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Enhancing tissue wet pressing performance and dry end material efficiency for cost savings, TAPPI Journal May 2024

ABSTRACT: The steadily growing global tissue paper demand lays a foundation for new technologies targeting tissue production optimization, as well as improved material and time efficiency. Tissue making is an especially energy-intensive field of paper industry, creating unique demands for performance in wet pressing and drying processes to cut energy usage. Intelligent roll solutions offer new tools for tissue making to achieve these goals. These tools aim at improving press nip, moisture, and tension profiles; reeling nip and parent roll hardness profiles; rewinder runnability; and end product web handling characteristics in converting. Intelligent rolls can be utilized in all the main processes and positions on tissue production lines. With these tools, production cost reductions and energy savings can be obtained by optimizing the press nip-to-Yankee cylinder contact, avoiding moisture profile errors requiring overdrying with the Yankee hood and reducing reeling/winding broke under low nip load conditions typical to tissue windups. The intelligent roll system consists of a helically mounted force or temperature sensors, roll covers, measurement electronics, digital radio transmission, and a receiver system connected to a user interface or the mill automation system. What distinguishes these implementations is that no layout changes or added external measurement devices are required, helping to fit into compact tissue machine environments, regardless of the equipment type • traditional, hybrid, or through-air drying (TAD) concept. In tissue processing equipment, the optimal positions for these rolls are press nip rollers, reeling cylinders, rewinder or converting line paper lead rolls, or rewinder winding drums. In addition to these, temperature profile measurements are utilized, with the main application being the sheet temperature profile detection after Yankee drying for moisture profile and drying process optimization.

In-situ green synthesis and adsorption on methylene blue of copper-based metal organic framework/cellulose/chitosan (CCTSA/HKUST-1) composite aerogel, TAPPI Journal October 2024

ABSTRACT: In order to explore the application of metal-organic frameworks (MOFs) in environmental and water treatment fields, a new composite aerogel of HKUST-1/cellulose/chitosan (CCTSA/HKUST-1) with better hydrostability was synthesized by an in-situ synthesis method combining covalent cross-linking and solvothermal methods as an efficient adsorbent for methylene blue (MB). The composite aerogel (CCTSA) obtained by covalent cross-linking of cellulose (CE) and chitosan (CTS) exhibited excellent stability under strong acid and solvent-thermal conditions. With the increase of CTS content, it was beneficial to the in-situ synthesis of HKUST-1, as well as to increase the mass loading rate of HKUST-1 to 37.06%, while the Brunauer-Emmett-Teller (BET) specific surface area of CCTSA/HKUST-1 composite aerogel reached 945.123 m2·g-1, which was much higher than that of the CCTSA composite aerogel (14.489 m2·g-1). The CCTSA/ HKUST-1 composite aerogel exhibited excellent adsorption capacity (537.6 mg·g-1) on MB solution, and cyclic adsorption could be achieved. This study proposes a concept of valorization of alkaline peroxide mechanical pulping (APMP) waste liquor to hemicellulose-based hydrogel. This hemicellulose-based hydrogel exhibits a sensitive temperature/pH dual response. Hemicellulose-based hydrogels swell or shrink through the change of hydrogen bond/electrostatic repulsion/charge screening. They also show good water absorption and water retention properties.

CFD and predictive modeling of temperature and calcination in a rotary lime kiln • Potential for steadier kiln operation, TAPPI Journal October 2024

