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Surface energy considerations for offset printing of coated paper and paperboard, TAPPI Journal November 2023

ABSTRACT: Offset printing of coated paper involves the complex interactions of ink with a surface that is characterized by three major properties: roughness, porosity, and related pore network structure and surface chemistry (related to surface free energy [SFE]). The effects of porosity and roughness are relatively well understood and are documented in the literature, whereas the influence of surface chemistry is much less studied and therefore the focus of this paper. The key results shown include: i) Coating porosity has a negligible effect on SFE determination by contact angle using two fluids. ii) The chemistry of the latex polymer in the coating formulation dominates the influence on SFE compared to pigment, with any surface energy differences present in the pigment being almost completely masked by latex. iii) Wetting agent and corona treatment can impact water absorption rate and surface spreading of water, resulting in small differences in printability. Increasing the concentration of the surfactant on a coated surface indicates switching orientation of the surfactant molecules, giving a “step wise” printing result. When looking to improve offset printability by selection of different pigments, the variation in SFE is less important than variation in either surface roughness or porosity.

Paper Chemistry for New Markets: An Overview, November/December 2023 Paper360º

Paper Chemistry for New Markets: Vendor Perspective, November/December 2023 Paper360º

Want to be Successful? Implement Systems and Seize Opportunities, November/December 2023 Paper360º

Over the Wire, Paper360º September/October 2023

TAPPI Journal Summaries, Paper360º September/October 2023

TAPPI Journal Summaries, Paper360º September/October 2023

Forests in Your Pocket, Paper360º November/December 2021

Forests in Your Pocket, Paper360º November/December 2021

Getting Color ´In Line’, Paper360º November/December 2021

Getting Color ´In Line’, Paper360º November/December 2021

Leadership in Maintenance: Wastefulness, Paper360º November/December 2021

Leadership in Maintenance: Wastefulness, Paper360º November/December 2021

Tetraethyl orthosilicate-containing dispersion coating — water vapor and liquid water barrier properties, TAPPI Journal September 2021

ABSTRACT: An aqueous styrene-butadiene latex dispersion coating containing in-situ processed tetraethyl orthosilicate (TEOS) applied on paperboard demonstrated improved water barrier performance. Coatings containing TEOS equivalent to 0.8% silicon dioxide (SiO2; dry basis) exhibited water vapor performance of < 25 g/m2/day (23°C, 50% relative humidity [RH]) and liquid water barrier performance Cobb 1800 s of < 6 g/m2, when applied as a single-layer 18 g/m2 coating. Cobb 1800 s barrier performance was still good (< 11 g/m2) at coat weights of 7•10 g/m2. The use of filler materials such as kaolin improved the vapor barrier properties of the coating, but this was not critical to the liquid water barrier properties.