Search
Use the search bar or filters below to find any TAPPI product or publication.
Filters
Content Type
Publications
Level of Knowledge
Committees
Collections
Journal articles
Magazine articles
Investigation of the influencing factors in odor emission from wet-end white water, TAPPI Journal October 2020
ABSTRACT: Emission of malodorous gases, such as volatile organic compounds (VOCs), hydrogen sulfide (H2S), and ammonia (NH3) during pulping and papermaking has caused certain harm to the air environment and human health. This paper investigated the influencing factors of odor emission from wet-end white water during the production of bobbin paper in a papermaking mill using old corrugated containers (OCC) as raw material. The concentration of malodorous gases emitted from wet-end white water was determined with pump-suction gas detectors. The results indicated that low temperature could limit the release of malodorous gases from white water. Specifically, no total volatile organic compounds (TVOC), H2S, and NH3 was detected at a temperature of 15°C. The concentrations of malodorous gases were slightly increased when temperature increased to 25°C. When temperature was 55°C, the released concentrations of TVOC, H2S, and NH3 were 22.3 mg/m3, 5.91 mg/m3, and 2.78 mg/m3, respectively. Therefore, the content of malodorous gases significantly increased with the temperature increase. The stirring of white water accelerated the release of malodorous gases, and the release rate sped up as the stirring speed increased. However, the total amount of malodorous gases released were basically the same as the static state. Furthermore, the higher the concentration of white water, the greater the amount of malodorous gases released. The pH had little influence on the TVOC release, whereas it significantly affected the release of H2S and NH3. With the increase of pH value, the released amount of H2S and NH3 gradually decreased. When pH reached 9.0, the release amount of H2S and NH3 was almost zero, proving that an alkaline condition inhibits the release of H2S and NH3.
Journal articles
Magazine articles
Lignin-based resins for kraft paper applications, TAPPI Journal November 2019
ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.
Journal articles
Magazine articles
Fundamental molecular characterization and comparison of the O, D0, and E stage effluents from hardwood pulp bleaching, TAPPI Journal 2019
ABSTRACT: The present study characterized effluents from the O, D0, and E stages using nuclear magnetic reso-nance (NMR) and gel permeation chromatography (GPC) techniques to better understand the chemical nature of the dissolved organics formed from the bleaching of a high-yield hardwood kraft pulp. Understanding the structures and molecular weight distribution of these organics is the first step in developing methods to mitigate these contam-inates in the discharged effluents. The results indicated that the molecular weight distribution (MWD) of the dis-solved organics from oxygen delignification effluent is broader than those from D0 and E stage effluents. In addition, the O stage filtrate contained considerable amounts of lignin and xylan fragments, which showed its efficiency in removing such materials. The effluent from the D0 stage contained a lower amount of high molecular weight frag-ments and a higher amount of low molecular weight fragments versus the O-stage filtrate. Aromatic structures were nearly absent in the D0 stage filtrate, but the degraded organic material, presumably from oxidized lignin, contained olefinic (C=C) and carbonyl (C=O) functional groups. Furthermore, higher molecular weight fragments were detected in the E-stage effluent, presumably due to the extensive solubilization and removal of the oxidized lignin generated from the D0 pulp.
Journal articles
Magazine articles
Influence of tensile straining and fibril angle on the stiffness and strength of previously dried kraft pulp fibers, TAPPI JOURNAL July 2018
Influence of tensile straining and fibril angle on the stiffness and strength of previously dried kraft pulp fibers, TAPPI JOURNAL July 2018
Journal articles
Magazine articles
Using multistage models to evaluate how pulp washing after the first extraction stage impacts elemental chlorine-free bleach demand, TAPPI Journal November 2018
Using multistage models to evaluate how pulp washing after the first extraction stage impacts elemental chlorine-free bleach demand, TAPPI Journal November 2018
Conference papers
Recent advances in the commercialization of NIR (near-infrar
ABSTRACT: Near-infrared (NIR) spectroscopy techniques have held the promise of a new generation of online and lab based process analyzers for the pulping and recovery areas for some years now. NIR technology has been shown to be a quite effective method for the analysis of white, green and black liquors by multiple investigators. NIR reflectance techniques have been shown to be effective in predicting yield and kappa number in pulp samples. Recently, commercial analyzers have been developed for green liquor analysis on the dissolving tank, white and green liquor analysis in the recaust area and black liquor analysis on batch and continuous digesters. These analyzers are currently running at different mill sites and are proving to be superior to current technology choices for these applications. A commercial online and lab based yield and kappa number analyzer are currently being developed based on NIR reflectance techniques. Results will be presented on the performance of these analyzers relating to accuracy, maintenance and total installed cost. Other potential NIR applications in the pulping and recovery area will also be addressed.