ABSTRACT: Rotary lime kilns are used in the pulp and paper industry to calcine lime mud to lime. Lime kiln models provide a means to understand the complex phenomena occurring within the kiln to aid in problem-solving during operation. A two-dimensional (2D) computational fluid dynamics (CFD) and one-dimensional (1D) bed model was previously developed for steady-state and transient analysis. This study explores data extracted from the model over a longer time period. The simulated outlet gas and shell temperature are compared to measured data for validation. The capability of using the model to estimate the production rate, accounting for the residence time within the kiln, is discussed. The maximum refractory wall temperature is analyzed during operation. Fluctuations in the calcination location are compared to outer shell heat-map data to correlate the calcination location and ring formation and growth. The model results to date indicate that fluctuations in the calcination zone may contribute to problematic ring growth, though a direct correlation has yet to be established. Additionally, a method for steadier kiln control is introduced and discussed. A machine learning model is also developed to predict the calcination start location from industrial data and is compared to the CFD model for validation. This model can generate results quickly and without the need for knowledge in CFD software and theory. Good agreement is found between the CFD and machine learning model during operation, with a mean absolute error (MAE) of 0.46 m, a mean absolute percentage error (MAPE) of 0.92%, and a root mean square error (RMSE) of 1.17 m.

Biofuels in lime kilns • Operating experience in the Nordic pulp and paper industry, TAPPI Journal October 2024

ABSTRACT: The lime reburning process is a central part of the chemical pulp mill. It is energy intensive and consumes large amounts of fossil fuel, globally consuming about 50 terawatt-hours (TWh) of fuel per year. Conversion to operation with biofuel is interesting, both to reduce carbon dioxide emissions and to reduce costs. Researchers interviewed managers in mills that use solid, liquid, or gasified biofuels to replace fuel oil or natural gas in their lime kilns, and they conducted surveys related to fuel consumption and operations and maintenance. In Sweden and Finland, there were ten mills in 2020 using biomass powder or gasified biomass as the primary fuel, and two more installations were under construction. There were also nine installations in operation or under construction outside the Nordic countries. Fourteen mills in Sweden and two mills in Finland used tall oil pitch as the main fuel. Fuel consumption in Swedish lime kilns was 3.8 TWh in 2020, and 90% of this energy was supplied with biofuels. Of about 4.2 TWh used in Finnish lime kilns, approximately 45% was supplied with biofuels. Developments in the design of the fuel supply system include belt dryers being used in all new installations and mass flow metered dosing systems being used in most new pulverized fuel installations. Bark gasifiers have increased considerably in size. Lignin powder firing has been established as a proven option. A solution for many Swedish and Finnish mills is the use of tall oil pitch as a replacement for fuel oil.

Model development for real oxygen delignification processes, TAPPI Journal October 2024

ABSTRACT: Previous extensive work has been done on modeling the oxygen delignification process, based on how the basic parameters, i.e., temperature, kappa number, concentration of alkali, and concentration of oxygen, affect the delignification rate. However, these models are not used extensively to evaluate the performance of real processes, primarily because they have not been able to properly consider all the essential issues affecting delignification in practice. Such issues include the mass transfer and consumption of oxygen, which defines the concentration of dissolved oxygen in the process, and the effect of that concentration on the delignification rate. In this paper, a new way to model the oxygen delignification process is used in which these parameters, among other smaller matters, are taken into account. The basic model and its parameters were defined by the information obtained from the literature, delignification made in the laboratory tests, and mill processes and mill tests. An essential aspect of these studies was the information obtained from the oxygen concentration measured in the residual gas obtained from the top of the reactor. With the aid of this measurement, it was possible to define more accurately the consumption of oxygen and partial pressure of oxygen that define the concentration of dissolved oxygen in the reactor. Using mill experiments, a model was formed that predicts the operation of the oxygen delignification process. The model was used to show how much the process could be improved by optimizing the charge of the oxygen. The mill experiments also confirmed that mass transfer of oxygen is modeled correctly enough, except when the charge of oxygen is very low and/or the mixing is not efficient enough. In that case, there is variation in the concentration of oxygen in the process that should be taken into account in the modeling.

