Search
Use the search bar or filters below to find any TAPPI product or publication.
Filters
Content Type
Publications
Level of Knowledge
Committees
Collections
Journal articles
Magazine articles
The role of hornification in the deterioration mechanism of physical properties of unrefined eucalyptus fibers during paper recycling, TAPPI Journal February 2024
ABSTRACT: Physical properties of cellulosic paper deteriorate significantly during paper recycling, which hinders the sustainable development of the paper industry. This work investigates the property deterioration mechanism and the role of hornification in the recycling process of unrefined eucalyptus fibers. The results showed that during the recycling process, the hornification gradually deepened, the fiber width gradually decreased, and the physical properties of the paper also gradually decreased. After five cycles of reuse, the relative bonding area decreased by 17.6%, while the relative bonding force decreased by 1.8%. Further results indicated that the physical property deterioration of the paper was closely related to the decrease of fiber bonding area. The fiber bonding area decreased linearly with the reduction of re-swollen fiber width during paper recycling. Re-swollen fiber width was closely related to the hornification. Hornification mainly reduces the bonding area of unrefined eucalyptus fiber rather than the bonding force. The work elucidates the role of hornification in the recycling process of unrefined eucalyptus fibers and the deterioration mechanism of paper physical properties, which will be helpful to control the property deterioration of paper and achieve a longer life cycle.
Journal articles
A systems approach for process debottlenecking towards a sustainable pulp and paper industry, TAPPI Journal April 2026
ABSTRACT: Increasing the competitiveness of the pulp and paper industry requires an effective optimization of its existing assets in line with a long-term vision for process transformation, production upgrade, and product diversification. Currently, pulp production increase is one of the main sources of additional revenue for the kraft industry. Likewise, energy efficiency is often employed as a cost-effective approach to reduce operating costs, enhancing the possibilities to lower fossil fuel consumption and contributing to a low-carbon economy. On the other hand, reaching higher production targets and facilitating process transformation, such as biorefinery implementation, heavily depend on the status and performance of a mill’s current infrastructure; therefore, a system analysis is needed to assess the new production requirements, the bottlenecks, and the interactions across departments. In order to obtain practical improvement solutions, direct and indirect impacts on process performance and resource utilization should be considered. This work provides an overview of the key challenges that need to be addressed for production increase and energy efficiency improvement. The methodology starts by a scope analysis for debottlenecking and screening capacity limitations vs. mill targets, followed by their ranking (bottleneck ranking diagram). Benchmarking, gap analysis, and root-cause techniques are applied to diagnose system inefficiencies. This mill-wide debottlenecking assessment is then used to guide the selection of a long-term sustainable operation and design a portfolio of improvement projects by avoiding cross effects of the short-term projects on the long term. A case study of a kraft pulp mill is used to illustrate the proposed methodology.
Journal articles
A targeted approach to produce energy-efficient packaging materials from high-yield pulp, TAPPI Journal August 2025
ABSTRACT: Unlike fossil-based plastics, wood-based packaging materials can be produced in an ecofriendly manner using wood chip residuals from sawmills and pulpwood. To produce high-yield pulp like chemithermomechanical pulps (CTMPs) for paperboard and liquid packaging, it is crucial to reduce the electric energy consumption during fiber separation. The ultimate objective is to revolutionize paperboard production by achieving a middle-layer CTMP process that consumes less than 200 kilowatt-hours per metric ton (kWh/t), significantly improving from the current 500•600 kWh/t energy demand. Optimizing the CTMP impregnation process of sodium sulfite (Na2SO3) in wood chips is crucial for achieving uniform softening, ideally at the fiber level. The properties of the fibers are significantly affected by the content of lignin sulfonates within the walls of the fiber and the middle lamellae. In this study, we employed in-house developed X-ray fluorescence (XRF) techniques, validated by beamline measurements, to map the distribution of sulfonated lignin within fibers. It also seemed possible to enhance the surface area of lignin-rich pulp fibers while losing minimal bulk by refining them with well-optimized low consistency (LC) refining. We aimed to achieve a highly efficient separation of coniferous wood fibers by co-optimizing the sulfonation and the temperature in the preheater and chip refiner. Additionally, we explored how lignin’s softening behavior and potential crosslinking influence subsequent unit operations, including pressing, peroxide bleaching, and drying, following the defibration process. In defibration during chip refining, the maximum softening of wood fibers is preferred to maximize fiber preservation and minimize energy consumption. However, optimizing the stiffness of finished pulp fibers is preferable to reduce bulk loss during paperboard production. It can strive to optimize processes to develop stronger, lighter, and more sustainable composite packaging materials. Reducing environmental impact and electric energy can help create a more sustainable future.
