the brightening reaction rate. When 50% peroxide is used, it is critical that proper engineering controls are used to mitigate any risks.
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Online measurement of bulk, tensile, brightness, and ovendry content of bleached chemithermomechanical pulp using visible and near infrared spectroscopy, TAPPI JOURNAL April 2018
Online measurement of bulk, tensile, brightness, and ovendry content of bleached chemithermomechanical pulp using visible and near infrared spectroscopy, TAPPI JOURNAL April 2018
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Quantification of block testing for coated paper substrates, TAPPI Journal November 2024
ABSTRACT: Block resistance is a critical property for coated paper and board substrate that will be rolled, stacked, or otherwise contact itself after coating. Small differences in the coated substrate’s blocking can determine whether the substrate can be successfully used for its designated purpose. However, this crucial property is typically evaluated using a qualitative scale that is based on subjective operator ratings and impacted by factors that include: (1) sound of coated substrate during separation, and (2) force with which substrates are separated. This paper tests the hypothesis that quantifying the block test by measuring the force required to peel samples apart improves the test by: (1) providing more standardized testing conditions by controlling peel force and rate; (2) more clearly differentiating samples that experience minimal to some blocking; and (3) maintaining customizability to evaluate customer-specific test conditions. The method developed in this study uses a standard block tester and block testing conditions, but it peels the coated paper samples using a hot tack/heat seal instrument with force measurement capabilities. This paper demonstrates, using the instrument’s heat seal capabilities, that it can measure peel forces that represent the full range of observable block scores. The efficacy of this method was evaluated by having a group of trained operators engage in a randomized, blind experiment where they assessed block resistance on a set of coated paper samples using a modified qualitative block scale and compared their results to force measurements collected using the proposed method. The sample set included two coatings that have successfully run in commercial trials with minimal blocking, and one coating that experienced significant blocking in commercial trials despite only exhibiting some blocking at standard block test conditions in laboratory testing. The quantitative test method presented in this paper clearly differentiated these samples, whereas the qualitative assessment could not predict which samples had suitable block resistance for commercial use. As any tensile tester capable of measuring with 0.1 N resolution can be used for the Quantitative Block Test, the proposed method can be widely adopted. Furthermore, this method can be used for any block condition.
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Rethinking the paper cup — beginning with extrusion process optimization for compostability and recyclability, TAPPI Journal June 2021
ABSTRACT: More than 50 billion disposable paper cups used for cold and hot beverages are sold within the United States each year. Most of the cups are coated with a thin layer of plastic — low density polyethylene (LDPE) — to prevent leaking and staining. While the paper in these cups is both recyclable and compostable, the LDPE coat-ing is neither. In recycling a paper cup, the paper is separated from the plastic lining. The paper is sent to be recycled and the plastic lining is typically sent to landfill. In an industrial composting environment, the paper and lining can be composted together if the lining is made from compostable materials. Coating paper cups with a compostable performance material uniquely allows for used cups to be processed by either recycling or composting, thus creating multiple pathways for these products to flow through a circular economy.A segment of the paper converting industry frequently uses an extrusion grade of polylactic acid (PLA) for zero-waste venues and for municipalities with ordinances for local composting and food service items. The results among these early adopters reveal process inefficiencies that elevate manufacturing costs while increasing scrap and generally lowering output when using PLA for extrusion coating. NatureWorks and Sung An Machinery (SAM) North America researched the extrusion coating process utilizing the incumbent polymer (LDPE) and PLA. The trademarked Ingeo 1102 is a new, compostable, and bio-based PLA grade that is specifically designed for the extrusion coating process. The research team identified the optimum process parameters for new, dedicated PLA extrusion coating lines. The team also identified changes to existing LDPE extrusion lines that processors can make today to improve output.The key finding is that LDPE and PLA are significantly different polymers and that processing them on the same equipment without modification of systems and/or setpoints can be the root cause of inefficiencies. These polymers each have unique processing requirements with inverse responses. Fine tuning existing systems may improve over-all output for the biopolymer without capital investment, and this study showed an increase in line speed of 130% by making these adjustments. However, the researchers found that highest productivity can be achieved by specifying new systems for PLA. A line speed increase to more than 180% and a reduction in coat weight to 8.6 µm (10.6 g/m2 or 6.5 lb/3000 ft2) was achieved in this study. These results show that Ingeo 1102 could be used as a paper coating beyond cups.