Colloid chemical aspects of paper formation in the presence of nanofibrillated cellulose and cationic starch, TAPPI Journal September 2024

ABSTRACT: A series of experimental tests were carried out to examine colloidal-scale consequences of optionally treating nanofibrillated cellulose (NFC) with cationic starches of different charge density and dosage (0.5% or 2.0% by weight), adding that material to a furnish prepared from 100% recycled copy paper, and then subjecting the mixture to very different levels of hydrodynamic shear. Tests included optical microscopy, sediment volume tests, sediment velocity tests, and “percent fines” assessment by means of a fiber quality analyzer (FQA). In addition, the zeta potential and charge demand of the studied materials were evaluated. Optical imaging revealed that cationic starch treatment of the NFC tended to agglomerate it into multiparticle clusters, which sometimes could be mostly redispersed by hydrodynamic shear. Subsequent addition of the starch-treated NFC to the default furnish resulted in much of the colloidal material becoming attached to fibers. Subsequent shearing of the mixtures was at least partly effective in separating the clusters of NFC from the fiber surface, resulting in essentially a two-component mixture. Multiparticle NFC clusters coexisted with the fiber suspension, sometimes attached and sometimes not, depending on the details of treatments. Sediment volume tests showed that systems containing cationic starch-treated NFC tended to have a higher density after settling in comparison to untreated NFC; these findings are consistent with the cationic starch acting as a stabilizer on the solid surfaces, allowing them to slide past each other during the settling process. Application of intense hydrodynamic shear tended to result in denser sediment. Results of tests with the sediment velocity messurement and the FQA percent fines assessment did not correlate well with changes in test conditions considered in this study.

THE IMPACT OF DISPERSION BARRIER COATINGS ON WATER QUALITY AFTER RECYCLING, TAPPICon 2023

Pigment loading level effects on water barrier properties in barrier coating formulations, TAPPICon25

Alternative disposal methods for pulp mill biosludge

ABSTRACT: The chemical pulp production process produces notable amounts of biosludge, mostly in the wastewater treatment system. Biosludge is a problematic waste stream due to its properties, and recently, its amounts have been on the increase. The most used disposal processes are incineration in a bark boiler or a recovery boiler now that landfilling is no longer permitted by legislation in many countries. Incineration of wet sludges with poor drying characteristics decreases the energy efficiency of the process. Biosludge is typically mixed with black liquor in the evaporation plant before feeding to the recovery boiler. Although the recovery boiler is designed to handle challenging fuels, biosludge disposal requires consideration of its behavior during evaporation and accumulation of non-process elements in the recovery cycle. This study discusses the currently used sludge handling methods and presents two novel methods, hydrothermal carbonization and anaerobic digestion, to convert sludge into a usable form. Production of hydrochar or biogas offers new usage possibilities for biosludge and improves the energy efficiency of the mill when the new methods replace incineration. The processes are still developing, and thus their economic feasibility is uncertain; however, depending on the case details, they can be considered promising alternatives to be implemented in the future.

Formic acid pulping process of rice straw for manufacturing of cellulosic fibers with silica, TAPPI Journal August 2021

ABSTRACT: Emerging technology has the potential to develop entirely new approaches for producing cellulose fiber-based materials along with fuels and chemical raw materials like lignin and furfural. Rice straw is a rich source of cellulosic fibers and inorganic micronic-sized particles termed as ash. They can prove helpful in development of new or enhanced agricultural residue-based materials and products that offer cost effective substitutes for nonrenewable materials used in different domestic and industrial applications. Lignocellulose is an abundant material that is submicronic at the basic level. Rice straw is a fibrous lignocellulosic material obtained as agricultural residue, but it differs from most crop residues in its high content of silicon dioxide (SiO2). Ash content on a dry weight basis ranges from 13% to 20%, varying according to the state of conservation of the straw after harvest. The ash in rice straw has nearly 75% SiO2. The particle size analysis shows variation from a few microns to hundreds of microns for inorganic residues left after burning at high temperatures above 550°C. Proximate analysis of rice straw shows that it contains 54% to 56% holocellulose and 15% to 18% lignin, both of which are natural biopolymers. The compound analysis shows the different compounds present in rice straw ash.Rice straw is available in hundreds of million tons in India and other Asian countries, so suitable technologies are required to convert rice straw from a biomass waste to useful bioproducts like pulp, paper, and paperboard. This research paper is intended to obtain pulp with fibers having inherent silica present in it to give high opacity paper and better bonding between fibers.