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Contrasting underlying mechanisms of different barrier coating types, TAPPI Journal January 2018
Contrasting underlying mechanisms of different barrier coating types, TAPPI Journal January 2018
Journal articles
Magazine articles
Citrus-based hydrocolloids: A water retention aid and rheology modifier for paper coatings, TAPPI Journal July 2019
ABSTRACT: The rheological and dewatering behavior of an aqueous pigmented coating system not only affects the machine runnability but also affects the product quality. The current study describes the use of natural hydrocol-loids derived from citrus peel fibers as a rheology modifier in paper coating applications. The results were compared with carboxymethyl cellulose (CMC) in a typical paper coating system. Water retention of the coating formulation was increased by 56% with citrus peel fibers compared to a default coating, and it also was higher than a CMC-containing coating. The Brookfield viscosity of paper coatings was found to increase with citrus peel fibers. Compared to CMC, different citrus peel fibers containing coating recipes were able to achieve similar or higher water retention values, with no change or a slight increase in viscosity. Coatings were applied on linerboard using the Mayer rod-coating method, and all basic properties of paper were measured to assess the impact of citrus peel fiber on the functional value of the coatings. Paper properties were improved with coated paper containing citrus peel fibers, including brightness, porosity, smoothness, surface bonding strength, and ink absorption.
Journal articles
Magazine articles
The evolution of reel statistical methods, TAPPI Journal June 2019
ABSTRACT: Multiple statistical methods for calculating the variance partition analysis (VPA) of reel data have existed for decades. In the paper industry, VPA is also commonly known as reel statistics. VPA commonly consists of total variance (TOT) that is then divided into three components: cross direction (CD), machine direction (MD), and residual (RES). A common mathematical procedure is referred to as ANOVA (analysis of variance). TAPPI Standard Test Method T 545 “Cross-machine grammage profile measurement (gravimetric method)” addresses paper testing and includes the ANOVA equations that have also been used to analyze scanning data.In the 1990s, TAPPI published TIP 1101-01 “Calculation and partitioning of variance using paper machine scanning sensor measurements,” which contained simple formulas that were easy to implement and could be used by a nov-ice to generate statistics on a spreadsheet. All involved quality control system (QCS) suppliers agreed to support this common method in their QCS. TIP 1101 was recently revised, and this paper concerns the analysis of data collected from a scanning sensor in a QCS and the creation of a common method for the calculation of reel statistics by TAPPI’s Process Control Division.
Journal articles
Magazine articles
Impact of fiber structure on edge-wicking of highly-sized paperboard, TAPPI JOURNAL August 2018
Impact of fiber structure on edge-wicking of highly-sized paperboard, TAPPI JOURNAL August 2018
Journal articles
Magazine articles
Tetraethyl orthosilicate-containing dispersion coating — water vapor and liquid water barrier properties, TAPPI Journal September 2021
ABSTRACT: An aqueous styrene-butadiene latex dispersion coating containing in-situ processed tetraethyl orthosilicate (TEOS) applied on paperboard demonstrated improved water barrier performance. Coatings containing TEOS equivalent to 0.8% silicon dioxide (SiO2; dry basis) exhibited water vapor performance of < 25 g/m2/day (23°C, 50% relative humidity [RH]) and liquid water barrier performance Cobb 1800 s of < 6 g/m2, when applied as a single-layer 18 g/m2 coating. Cobb 1800 s barrier performance was still good (< 11 g/m2) at coat weights of 7•10 g/m2. The use of filler materials such as kaolin improved the vapor barrier properties of the coating, but this was not critical to the liquid water barrier properties.
Journal articles
Estimating dose and interaction of X-rays with cellulose-based fibrous materials using micro-computed tomography, TAPPI Journal March 2026
ABSTRACT: Micro-computed tomography (ìCT) has a reputation as a nondestructive analysis method. Unfortunately, this leads to the common misconception that radiation damage of the sample does not play a role. With the increased use of ìCT in laboratory-based machines, more and more cellulose-based materials are studied. In this paper, we show with three examples that radiation damage is important in dry and wet paper and in viscose fibers. In an attempt to quantify radiation damage, we came up with a workflow that enables researchers to predict the X-ray dose within a laboratory-based ìCT machine. This gives researchers the possibility to quantitatively judge the influence of radiation damage on each measured sample. While one cannot extend the measured doses from one machine to another, one can still apply the work flow presented in this study to any ìCT setup. In this way, it is possible to minimize radiation damage by choosing the best parameters in a ìCT for obtaining perfect data with no or little radiation damage.