Journal articles
Magazine articles
Rethinking the paper cup — beginning with extrusion process optimization for compostability and recyclability, TAPPI Journal June 2021
ABSTRACT: More than 50 billion disposable paper cups used for cold and hot beverages are sold within the United States each year. Most of the cups are coated with a thin layer of plastic — low density polyethylene (LDPE) — to prevent leaking and staining. While the paper in these cups is both recyclable and compostable, the LDPE coat-ing is neither. In recycling a paper cup, the paper is separated from the plastic lining. The paper is sent to be recycled and the plastic lining is typically sent to landfill. In an industrial composting environment, the paper and lining can be composted together if the lining is made from compostable materials. Coating paper cups with a compostable performance material uniquely allows for used cups to be processed by either recycling or composting, thus creating multiple pathways for these products to flow through a circular economy.A segment of the paper converting industry frequently uses an extrusion grade of polylactic acid (PLA) for zero-waste venues and for municipalities with ordinances for local composting and food service items. The results among these early adopters reveal process inefficiencies that elevate manufacturing costs while increasing scrap and generally lowering output when using PLA for extrusion coating. NatureWorks and Sung An Machinery (SAM) North America researched the extrusion coating process utilizing the incumbent polymer (LDPE) and PLA. The trademarked Ingeo 1102 is a new, compostable, and bio-based PLA grade that is specifically designed for the extrusion coating process. The research team identified the optimum process parameters for new, dedicated PLA extrusion coating lines. The team also identified changes to existing LDPE extrusion lines that processors can make today to improve output.The key finding is that LDPE and PLA are significantly different polymers and that processing them on the same equipment without modification of systems and/or setpoints can be the root cause of inefficiencies. These polymers each have unique processing requirements with inverse responses. Fine tuning existing systems may improve over-all output for the biopolymer without capital investment, and this study showed an increase in line speed of 130% by making these adjustments. However, the researchers found that highest productivity can be achieved by specifying new systems for PLA. A line speed increase to more than 180% and a reduction in coat weight to 8.6 µm (10.6 g/m2 or 6.5 lb/3000 ft2) was achieved in this study. These results show that Ingeo 1102 could be used as a paper coating beyond cups.
Journal articles
Conversion of paper-grade pulp from rice straw into dissolving pulp, TAPPI Journal June 2025
ABSTRACT: About 1,165 million metric tons of rice straw is generated every year worldwide, which can be a good source for the circular bioeconomy. In this research paper, the paper-grade pulp from rice straw was converted to dissolving-grade pulp by fractionation in a biorefinery initiative. Rice straw was cooked at an optimum condition of 8% potassium hydroxide (KOH) charge for 120 min at 150°C and produced a pulp yield of 47.2% with a kappa number of 18.5. Subsequently, D0(EP)D1 bleaching was carried out for the produced pulp, and the brightness of the pulp reached to 82.4%. From the black liquor, 16.5% of the lignin and 11.9% of the hemicellulose were isolated for producing biobased products and chemicals, and then the spent liquor was used for soil amendment. The bleached pulp was fractionated in a Bauer McNett fiber classifier. The pulp fibers retained on 16-, 30-, and 50-mesh screens were used as a longer fiber fraction pulp, and pulp fibers retained on 100- and 200-mesh screens were used as a shorter fiber pulp. The longer and shorter fiber fraction pulps were analyzed for cellulose, R10, pentosan, and viscosity. The long fiber fraction pulps were characterized by higher cellulose (88.2% vs. 83.1%) and lower pentosan (11.3% vs. 13.0%) content than the shorter fiber fraction pulps. The longer fiber fraction was further treated with cold KOH to remove residual hemicellulose. The KOH extraction reduced pentosan content in pulp to 6.3% and increased á-cellulose content to 91.3%. The short fiber fraction was converted to monomeric sugars using cellulase enzymes with varying reaction time, temperature, and consistency. The efficiency of cellulase activity was assessed through glucose yield and residual dry weight. A temperature of 45°C, 5.0 pH, 5% consistency, and 6 filter paper units/gram (FPU/g) o.d. pulp resulted in maximum sugar conversion of 85.7%.
