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Value creation by converting pulp mill flue gas streams to green fuels, TAPPI Journal March 2023
ABSTRACT: Climate change mitigation induces strong growth in renewable electricity production, partly driven by shifts in environmental policies and regulation. Intermittent renewable electricity requires supporting systems in the form of sustainable hydrocarbon chemicals such as transportation fuels. Bulk chemical production fits well into a pulp mill environment, given their large volumes, stable operation, and ample supply of biomass-based carbon feed-stock in the form of flue gases. Until now, the utilization of the flue gases from conventional operation of a pulp mill has received little attention. Harnessing these flue gases into usable products could offer additional value to mill operators, while also diversifying their product portfolio. However, electricity-based fuels and products require extra energy in the conversion step and may not be commercially competitive with current fossil products under the current regulation. There might also be uncertainties about future commodity prices. Thus, the objective of this study is to estimate the economic competitiveness and the added value of selected side products that could be produced alongside conventional pulp and paper products. A typical modern pulp mill is modeled in different product configurations and operational environments, which allows testing of various development paths. This illustrates how the overall energy and mass balance of a pulp mill would react to changes in different final products and other parameters. The focus of the study is in synthetic methanol, which is produced from flue gases and excess resources from the mill, with minimal interference to the pulping process. The results aid in assessing the necessity and magnitude of a premium payment for subsidizing green alter-natives to replace current fossil fuels and chemicals. Additionally, the results function as an indicator of the development state of the pulp and paper industry in the turmoil of climate change regulation. The results indicate that power-to-X systems offer one more viable pathway alternative for broadening the product portfolio of the pulp and paper sector, as well as opening new flexibility measures and services to grid stabilization. Market conditions were found to have a significant impact on the perceived profitability.
Journal articles
Magazine articles
Techno-economic analysis of hydrothermal carbonization of pulp mill biosludge, TAPPI Journal March 2023
ABSTRACT: For many mills, the biosludge from wastewater treatment is difficult to recycle or dispose of. This makes it a challenging side stream and an important issue for chemical pulping. It often ends up being burned in the recovery or biomass boiler, although the moisture and non-process element (NPE) contents make it a problematic fuel. Biosludge has proven resistant to attempts to reduce its moisture. When incinerated in the biomass boiler, the heat from dry matter combustion is often insufficient to yield positive net heat. Mixing the sludge with black liquor in the evaporator plant for incineration in the recovery boiler is more energy efficient, but is still an additional load on the evaporator plant, as well as introducing NPEs to the liquor. In this study, treating the biosludge by hydrother-mal carbonization (HTC), a mild thermochemical conversion technology, is investigated. The HTC process has some notable advantages for biosludge treatment; taking place in water, it is well suited for sludge, and the hydrochar product is much easier to dewater than untreated sludge. In this study, two HTC plant designs are simulated using IPSEpro process simulation software, followed by economic analysis. Low temperature levels are used to minimize investment costs and steam consumption. The results show that if the sludge is incinerated in a biomass boiler, payback periods could be short at likely electricity prices. The HTC treatment before mixing the sludge with black liquor in the evaporator plant is profitable only if the freed evaporator capacity can be used to increase the firing liquor dry solids content.
Journal articles
Magazine articles
Mechanical modification of softwood pulp fibers using a novel lightweight vertical bar plate, TAPPI Journal April 2021
ABSTRACT: Refiner plates made using sand casting have a draft angle, which results in a trapezoidal bar shape. These trapezoidal bar plates have a limited throughput compared to the vertical bar plates, and eventually the edges of the bars become dull, resulting in longer time to reach the target freeness and shorter service life. The new light-weight refiner plate with a bar insertion method into a plate base was developed by selecting an aluminium-based alloy as the plate base material and a stainless steel alloy with high wear resistance as the bar material. The light-weight plate with sharp bar edges was very effective in reducing refining energy by reaching the target freeness faster than the sand-cast bar plate. Finally, the lightweight sharp bar plate, which weighed only about half the weight of the cast bar plate, was expected to significantly contribute to easy replacement, improved paper quality, and larger throughput without excessive loss of fiber length.
Journal articles
Magazine articles
Multifunctional starch-based barrier materials, TAPPI Journal August 2021
ABSTRACT: Natural and renewable polymer-based barrier materials play an inevitable role in a sustainable economy. Most commercially available barrier materials are either based on multiple layers of synthetic polymers or petroleum-based chemicals. Tremendous amounts of research are being done in academia and industry to replace these synthetic barrier materials with natural and environmentally friendly materials. The current work summarizes the application of starch-based materials for various barrier applications, such as water vapor, oxygen, liquid water, oil, and grease. Also, exotic starch-based barrier materials for the application of sound, ultraviolet, and thermal barrier applications are reviewed. The potential of starch-based materials to offer antimicrobial and antiviral properties is discussed. Finally, commercially available starch-based barrier materials have been summarized.