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Tetraethyl orthosilicate-containing dispersion coating — water vapor and liquid water barrier properties, TAPPI Journal September 2021
ABSTRACT: An aqueous styrene-butadiene latex dispersion coating containing in-situ processed tetraethyl orthosilicate (TEOS) applied on paperboard demonstrated improved water barrier performance. Coatings containing TEOS equivalent to 0.8% silicon dioxide (SiO2; dry basis) exhibited water vapor performance of < 25 g/m2/day (23°C, 50% relative humidity [RH]) and liquid water barrier performance Cobb 1800 s of < 6 g/m2, when applied as a single-layer 18 g/m2 coating. Cobb 1800 s barrier performance was still good (< 11 g/m2) at coat weights of 7–10 g/m2. The use of filler materials such as kaolin improved the vapor barrier properties of the coating, but this was not critical to the liquid water barrier properties.
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Editorial: TAPPI Journal 2019 Best Research Paper addresses hard scale formation in green liquor pipelines, TAPPI Journal March 2020
ABSTRACT: TAPPI and the TAPPI Journal (TJ) Editorial Board would like congratulate the authors of the 2019 TAPPI Journal Best Research Paper Award: Alisha Giglio, Vladimiros Papangelakis, and Honghi Tran. Their paper, “The solubility of calcium carbonate in green liquor handling systems,” appeared on p. 595 of the October 2019 issue. This kraft recovery cycle research was recognized by the TJ Editorial Board for its innovation, creativity, scientific merit, and clear expression of ideas.
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Understanding extensibility of paper: Role of fiber elongation and fiber bonding, TAPPI Journal March 2020
ABSTRACT: The tensile tests of individual bleached softwood kraft pulp fibers and sheets, as well as the micro-mechanical simulation of the fiber network, suggest that only a part of the elongation potential of individual fibers is utilized in the elongation of the sheet. The stress-strain curves of two actual individual pulp fibers and one mimicked classic stress-strain behavior of fiber were applied to a micromechanical simulation of random fiber networks. Both the experimental results and the micromechanical simulations indicated that fiber bonding has an important role not only in determining the strength but also the elongation of fiber networks. Additionally, the results indicate that the shape of the stress-strain curve of individual pulp fibers may have a significant influence on the shape of the stress-strain curve of a paper sheet. A large increase in elongation and strength of paper can be reached only by strengthening fiber-fiber bonding, as demonstrated by the experimental handsheets containing starch and cellulose microfibrils and by the micromechanical simulations. The key conclusion related to this investigation was that simulated uniform inter-fiber bond strength does not influence the shape of the stress-strain curve of the fiber network until the bonds fail, whereas the number of bonds has an influence on the activation of the fiber network and on the shape of the whole stress-strain curve.
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Effects of different ammonium lignosulfonate contents on the crystallization, rheological behaviors, and thermal and mechanical properties of ethylene propylene diene monomer/polypropylene/ammonium lignosulfonate composites, TAPPI Journal January 2020
ABSTRACT: Thermoplastic elastomer (TPE), made from ethylene propylene diene monomer (EPDM) and polypropylene (PP) based on reactive blending, has an excellent processing performance and characteristics and a wide range of applications. However, there are currently no reports in the literature regarding the usage of TPE in making composite boards. In this paper, EPDM, PP, and ammonium lignosulfonate (AL) were used as the raw materials, polyethylene wax was used as the plasticizer, and a dicumyl peroxide vulcanization system with dynamic vulcanization was used to make a new kind of composite material. This research studied the influences of the AL contents on the crystallization behaviors, rheological properties, thermal properties, and mechanical properties of the composites. The results showed that the AL content had a noticeable impact on the performance of the composite board. Accordingly, this kind of composite material can be used as an elastomer material for the core layer of laminated flooring.
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Wheat straw as an alternative pulp fiber, TAPPI Journal January 2020
ABSTRACT: The desire to market sustainable packaging materials has led to an interest in the use of various fiber types as a raw material. It has been suggested that the use of annual crops for partial replacement of wood fiber would result in more sustainable products. Several life cycle analyses (LCA) have been performed to evaluate these claims. These LCAs provided conflicting and contradictory results because of the local conditions and the specific pulping processes investigated. Selected LCAs are reviewed and the underlying reasons for these conflicting results are analyzed.
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How to use total dissolved solids measurements to evaluate the performance of diffuser washers—A mill study, TAPPI Journal April 2020
ABSTRACT: Various types of pulp washing equipment are available. Each washing device has a unique mechanical construction, and the washing principle is often a combination of dilution, thickening, and displacement washing. In this work, the performance of the pressure diffuser washer is studied. In stepwise trials, the effect of the feed and discharge consistencies on the performance of the diffuser was studied. The effect of the downward velocity of the screen on the pressure diffuser’s washing efficiency was also studied. The measurement of total dissolved solids (TDS) by a process refractometer was used as a wash loss measurement unit and the refractometer’s results were used in the calculations of standardized Nordén efficiency (E10) values. The chemical oxygen demand (COD) and conductivity values were also measured and their results compared to the TDS results.The results indicated that feed consistency has a significant effect on the performance and effectiveness of the diffuser washers in the mill. It can also be stated that when the downward velocity of the screen is adjusted to too high a level, the washing efficiency of the pressure diffuser decreases. As a conclusion from the mill tests, it can be stated that even small process parameter changes can provide enhanced diffuser washing at the beginning of the washing line, which has a direct effect on the performance of post-oxygen washing.
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Mill experience of calcium carbonate scale formation in green liquor pipelines, TAPPI Journal August 2020
ABSTRACT: Experience of hard calcite (CaCO3) scale formation in green liquor pipelines at four kraft pulp mills was systematically investigated to determine if there is any correlation between the severity of the scaling problem at each mill and the design and operating conditions of its causticizing plant. The results show that the high degree of supersaturation of calcium ions (Ca2+) in the liquor is the main contributing factor. Mills that operate at a lower green liquor total titratable alkali (TTA), higher causticity, and a larger liquor temperature drop are more likely to produce a green liquor that is supersaturated with Ca2+, and thus experience more severe scaling problems. In order to minimize CaCO3 scaling, the green liquor handling equipment should be operated as steady as possible to avoid conditions that allow Ca2+ to be supersaturated. The strategies include minimizing variations in liquor TTA, insulating the green liquor pipelines to reduce temperature gradients, and adding lime mud to weak wash to provide seeds for precipitation to occur on mud particles instead of on metal substrate.
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Does the kappa number method accurately reflect lignin content in nonwood pulps?, TAPPI Journal November 2018
Does the kappa number method accurately reflect lignin content in nonwood pulps?, TAPPI Journal November 2018
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Understanding the pulping and bleaching performances of eucalyptus woods affected by physiological disturbance, TAPPI Journal November 2018
Understanding the pulping and bleaching performances of eucalyptus woods affected by physiological disturbance, TAPPI Journal November 2018
Journal articles
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A review of green liquor scale formation, TAPPI Journal October 2018
A review of green liquor scale formation, TAPPI Journal October 2018