Journal articles
Optimization of optical coverage of board surfaces with assessment of light scattering and absorption using mineral as a coating component, TAPPI Journal June 2026
ABSTRACT: One of the primary functions of mineral inclusion into paper or paperboard is to improve the optical performance of the substrate. A coating may be applied to a sheet in order to cover a dark base, to improve the sheet opacity, to give the correct smoothness and gloss, or to give a suitable surface on which to print. The brightness of a pigment has long been used as a guide for pigment choice in paper and board. However, the measured paper brightness is a function of color and light absorption (K) of the coating and base and the light scattering (S) within the sheet resulting from interfaces with different refractive index. The optical performance can be quantified by measuring the S&K coefficients as described by the Kubelka-Munk model/theory in a filled or coated paper sheet. In coating, this is often assessed as a function of coat weight, and the corresponding physical sheet properties are assessed at the same time; for example, the correct gloss, smoothness, point-to-point uniformity, and printability. The optical performance in the sheet is often not directly related to the pigment brightness, but is largely a function of the particle packing within the sheet and coating layer. In the first and second main sections of this work, respectively, we show how S&K calculations from the Kubelka- Munk equations can be used in coated sheets to determine the optical performance and how this can be used as a predictive tool for the final sheet performance. This is presented for base sheets with different starting brightness. The third section of this work focuses on how mineral combinations in coatings can be used to improve the light scattering and consequently the optical performance of the board. We include theoretical considerations and then finally share a case study for improvement on the optical properties of recycled board.
Journal articles
Data driven modeling to reduce fossil fuel consumption in a lime kiln integrated with biomass gasifier, TAPPI Journal September 2026
ABSTRACT: Biomass gasification, although already known and applied, is currently being consolidated as a sustainable alternative in the pulp industry, contributing to the reduction of fossil carbon dioxide (CO2) emissions and to the utilization of forest residues. In this context, pulp mills are beginning to adopt biomass gasification within their chemical recovery cycles by integrating the technology with lime kilns. However, further process studies are still needed to support and optimize this application. Thus, the present study aimed to analyze lime mud feed temperature by applying an artificial neural network model to a gasification system integrated with a lime kiln. For this evaluation, 10 periods of system stability throughout 2024 were selected under different operational conditions. Data from 28 potential predictive variables were collected, a total of 348 observations. This dataset was then processed using R software, where data treatment and model dimensionality reduction were performed, resulting in 10 predictive variables between gasifier and kiln. Next, the dataset was randomly divided into training (70% of the observations) and testing data. The established neural network model (using “neuralnet” package) was optimized, resulting in a configuration containing one hidden layer with three neurons. This setup enabled optimal estimation of the flue gas kiln outlet temperature, with mean absolute error (MAE) = 3.0°C and root mean square error (RMSE) = 4.1°C, applying the resilient backpropagation algorithm with backtracking — both below the thermocouple’s measurement error (±5.0°C) for the evaluated average temperature range (668.2°C). When the same dataset was modeled using the resilient backpropagation algorithm without backtracking, even better results were achieved: MAE = 2.5°C and RMSE = 3.7°C. Thus, after evaluating these and other configurations, it was concluded that the best model required 10 predictive variables and the backpropagation algorithm without backtracking to determine flue gas kiln outlet temperature. These results provide a better understanding of how gasifier and kiln variables influence the temperature in the lime kiln, which is essential to improve control and optimize the calcination process, avoiding supplementary fossil fuel consumption.