Journal articles
Paper strength factors in systems with nanofibrillated cellulose, cationic starch, colloidal silica, cationic acrylamide copolymer, and hydrodynamic shear, TAPPI Journal May 2025
ABSTRACT: Laboratory paper sheets were formed by first pretreating nanofibrillated cellulose (NFC) with cationic starch at the 5% level by mass. The treated NFC was then added to stock prepared from 100% recycled copy paper. The combined furnish was next optionally treated with a cationic retention aid (cPAM, 0.1%) and then colloidal silica (0.1% or 0.2%). Vacuum dewatering, fine-particle retention, and several paper properties were studied as a function of the colloidal silica level (zero, 1%, and 2%) and at different levels of shear stress applied just before forming the sheets. Dewatering and strength results were generally more favorable when using a medium charge cationic starch (~ 0.03 degree of substitution, DS) to pretreat the NFC rather than a high charge density cationic starch (~ 0.2 DS). In each case, the dewatering was further enhanced by subsequent treatments by cPAM (0.1% on whole furnish solids) and then even more with the final addition of colloidal silica (0.1% and 0.2% levels compared). However, the colloidal silica additions progressively hurt the tensile strength of the paper, especially in the case of the high charge cationic starch and at the higher level of colloidal silica. Though the dewatering performance was favorable, in such cases, the paper strength was not improved compared to paper made without any NFC. The fact that the systems involving cPAM treatment, and especially those involving both cPAM and colloidal silica, tended to reduce the resulting paper’s tensile strength supports a mechanism in which the additives result in the clustering of the NFC, possibly in multiparticle bunches. Evidence suggests that such bunches of clustered NFC particles, which are difficult to redisperse even at levels of hydrodynamic shear present in high-speed paper machine systems, are resistant to full integration into the sheet structure as the paper is being formed.
Journal articles
Magazine articles
Application of spruce wood flour as a cellulosic-based wood additive for recycled paper applications— A pilot paper machine study, TAPPI Journal October 2021
ABSTRACT: This study gives a first insight into the use of wood flour as a plant-based and cellulosic-based alter-native additive for newsprint and paperboard production using 100% recycled fibers as a raw material. The study compares four varieties of a spruce wood flour product serving as cellulosic-based additives at addition rates of 2%, 4%, and 6% during operation of a 12-in. laboratory pilot paper machine. Strength properties of the produced news-print and linerboard products were analyzed. Results suggested that spruce wood flour as a cellulosic-based additive represents a promising approach for improving physical properties of paper and linerboard products made from 100% recycled fiber content. This study shows that wood flour pretreated with a plant-based polysaccharide and untreated spruce wood flour product with a particle size range of 20 μm to 40 μm and 40 μm to 70 μm can increase the bulk and tensile properties in newsprint and linerboard applications.
Journal articles
Magazine articles
Flow rheology of light foams generated from aqueous solutions of polyvinyl alcohol, TAPPI Journal January 2023
ABSTRACT: Recent studies have shown that foam-assisted application of additives into a wet web has advantages over the conventional way of adding the chemicals into the pulp suspension before forming, e.g., increased mechanical retention as well as high dosage giving increased wet strength without impairing the sheet uniformity. To engineer processes utilizing this new technology, the complex flow behavior of applied foams must be quantified. At the minimum, the foam viscosity and the slip velocity at the solid surfaces need to be known to build practical models that can be used in analyzing and upscaling unit processes of the foam-assisted application.In this study, the rheological behavior was quantified for foams having polyvinyl alcohol (PVOH), a widely used strength additive chemical, as the surfactant. The foam density was varied between 100 g/L and 300 g/L, and the concentration of the PVOH solution was varied between 0.5% and 6.0% (w/w). The foams were generated with a commercial foam generator, and the rheological properties of the foams were measured by using a horizontal pipe bank. At the outlet from the generator, the volumetric flow rate, the absolute pressure, and the bubble size distribution of the foam were measured. In the measurement pipe section, the viscous pressure gradient and the slip velocity were measured, after which the foam was discharged to ambient air pressure. The viscosity and the dynamic surface tension of the PVOH solutions were quantified with commercial laboratory devices. In the viscosity analysis, the apparent shear rate was calculated from the volumetric flow rate, and the resulting apparent viscosity was translated to real material viscosity data by applying the Weissenberg-Rabinowitsch correction. The results indicated that PVOH foams can be described with high accuracy as shear-thinning power-law fluids where the detailed behavior depends on the foam density and the PVOH concentration. Slip flow, as usual, increased with increasing wall shear stress, but it was also dependent on the PVOH concentration, the air content, and the bubble size. For both the foam viscosity and the slip flow, a correlation was found that described the quantitative behavior of all the studied foams with good accuracy.
