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Probing the molecular weights of sweetgum and pine kraft lignin fractions, TAPPI Journal June 2021
ABSTRACT: The present investigation undertook a systematic investigation of the molecular weight (MW) of kraft lignins throughout the pulping process to establish a correlation between MW and lignin recovery at different extents of the kraft pulping process. The evaluation of MW is crucial for lignin characterization and utilization, since it is known to influence the kinetics of lignin reactivity and its resultant physico-chemical properties. Sweetgum and pine lignins precipitated from black liquor at different pHs (9.5 and 2.5) and different extents of kraft pulping (30•150 min) were the subject of this effort. Gel permeation chromatography (GPC) was used to determine the number average molecular weight (Mn), mass average molecular weight (Mw), and polydispersity of the lignin samples. It was shown that the MW of lignins from both feedstocks follow gel degradation theory; that is, at the onset of the kraft pulping process low molecular weight-lignins were obtained, and as pulping progressed, the molecular weight peaked and subsequently decreased. An important finding was that acetobromination was shown to be a more effective derivatization technique for carbohydrates containing lignins than acetylation, the technique typically used for derivatization of lignin.
Journal articles
Magazine articles
Quantification of vegetable oil in recycled paper, TAPPI JOURNAL September 2020
ABSTRACT: Vegetable soybean oil is commonly used in cooking foods that are packaged in takeaway paper-board containers. Vegetable oil is hydrophobic, and in sufficiently high concentration, could interfere with interfiber bonding and result in paper strength loss. In order to quantify the effect of oil on the resulting paperboard strength, it is necessary to quantify the oil content in paper. A lab method was evaluated to determine the soybean oil content in paper. Handsheets were made with pulps previously treated with different proportions of vegetable oil. Pyrolysis gas chromatography-mass spectrometry (pyGCMS) was used to quantify the amount of oil left in the handsheets. The results revealed a strong correlation between the amount of oil applied to the initial pulp and the amount of oil left in the handsheets.In addition, the effect of vegetable oils on paper strength may be affected by the cooking process. Vegetable oil is known to degrade over time in the presence of oxygen, light, and temperature. The vegetable oil was put in an oven to imitate the oil lifecycle during a typical pizza cooking process. The cooked oil was then left at room temperature and not protected from air (oxygen) or from normal daylight. The heated, then cooled, oil was stored over a period of 13 weeks. During this time, samples of the aged oil were tested as part of a time-based degradation study of the cooked and cooled oil.
Journal articles
Magazine articles
Pigmented aqueous barrier coatings, TAPPI Journal November 2020
ABSTRACT: The desire for more sustainable packaging has led to the development of new packaging materials that are fiber based. Aqueous coatings are a pathway to improve the recyclability of these materials. Pigments used in these coatings can improve the performance of the coating and reduce cost while further improving the recyclability. Mineral pigments are also considered to be compost neutral. In this paper, we provide the reader a better fundamental understanding of the mechanisms by which pigments work in barrier coatings. A pigment’s mineralogy and physical characteristics are important to how it will perform, and there have been recent pigment developments that improve coating performance. This paper shows that some pigments are better than others in particular barrier applications. Also, pigmented base or pre-coats can be used to prepare the surface for more highly functional coatings that go on top, improving the barrier function of packaging material and reducing overall cost. Finally, the converting operation is of major importance in driving formulation choices for barrier applications.
Journal articles
Magazine articles
Critical parameters for tall oil separation I: The importance of ration of fatty acids to rosin acids, TAPPI Journal September 2019
ABSTRACT: Tall oil is a valuable byproduct in chemical pulping of wood, and its fractions have a large spectrum of applications as chemical precursors, detergents, and fuel. High recovery of tall oil is important for the economic and environmental profile of chemical pulp mills. The purpose of this study was to investigate critical parameters of tall oil separation from black liquor. To investigate this in a controlled way, we developed a model test system using a “synthetic” black liquor (active cooking chemicals OH- and HS- ions), a complete process for soap skimming, and determination of recovered tall oil based on solvent extraction and colorimetric analysis, with good reproducibility. We used the developed system to study the effect of the ratio of fatty acids to rosin acids on tall oil separation. When high amounts of rosin acids were present, tall oil recovery was low, while high content of fatty acids above 60% significantly promoted tall oil separation. Therefore, manipulating the content of fatty acids in black liquor before the soap skimming step can significantly affect the tall oil solubility, and hence its separation. The findings open up chemical ways to improve the tall oil yield.
Journal articles
Magazine articles
A new technique for the measurement of show-through mottle of fine paper, TAPPI Journal September 2019
ABSTRACT: Mottling within print-through and show-through is caused by the variability of the local optical properties of the sheet. This mottling is visually disturbing and a mark of poor paper quality. The ability to predict print-through mottle of printed paper by measuring show-through mottle on the unprinted sheet would be a valuable asset for paper machine control.We examined the relationship between print-through mottle and show-through mottle. We worked with nine samples of 60 lb. uncoated fine paper (90 g/m2), from various North American paper companies, that were printed on an offset press, 400K (400% Black), on both sides. A show-through mottle instrumental determination technique was developed using an existing Fast Fourier Transform-based algorithm. The nine samples examined were ranked similarly by the visual evaluation of print-through mottle and by the instrumental determination of show-through mottle. We thus established that show-through on the unprinted sheet can be used as a reliable predictor of print-through, therefore saving time and money for papermakers. We also found a significant two-sidedness in show-through for some of the samples.