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Novel test method for measuring defects in barrier coatings, TAPPI Journal November 2022
ABSTRACT: In the last several years, activity to develop water-based barrier coatings (WBBCs) that meet challenging packaging performance requirements has increased dramatically. Cellulose-based packaging solutions can provide a more sustainable packaging option for replacing single-use plastic-based options like extrusion-based and laminated materials. An advantage of WBBCs is the opportunity to reduce the coating thickness applied, as long as the barrier requirements can be met. A challenge that must be overcome is the ability to maintain a defect and pin-hole-free coating layer after coating and drying to retain the barrier performance. Many formulation and coating parameters can affect the barrier coating layer quality; however, methods for detecting more subtle differences in these types of studies are not widely available. Work was carried out to develop a quantitative technique for detecting and measuring the quantity and size of defects in the barrier coating layer. A test method has been developed using a combination of dyed oil and image analysis to be able to characterize the imperfections in the coating surface. The use of dyed oil serves two purposes. First, it better simulates the types of materials, in this case, oils and grease, for which the barrier coating is expected to hold out. Second, it also provides contrast between the coating and failure points for testing. An image analysis technique is employed to characterize the number and size of the imperfections. For the former, it reduces the testing time required if a quality control or laboratory technician counts the dots. For the latter, it assists with judgment on the source of the root cause of the imperfection, such as base sheet defects, coating dispersion issues, or perhaps micro-blisters in the coating, as some examples.To show the benefit of this technique, several pilot coating studies were designed to see if the new technique could be utilized to detect differences in WBBC performance. Both process and chemical variables were evaluated. With refinement, it is believed this technique can be utilized in development work, as well as for a potential quality control technique for manufacturing of coated paper and paperboard products.
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Production and characterization of furanic bio-oil from Kawayan kiling (Bambusa vulgaris Schrad ex. Wendl) using molten citric acid in an open system, TAPPI Journal August 2024
ABSTRACT: The burning of fossil fuels poses many threats to the environment. These predicaments have led to a continuous search for alternative sources and production of energy, and biomass is considered the most abundant renewable energy source. In this study, the potential to produce furanic bio-oil from the cellulose of Bambusa vulgaris was explored. The proximate chemical analysis of bamboo was determined using TAPPI Standards. Cellulose was isolated through dewaxing, delignification, and alkaline treatments. The furanic bio-oil was produced by mixing cellulose and citric acid in a solvent-free environment. The effects of the digestion time (120 min, 180 min, and 240 min) on the yield and characteristics were determined. The chemical compositions were determined using Fourier transform infrared (FTIR) spectroscopy and gas chromatography-mass spectrometry (GCMS). B. vulgaris has the following chemical composition: alpha-cellulose (57.42 ± 0.40), holocellulose (78.84 ± 0.52), lig-nin (28.85 ± 0.17), hot water extractives (3.99 ± 0.08), organic extractives (0.77 ± 0.04), ash (4.67 ± 0.02), and moisture (12.98 ± 0.22). The bio-oil yield was affected by the digestion time. The highest yield was obtained at 180 min, followed by 120 min, and 240 min with 88.59%, 59.28%, and 49.96%, respectively. The peaks in the FTIR spectra corresponded to the compounds determined by the GCMS analysis. The dominant chemicals were furans (29.19%), ketones (26.31%), and carboxylic acids (19.26%). The bio-oil obtained at 180-min digestion time has the following properties: sulfur content (0.032 wt%), kinematic viscosity (1.03 mm2/s), specific gravity (0.925), copper corrosion test (No. 1a), pH (2.753), and water content (not detected). Overall, the obtained values from the properties and chemical characterization can be the basis for investigating its performance for biofuel production and utilization. This study is aligned with the Bamboo Industry’s Strategic Science and Technology Plan for the Philippines to develop other value-added products from bamboo and to achieve Sustainable Development Goal 7 (SDG 7) as determined by the United Nations.
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Preparing prehydrolyzed kraft dissolving pulp via phosphotungstic acid prehydrolysis from grape branches, TAPPI Journal January 2022
ABSTRACT: Dissolving pulp was successful prepared via phosphotungstic acid (PTA) prehydrolysis kraft (PHK) cooking followed by an elementary chlorine-free (ECF) bleaching process from grape branches. The effects of prehydrolysis temperature, reaction time, and PTA concentration that potentially affect the quality of dissolving pulp product on chemical components of pulp were studied via an orthogonal experiment. The structure of lignin was activated during the PTA prehydrolysis phase, and lignin was easily removed during the following cooking process. Thus, relatively mild conditions (140°C, 100 min) can be used in the cooking process. During the prehydrolysis phase, temperature exhibited the most significant influence on the cellulose purity of the obtained pulp fiber, followed by reaction time and PTA concentration. The optimized prehydrolysis conditions were as follows: prehydrolysis temperature, 145°C; reaction time, 75 min; and PTA concentration, 1 wt%. Whether the excessively high prehydrolysis temperature or prolonging the reaction time did not favor the retention of long chain cellulose, the delignification selectivity for the cooking process could not be further improved by excessive PTA loading. Under these prehydrolysis conditions, 94.1% and 29.0% for a-cellulose content and total yield could be achieved after the given cooking and bleaching conditions, respectively. Moreover, the chemical structure and crystal form of cellulose were scarcely changed after PTA prehydrolysis, which could be confirmed by results from Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). PTA prehydrolysis could be considered as an alternative method for preparing PHK dissolving pulp under relatively mild cooking conditions.