Journal articles
Magazine articles
Value creation by converting pulp mill flue gas streams to green fuels, TAPPI Journal March 2023
ABSTRACT: Climate change mitigation induces strong growth in renewable electricity production, partly driven by shifts in environmental policies and regulation. Intermittent renewable electricity requires supporting systems in the form of sustainable hydrocarbon chemicals such as transportation fuels. Bulk chemical production fits well into a pulp mill environment, given their large volumes, stable operation, and ample supply of biomass-based carbon feed-stock in the form of flue gases. Until now, the utilization of the flue gases from conventional operation of a pulp mill has received little attention. Harnessing these flue gases into usable products could offer additional value to mill operators, while also diversifying their product portfolio. However, electricity-based fuels and products require extra energy in the conversion step and may not be commercially competitive with current fossil products under the current regulation. There might also be uncertainties about future commodity prices. Thus, the objective of this study is to estimate the economic competitiveness and the added value of selected side products that could be produced alongside conventional pulp and paper products. A typical modern pulp mill is modeled in different product configurations and operational environments, which allows testing of various development paths. This illustrates how the overall energy and mass balance of a pulp mill would react to changes in different final products and other parameters. The focus of the study is in synthetic methanol, which is produced from flue gases and excess resources from the mill, with minimal interference to the pulping process. The results aid in assessing the necessity and magnitude of a premium payment for subsidizing green alter-natives to replace current fossil fuels and chemicals. Additionally, the results function as an indicator of the development state of the pulp and paper industry in the turmoil of climate change regulation. The results indicate that power-to-X systems offer one more viable pathway alternative for broadening the product portfolio of the pulp and paper sector, as well as opening new flexibility measures and services to grid stabilization. Market conditions were found to have a significant impact on the perceived profitability.
Journal articles
Magazine articles
The use of minerals in fiber-based packaging and pulp molding, TAPPI Journal January 2024
ABSTRACT: Minerals are widely used in the pulp and paper industry for aiding the processing, economics, and final quality of fiber-based products. Among these, calcium carbonate, talc, and kaolin are widely used as fillers, and these can have varying brightness, particle size distributions, and aspect ratios. For the molded fiber area, these minerals can raise the solids content of the pulp mixture and improve throughput and lower energy requirements for drying. Talc is also widely used as a process control agent, picking up pitch and stickies and improving productivity by lowering machine cleaning time.The replacement of single use plastic with fiber-based replacements is a global trend; however, it does come with some significant challenges, such as grease and moisture proofing. Previously, per- and polyfluoroalkyl substances (PFAS) have been used to provide functions such as water and grease repellency, but regulatory demands have seen its demise in the packaging industry. Therefore, water holdout is now generally achieved by addition of alkyl ketene dimer (AKD) sizing. Wax additives are being developed and tested as PFAS replacements for oil and grease resistance. Rather than strongly repelling lipids from the fiber surface, these PFAS alternatives restrict flow pathways and react with food oils to alter their flow characteristics to prevent penetration through the substrate. During studies incorporating both PFAS substitutes and minerals, no detrimental interactions were observed. This paper addresses the different needs of the molded fiber market by including mineral fillers in molded fiber articles and will be presented as a series of different case studies. In all studies, we show that the trends observed when mineral filler is added to molded fiber are broadly similar to those seen in conventional paper and paperboard applications. Mineral addition in all studies gave improvements in productivity and optical appearance. With its organophilic surface, hydrophobic talc had the additional advantage of pitch and sticky control, and although a small decrease in strength was always observed when filler was added, the final articles still retained sufficient strength for their particular application. This small strength reduction should be balanced against the productivity gains.