Journal articles
A method to produce paperboard with a lightweight low-density coating, TAPPI Journal November 2025
ABSTRACT: In this work, a method is described in which a coating layer is produced that consists of a network of bubble-shaped air-filled voids within the coating. This is accomplished by instantaneously flash-drying all the water in the coating as it exits the application nip. The nip is formed between a polished chrome drum and a deformable press roll. The combination of the drum temperature, nip pressure, and nip width allow for sufficient energy to be transferred to the coating to completely flash-dry the coating material. The pressure within the nip is sufficient to allow the coating to superheat within the nip, then flash boil as it exits the nip. This boiling effect and resulting expansion are constrained by the roll surface, resulting in a coated surface that mirrors the polished chrome surface. The coating immobilizes while in the process of boiling, which preserves the bubble structure. With a coat weight of 5 g/m2, a flat, smooth surface is produced. This process was scaled up to a mill production machine layout and run at speeds as high as 450 m/min.
Journal articles
Magazine articles
Review of coating cracking and barrier integrity on paperboard substrates, TAPPI JournalDecember 2024
Authors: Joel C. Panek and Peter W. Hart | TAPPI J. 21(11): 589(2022) - ABSTRACT: Barrier packaging formats are major growth areas for the pulp and paper industry. It is technically challenging to maintain barrier properties during converting and end-use applications. Improved manufacturing capabilities and coating formulation knowledge will help maintain barrier integrity and enable growth of barrier products in challenging applications. These improvements will accelerate product development and commercialization, and allow faster response to product performance issues such as cracking. The literature on coating cracking provides knowledge mostly on the effects of coating formulations and to a lesser extent on substrate effects. Despite a large number of publications dedicated to coating failures, the approach to improve coating cracking remains empirical, and the transferability between studies and to real life applications has not been well established. Model development that successfully predicts commercial performance is in its infancy. However, some of these simplified models do a fairly good job predicting experimental data. The current work reviews the state of understanding as regards coating and barrier cracking and highlights the need for more research on cracking and barrier integrity.
Journal articles
Magazine articles
Evaluation of rice straw for purification of lovastatin, TAPPI Journal November 2021
ABSTRACT: Cholesterol synthesis in the human body can be catalyzed by the coenzyme HMG-CoA reductase, and lovastatin, a key enzyme inhibitor, can reduce hypercholesterolemia. Lovastatin can be obtained as a secondary metabolite of Aspergillus terreus ATCC 20542. In this study, rice straw of lignocellulose was used in aeration and agitation bath fermentation in a 1-L flask, and a maximal crude extraction rate of 473 mg/L lovastatin was obtained. The crude extract was treated with silica gel (230•400 mesh) column chromatography. Ethyl acetate/ethanol (95%) was used as the mobile phase, and isolation was performed through elution with various ethyl acetate/ethanol ratios. The highest production rate of 153 mg/L was achieved with ethyl acetate/ethanol in a ratio of 8:2. The lovastatin gained from the crude extract was added to 12 fractions treated with 0.001 N alkali, and acetone was then added. After 24 h of recrystallization at 4°C, the extract underwent high-performance liquid chromatography. The purity had increased from 25% to 84.6%, and the recovery rate was 65.2%.
Journal articles
Magazine articles
Effects of phosphogypsum whiskers modification with calcium stearate and their impacts on properties of bleached softwood paper sheets, TAPPI Journal September 2021
ABSTRACT: By combining the structural properties and characteristics of phosphogypsum whiskers, a preliminary study on the modification of phosphogypsum whiskers and their application in papermaking was carried out. The effects of reaction temperature, reaction time, and reaction concentration on the solubility and retention of modified phosphogypsum whiskers and the effects of phosphogypsum whiskers on the physical properties of paper under different modified conditions were explored. The research results show that, after the phosphogypsum whiskers are modified with calcium stearate, a coating layer will be formed on the surface of the whiskers, which effectively reduces the solubility of the phosphogypsum whiskers. The best modification conditions are: the amount of calcium stearate relative to the absolute dry mass of the phosphogypsum whisker is 2.00%; the modification time is 30 min, and the modification temperature is 60°C. The use of modified phosphogypsum whiskers for paper filling will slightly reduce the whiteness, folding resistance, burst resistance, and tensile strength of the paper, but the tearing degree and retention of the filler will be increased to some extent.