Journal articles
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Application of spruce wood flour as a cellulosic-based wood additive for recycled paper applications— A pilot paper machine study, TAPPI Journal October 2021
ABSTRACT: This study gives a first insight into the use of wood flour as a plant-based and cellulosic-based alter-native additive for newsprint and paperboard production using 100% recycled fibers as a raw material. The study compares four varieties of a spruce wood flour product serving as cellulosic-based additives at addition rates of 2%, 4%, and 6% during operation of a 12-in. laboratory pilot paper machine. Strength properties of the produced news-print and linerboard products were analyzed. Results suggested that spruce wood flour as a cellulosic-based additive represents a promising approach for improving physical properties of paper and linerboard products made from 100% recycled fiber content. This study shows that wood flour pretreated with a plant-based polysaccharide and untreated spruce wood flour product with a particle size range of 20 μm to 40 μm and 40 μm to 70 μm can increase the bulk and tensile properties in newsprint and linerboard applications.
Journal articles
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Corrosion damage and in-service inspection of retractable sootblower lances in recovery boilers, TAPPI Journal October 2021
ABSTRACT: Several reports of accidents involving serious mechanical failures of sootblower lances in chemical recovery boilers are known in the pulp and paper industry. These accidents mainly consisted of detachment and ejection of the lance tip, or even of the entire lance, to the inside of the furnace, towards the opposite wall. At least one of these cases known to the author resulted in a smelt-water explosion in the boiler.In other events, appreciable damage or near-miss conditions have already been experienced. The risk of catastrophic consequences of the eventual detachment of the lance tip or the complete lance of a recovery boiler soot-blower has caught the attention of manufacturers, who have adjusted their quality procedures, but this risk also needs to be carefully considered by the technical staff at pulp mills and in industry committees.This paper briefly describes the failure mechanisms that prevailed in past accidents, while recommending inspection and quality control policies to be applied in order to prevent further occurrences of these dangerous and costly component failures. Digital radiography, in conjunction with other well known inspection techniques, appears to be an effective means to ensure the integrity of sootblower lances in chemical recovery boilers used in the pulp and paper industry.
Journal articles
Magazine articles
Flow rheology of light foams generated from aqueous solutions of polyvinyl alcohol, TAPPI Journal January 2023
ABSTRACT: Recent studies have shown that foam-assisted application of additives into a wet web has advantages over the conventional way of adding the chemicals into the pulp suspension before forming, e.g., increased mechanical retention as well as high dosage giving increased wet strength without impairing the sheet uniformity. To engineer processes utilizing this new technology, the complex flow behavior of applied foams must be quantified. At the minimum, the foam viscosity and the slip velocity at the solid surfaces need to be known to build practical models that can be used in analyzing and upscaling unit processes of the foam-assisted application.In this study, the rheological behavior was quantified for foams having polyvinyl alcohol (PVOH), a widely used strength additive chemical, as the surfactant. The foam density was varied between 100 g/L and 300 g/L, and the concentration of the PVOH solution was varied between 0.5% and 6.0% (w/w). The foams were generated with a commercial foam generator, and the rheological properties of the foams were measured by using a horizontal pipe bank. At the outlet from the generator, the volumetric flow rate, the absolute pressure, and the bubble size distribution of the foam were measured. In the measurement pipe section, the viscous pressure gradient and the slip velocity were measured, after which the foam was discharged to ambient air pressure. The viscosity and the dynamic surface tension of the PVOH solutions were quantified with commercial laboratory devices. In the viscosity analysis, the apparent shear rate was calculated from the volumetric flow rate, and the resulting apparent viscosity was translated to real material viscosity data by applying the Weissenberg-Rabinowitsch correction. The results indicated that PVOH foams can be described with high accuracy as shear-thinning power-law fluids where the detailed behavior depends on the foam density and the PVOH concentration. Slip flow, as usual, increased with increasing wall shear stress, but it was also dependent on the PVOH concentration, the air content, and the bubble size. For both the foam viscosity and the slip flow, a correlation was found that described the quantitative behavior of all the studied foams with good accuracy.