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Journal articles
Open Access
Single-Site Catalyst Produced Polyolefin Plastomers for Extrusion Coating and Laminating, TAPPI JOURNAL, January 1999, Vol. 83(5)

Single-Site Catalyst Produced Polyolefin Plastomers for Extrusion Coating and Laminating, TAPPI JOURNAL, January 1999, Vol. 83(5)

Journal articles
Open Access
Use of Mercury Porosimetry to Characterize Pore Structure and Model End-use Properties of Coated Papers - Part 1: Optical and Strength Properties, TAPPI JOURNAL, January 1999, Vol. 83(5)

Use of Mercury Porosimetry to Characterize Pore Structure and Model End-use Properties of Coated Papers - Part 1: Optical and Strength Properties, TAPPI JOURNAL, January 1999, Vol. 83(5)

Journal articles
Open Access
Hydrodynamic Pressure Generated by Doctoring in Blade Gap Fo

Hydrodynamic Pressure Generated by Doctoring in Blade Gap Formers, 1999 Engineering Conference Proceedings

Journal articles
Magazine articles
Open Access
Three-dimensional visualization and characterization of paper machine felts and their relationship to their properties and dewatering performance, TAPPI Journal July 2021

ABSTRACT: Polymeric felts are commonly used in the papermaking process on the paper machine wet end, in the press section, and in the dryer section. They provide an important function during paper manufacturing, including as a carrier or support; as a filter media assisting with water removal on the paper machine; in retention of fibers, fines, and fillers; and in some applications, such as tissue and towel, to impart key structural features to the web. These felts can have highly interwoven complex internal structures comprised of machine direction and cross-machine direction yarns of varying sizes and chemical compositions. Here, we present a non-intrusive three-dimensional (3D) image visualization method using advanced X-ray computed tomography (XRCT). This method was used to characterize the complex 3D felt structure and determine the water removal characteristics of some commonly used paper machine felts. The structural features analyzed include porosity; specific pore-yarn interfacial surface area; 3D pore size distribution; 3D fiber or yarn-size distribution; and their variations through the thickness direction. The top, middle, and bottom layers of the felt have very different structures to assist with water removal and impart paper properties. The size distribution of the yarns, as well as the pores in the different layers of the felt, are also inherently different. These structural features were non-intrusively quantified. In addition, variation in the structural characteristics through the thickness of the felts and its potential role in papermaking is explored. In addition to the 3D structural characteristics, permeability characteristics and water removal characteristics, including rewetting of select felt samples, have also been experimentally determined. It is interesting to observe the relationship between key structural features and permeability and water removal characteristics. These relationships can provide additional insights into press felt design, as well as ways to improve product properties and the dewatering efficiency and productivity of the paper machine.

Journal articles
Magazine articles
Open Access
Tetraethyl orthosilicate-containing dispersion coating — water vapor and liquid water barrier properties, TAPPI Journal September 2021

ABSTRACT: An aqueous styrene-butadiene latex dispersion coating containing in-situ processed tetraethyl orthosilicate (TEOS) applied on paperboard demonstrated improved water barrier performance. Coatings containing TEOS equivalent to 0.8% silicon dioxide (SiO2; dry basis) exhibited water vapor performance of < 25 g/m2/day (23°C, 50% relative humidity [RH]) and liquid water barrier performance Cobb 1800 s of < 6 g/m2, when applied as a single-layer 18 g/m2 coating. Cobb 1800 s barrier performance was still good (< 11 g/m2) at coat weights of 7•10 g/m2. The use of filler materials such as kaolin improved the vapor barrier properties of the coating, but this was not critical to the liquid water barrier properties.

Journal articles
Magazine articles
Open Access
Application of ATR-IR measurements to predict the deinking efficiency of UV-cured inks, TAPPI Journal January 2022

ABSTRACT: In recent years, ultraviolet (UV)-curable ink has been developed and widely used in various printing applications. However, using UV-printed products (UV prints) in recovered paper recycling causes end-product dirt specks and quality issues. A new method was developed that can distinguish UV prints from other prints by means of attenuated total reflectance infrared (ATR-IR) spectroscopy. Application of this method could allow more efficient use of UV prints as raw materials for paper recycling.First, a mill trial was performed using UV prints alone as raw materials in a deinked pulp (DIP) process. Second, test prints were made with four types of UV inks: a conventional UV ink and three different highly-sensitive UV inks. Each print sample had four levels of four-color ink coverage patterns (100%, 75%, 50%, and 25%). Next, deinkability of all prints was evaluated by laboratory experiments. Finally, each print was measured using the ATR-IR method, and the relationship between the IR spectra and deinkability was investigated. Mill trial results showed that UV prints caused more than 20 times as many dirt specks as those printed with conventional oil-based ink. There were variations in recycling performance among UV prints taken from bales used for the mill trial. Lab tests clearly revealed that not all UV-printed products lead to dirt specks. In order to clarify the factors that affected deinkability of UV prints, the print samples were investigated by lab experiments. Key findings from lab experiments include: œ The number of dirt specks larger than 250 µm in diameter increased as the ink coverage increased. œ Higher ink coverage area showed stronger intensity of ATR-IR spectral bands associated with inks. These results indicate that deinkability of UV prints could be predicted by analysis of ATR-IR spectra. œ Finally, the method was applied for assessment of recovered paper from commercial printing presses. It was confirmed that this method made it possible to distinguish easily deinkable UV prints from other UV prints. Based on these findings, we concluded that the ATR-IR method is applicable for inspection of incoming recovered paper.