Journal articles
Magazine articles
Comparative study of guar gum and its cationic derivatives as pre-flocculating polymers for PCC fillers in papermaking applications, TAPPI Journal April 2022
ABSTRACT: In this work, gums from guar seeds were evaluated as a potential precipitated calcium carbonate (PCC) filler pre-flocculant to induce functional filler in papermaking applications. In recent years, guar has been conidered one of the promising wet-end additives due to its abundance, rich source of hemicellulose content, and bio-degradability. However, application of guar gum in filler pretreatment methods for producing high ash paper has scarcely been reported. In this paper, the flocculating ability of three types of guar gum was established with charge analysis and turbidity (NTU) of the system at 1% and 5% for each gum: native gum (NG) having a degree of substitution (DS) of 0, and cationic gums having a DS value of 0.07 (CL) and 0.15 (CH). It was interesting to observe that even at a 5% dose of G, the charge density of PCC did not deviate much from the initial values. The system carried a weak negativeharge, resulting in an unstable colloidal suspension that led to PCC-PCC particle bridging. On the other hand, the operative mechanism of CL and CH during adsorption and PCC flocculation was predicted to be charge neutralization and electrostatic-patch formation, accompanied by particle bridging. Note that CL, with a maximum 47.5% eduction in residual turbidity of PCC at a 1% dose, was much more efficient in doing so than the other two gums; NG had a 40% maximum reduction in residual turbidity at a 5% dose and CH had a maximum 30% reduction at a 1% ose. Later on, floc formation and structure were correlated with optical and field emission scanning electron microscopy (FE-SEM) images. In the next set of trials, paper properties were determined by varying the different gum dosages from 0.2% to 5% at a constant dose of 20% filler. It is also noteworthy to mention that with 1% CL (low DS) dose, PCC retention increased by 39%, which also enhanced the tensile, tear, burst, and opacity properties by 11%, 19%, 5%, and 4.4%, respectively, without significantly affecting the bulk properties. Further, wide-angle X-ray diffraction (XRD) analysis nd Fourier transform infrared (FTIR) analysis revealed that pre-flocculating PCC with a 1% gum dose did not induce any change in crystalline transformation. Based on observation, it was found that cationic gums with low DS values re a better choice for maximizing the strength of paper while maintaining bulk and high opacity when pre-flocculaion is adopted to increase the filler retention in paper.
Journal articles
Magazine articles
Application of ATR-IR measurements to predict the deinking efficiency of UV-cured inks, TAPPI Journal January 2022
ABSTRACT: In recent years, ultraviolet (UV)-curable ink has been developed and widely used in various printing applications. However, using UV-printed products (UV prints) in recovered paper recycling causes end-product dirt specks and quality issues. A new method was developed that can distinguish UV prints from other prints by means of attenuated total reflectance infrared (ATR-IR) spectroscopy. Application of this method could allow more efficient use of UV prints as raw materials for paper recycling.First, a mill trial was performed using UV prints alone as raw materials in a deinked pulp (DIP) process. Second, test prints were made with four types of UV inks: a conventional UV ink and three different highly-sensitive UV inks. Each print sample had four levels of four-color ink coverage patterns (100%, 75%, 50%, and 25%). Next, deinkability of all prints was evaluated by laboratory experiments. Finally, each print was measured using the ATR-IR method, and the relationship between the IR spectra and deinkability was investigated. Mill trial results showed that UV prints caused more than 20 times as many dirt specks as those printed with conventional oil-based ink. There were variations in recycling performance among UV prints taken from bales used for the mill trial. Lab tests clearly revealed that not all UV-printed products lead to dirt specks. In order to clarify the factors that affected deinkability of UV prints, the print samples were investigated by lab experiments. Key findings from lab experiments include: œ The number of dirt specks larger than 250 µm in diameter increased as the ink coverage increased. œ Higher ink coverage area showed stronger intensity of ATR-IR spectral bands associated with inks. These results indicate that deinkability of UV prints could be predicted by analysis of ATR-IR spectra. œ Finally, the method was applied for assessment of recovered paper from commercial printing presses. It was confirmed that this method made it possible to distinguish easily deinkable UV prints from other UV prints. Based on these findings, we concluded that the ATR-IR method is applicable for inspection of incoming recovered paper.