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Amphoteric dry strength chemistry approach to deal with low-quality fiber and difficult wet-end chemistry conditions in the Asian and North American markets, TAPPI Journal January 2024

ABSTRACT: With Japan’s high recycling rates and low access to fresh fiber sources, reaching strength targets in manufacturing packaging materials is a challenge. Declining quality of recycled fiber and minimal freshwater con-sumption results in difficult wet-end chemistry conditions in terms of high conductivity and elevated levels of dissolved and colloidal substances (DCS). These trends are somewhat typical of other Asian regions. Due to global trade, Asian packaging materials have become a part of the North American (NA) raw material pool. The gradual closing of mill water circuits for fresh water and energy savings results in more difficult wet-end chemistry conditions experienced in North America. China’s ban on the import of mixed paper and the consequent ban on all waste-paper imports triggered a significant price drop in recycled raw material, resulting in plans for increased manufacturing capacity in North America. Between increased demand, decreasing fiber quality, and movement towards more closed white water systems associated with packaging grade paperboard (even a virgin fiber mill uses a fair amount of recycled fiber), new methods to overcome strength reduction in raw materials must be proactively considered for North America. Reviewing the strategies currently used in the Asian industry regarding strength development is an excellent starting place for NA producers. A clear difference between Asian and NA wet-end chemistry is the dominant position of amphoteric dry strength agents. This paper reviews the fundamentals of dry strength development that explain the trend towards the increased application of amphoteric dry strength technology for poor-quality fiber and highly contaminated water circuits in Asian markets. This paper discusses the development and application perfor-mance of the novel 4th generation amphoteric polyacrylamide (AmPAM) dry strength technology, based on selected laboratory and mill case studies.

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TAPPI News, Paper360º January/February 2024

Journal articles
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Open Access
Editoral: Investing in the future: Writing and peer-reviewing for TAPPI Journal, TAPPI Journal July 2024

ABSTRACT: Those who actively participate in TAPPI realize how much there is to gain from the networking, educational resources, career development, and other opportunities that come with this involvement. One important opportunity is the ability to share your work and expertise with others in your field, and an excellent way to do this is by taking part in the TAPPI Journal peer-review process, either as an author or a reviewer or both.

Journal articles
Magazine articles
Open Access
Modeling the dynamics of evaporator wash cycles, TAPPI Journal July 2024

ABSTRACT: Kraft pulping is a process that utilizes white liquor, composed of sodium sulfide (Na2S) and sodium hydroxide (NaOH), for wood delignification and pulp production. This process involves washing the dissolved organics and spent chemicals from the pulp, resulting in the generation of black liquor. Prior to its use as fuel in the recovery boiler, the black liquor is concentrated in multiple-effect evaporators. During the evaporation process, the inorganic salts present in the liquor become supersaturated and undergo crystallization. Fluctuations in sodium, carbonate, sulfate, and oxalate can give rise to severe sodium salt scaling events, which significantly impact the thermal efficiency of the evaporators, and ultimately, pulp production. Dynamic modeling provides insights into fluctuations in liquor chemistry in the evaporators. The primary objective of this study was to employ dynamic modeling to evaluate the effects of wash liquor recovery from evaporator wash cycles. The dynamics associated with wash cycles encompass variations in the concentrations of salts and solids in the recovered wash liquor, changes in the flow rate of wash liquor recovery, and fluctuations in liquor volume within the liquor tanks. The dynamic model was developed using Matlab Simulink and applied to the evaporation plant of a pulp mill in South America. By utilizing one month of mill process data, the model enabled the evaluation of fluctuations in liquor chemistry due to evaporator wash cycles. The developed model has demonstrated the potential to estimate the concentration of key ions responsible for scaling and to contribute to enhancements in evaporator washing strategies.

Journal articles
Magazine articles
Open Access
Comparing a linear transfer function-noise model and a neural network to model boiler bank fouling in a kraft recovery boiler, TAPPI Journal, July 2024

ABSTRACT: Boiler bank fouling reduces heat transfer efficiency in kraft recovery boilers. Here, we model the relationships between boiler parameters and boiler bank pressure drop, an indicator of fouling, based on recovery boiler operating data. We compared two models: an autoregressive integrated exogenous (ARIX) model and a feedforward neural network. The ARIX model better simulates boiler bank pressure drop compared to the neural network (R2 of 0.64 vs. 0.58). Based on the ARIX model, we identified six boiler parameters that significantly influence boiler bank fouling and their relative contributions. Finally, we demonstrate how the models can simulate boiler bank pressure drop given artificial perturbations in boiler parameters.