Journal articles
Magazine articles
Open Access
Web lateral instability caused by nonuniform paper properties, TAPPI Journal January 2022

ABSTRACT: Lateral or cross-machine direction (CD) web movement in printing or converting can cause problems such as misregistration, wrinkles, breaks, and folder issues. The role of paper properties in this problem was studied by measuring lateral web positions on commercial printing presses and on a pilot-scale roll testing facility (RTF). The findings clearly showed that CD profiles of machine direction (MD) tension were a key factor in web stability. Uneven tension profiles cause the web to move towards the low-tension side. Although extremely nonuniform tension profiles are visible as bagginess, more often, tension profiles must be detected by precision devices such as the RTF. Once detected, the profiles may be analyzed to determine the cause of web offset and weaving problems.Causes of tension profiles can originate from nonuniform paper properties. For example, by means of case studies, we show that an uneven moisture profile entering the dryer section can lead to a nonuniform tension profile and lateral web movement. Time-varying changes in basis weight or stiffness may also lead to oscillations in the web’s lateral position. These problems were corrected by identifying the root cause and making appropriate changes. In addition, we developed a mathematical model of lateral stability that explains the underlying mechanisms and can be used to understand and correct causes of lateral web instability.

Journal articles
Magazine articles
Open Access
Web instability in the open draw and the impact on paper machine efficiency, TAPPI Journal May 2022

ABSTRACT: Paper is most likely to break in the first open draw on a paper machine where it is unsupported, wettest, and weakest. Tension is applied to peel the web from the roll surface, as well as minimize web flutter in the open draw. The average tension is well below the breaking point and is often set by adjusting the speed difference between the press and the next machine element by visually observing the behavior of the web. However, machine direction variations caused by instabilities in the paper machine can cause tension swings that exceed the strength of the web. Measurement of the web’s release point from press rolls on pilot and commercial paper machines was used to identify the cause of tension instabilities. Variations in the speed of the paper machine drives and the work of adhesion from the press roll surface were identified as key factors. Fluctuations of paper moisture, which affects the elastic modulus and strength of the web, appear to be less important.

Journal articles
Magazine articles
Open Access
Evaluation of soap recovery efficiency from black liquor — analytical tools, TAPPI Journal April 2023

ABSTRACT: Soap skimmings (“soap”) are typically recovered from black liquor in kraft mills that process a high percentage of softwood. In many mills, the recovery of soap is inefficient, negatively impacting performance of evaporators and recovery boilers and resulting in loss of potential revenue. A thorough evaluation of soap recovery performance in a kraft mill requires measurement of soap content in black liquor at various sampling locations, especially around the soap skimmer.The standard laboratory method for evaluating soap content in black liquor is a complex, multi-step process that relies on solvent extraction and titration; most mills send these samples to an outside laboratory for this analysis. In this study, 100 black liquor samples, with a wide range of soap concentrations, were tested by the standard solvent extraction method. After additional dilution, each sample was also tested for surface tension with a bubble pressure tensiometer. The results were found to correlate very closely with the solvent extraction tests results. This alternate method, using surface tension measurements of diluted black liquor samples, produces rapid results and can be easily implemented in most kraft mills, which would facilitate much more frequent in-house evaluations of soap recovery performance.

Journal articles
Magazine articles
Open Access
Pilot scale black liquor concentration using pressure driven membrane separation, TAPPI Journal April 2023

ABSTRACT: Black liquor concentration using pressure driven membrane separation has long been proposed as a means of achieving energy savings and breaking production bottlenecks. To date, limitations in membrane performance and stability under black liquor process conditions have prevented those promises from being realized out-side of tightly controlled laboratory settings. In this work, we describe the first successful pilot scale field deployments of a membrane system for black liquor concentration. Using a purpose-built system and commercial sized, spiral wound graphene oxide membrane elements, we have logged nearly 6000 h of runtime across deployments to multiple mill sites. We demonstrate concentration of black liquor from 14% to >20% total solids, while generating permeate water comparable in quality to that of evaporator condensate and an 81% reduction in energy consumption relative to evaporation. At a commercial scale, these results translate to $2 M/year in net energy savings for a typical mill, as well as an opportunity to support production increases or mill expansions. These results represent a significant leap forward in the ability of membrane systems to deliver substantial value via black liquor concentration.