Journal articles
Influence of base sheet properties on barrier coating performance, TAPPI Journal November 2025
ABSTRACT: Paper packaging offers a sustainable alternative to standard plastic-based materials, particularly for food and beverage applications. With reduced fiber treatment options like fluorochemicals, uncoated base stock often provides little-to-no effective barrier against liquid water, oil/grease, or moisture transmission. Despite the lack of natural barrier performance, base sheet properties can significantly influence the efficiency of applied waterbased barrier coatings. In this study, various base stock properties, such as caliper, porosity, roughness, and ash content, are reported to influence the barrier performance of styrene-acrylic and a copolymer of styrene-butadiene/styrene-acrylate based barrier coatings. These findings will help paper and board producers design better, more cost-effective, purposebuilt substrates for barrier applications in the packaging industry.
Journal articles
A laboratory-scale automated vacuum-assisted device for coating of cellulose nanofibrils onto paper, TAPPI Journal November 2025
ABSTRACT: An automated vacuum-assisted coating system was developed to deposit cellulose nanofibril (CNF) layers onto paper substrates, simulating potential industrial geometries while allowing precise control of web speed (10•20 m/min), vacuum time (up to 30 s), and applicator gap (0.5•0.9 mm). Vacuum assistance makes it possible to obtain coat weights over 5 g/m2 in a single pass and increases solids after coating from less than 10% to over 28%• 30%, reducing drying demand by more than 60%. Coat weights were tuned from 6 to over 11 g/m² by varying suspension solids (0.4•0.6 wt%), line speed, and filtration length (20•40 mm), with strong agreement between experimental data and model predictions. Barrier testing showed Kit test values for double folded samples of 9•12 and Gurley air resistances above 4 × 104 s once coat weights exceeded 7 g/m². Comparable performance was achieved with lower fines content CNF (60%) by increasing coat weight, providing technical flexibility and cost advantages for industrial scale-up.
Journal articles
Permeability simulation for filled paper based on three-dimensional structural model developed by X-ray computed tomography scanning, TAPPI Journal March 2026
ABSTRACT: In this study, an in-depth exploration of filled paper was conducted to understand its structural and permeability characteristics. Cotton linter pulp and precipitated calcium carbonate (PCC) filler were utilized to prepare pure fiber paper, and PCC1 and PCC2 filled papers with different filler particle sizes. Then, the pore structure parameters of paper samples were characterized by mercury intrusion porosimetry, and the X-ray computed tomography (X-CT) scanning was carried out. Subsequently, the 3D microstructures were established based on the X-CT slice images, and the filler characteristic parameters and filler 3D distribution were quantitatively analyzed. Finally, permeation simulations in the thickness and horizontal directions were performed. The findings indicate that filling changes the paper porosity, and the pore tortuosity varies with direction. The estimated pore•throat radius distribution shows specific patterns for different papers. The fillers have different distribution characteristics in the paper samples. Moreover, the paper permeability differs with direction, with smallsized filler having a significant impact on fluid penetration in the thickness direction. Overall, this study provides an effective method for investigating internal paper filler and its distribution, which contributes to the understanding of paper structure•performance relationships.
Journal articles
Effects of in-plane straining on the out-of-plane delamination properties of paperboard, TAPPI Journal March 2026
ABSTRACT: Delamination strength is an essential property for the creasing and folding operations of paperboard into boxes. Due to fixation during creasing, the paperboard suffers in-plane straining. In the present study, we aim to increase our understanding of how in-plane straining affects the delamination properties of paperboard. Samples of paperboard were first strained in in-plane tensile loading, both in the machine-direction and in the cross-direction. Afterward, the paperboard is loaded in the out-of-plane (ZD) direction. Three different grades of commercial paperboard from two major manufacturers were tested in a climate-controlled lab. The results showed similar results for all grades of paperboard, with the delamination strength and the out-of-plane stiffness decreasing virtually linearly with pre-straining. With about 5% plastic in-plane straining, the strength was reduced by about 20% and the stiffness decreased by more than 50% for all grades of paperboard. Normalizing the strength and the stiffness with their values without pre-straining reveals virtually the same relation for all grades of paperboard. If proven to be a general result, this will prove valuable in reducing the demand for experiments.
Journal articles
Magazine articles
Chemical addition to wet webs using foam application, TAPPI Journal January 2023
ABSTRACT: In papermaking, the conventional way to add chemicals to the web is to dose them into the fiber stock and form the paper afterwards. However, in many cases, adding chemicals directly to the stock is challenging. For example, strength aids tend to increase flocculation in the stock, which limits the addition amounts of those aids. The need for better performance of paper (and paperboard) products has given rise to the need for functionalization of paper. Adding such functional chemicals to the stock is usually rather inefficient. Hence, novel methods are needed to add chemicals to the paper bulk. One such method is dosing chemicals to the wet web via foam application. In this study, we built a laboratory-scale sheetfed dynamic foam application device and utilized it to study addition of starch to wet bleached chemithermomechanical pulp (BCTMP) paper handsheets. The impact of parameters such as vacuum level, the amount of added chemical, and the viscosity of the foaming liquid on the penetration of starch into the wet web was explored. Starch penetration into wet webs was measured via iodine-potassium iodide staining, followed by image analysis. According to our results, controlling the viscosity of the foaming liquid gives the best possibility to control the penetration.