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Journal articles
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Open Access
Tetraethyl orthosilicate-containing dispersion coating — water vapor and liquid water barrier properties, TAPPI Journal September 2021

ABSTRACT: An aqueous styrene-butadiene latex dispersion coating containing in-situ processed tetraethyl orthosilicate (TEOS) applied on paperboard demonstrated improved water barrier performance. Coatings containing TEOS equivalent to 0.8% silicon dioxide (SiO2; dry basis) exhibited water vapor performance of < 25 g/m2/day (23°C, 50% relative humidity [RH]) and liquid water barrier performance Cobb 1800 s of < 6 g/m2, when applied as a single-layer 18 g/m2 coating. Cobb 1800 s barrier performance was still good (< 11 g/m2) at coat weights of 7•10 g/m2. The use of filler materials such as kaolin improved the vapor barrier properties of the coating, but this was not critical to the liquid water barrier properties.

Journal articles
Magazine articles
Open Access
Commercially relevant water vapor barrier properties of high amylose starch acetates: Fact or fiction?, TAPPI Journal September 2021

ABSTRACT: Starches have recently regained attention as ecofriendly barrier materials due to the increased demand for sustainable packaging. They are easily processable by conventional plastics processing equipment and have been utilized for oil and grease barrier applications. While starches have excellent oxygen barrier properties and decent water barrier properties at low relative humidity (RH), they are moisture sensitive, as demonstrated by the deterioration of the barrier properties at higher RH values. Starch esters are chemically modified starches where the hydroxyl group of the starch has been substituted by other moieties such as acetates. This imparts hydrophobicity to starches and has been claimed as a good way of retaining water vapor barrier properties of starches, even at high RH conditions. We studied the water vapor barrier properties of one class of starch esters, i.e., high amylose starch acetates that were assumed to have good water vapor barrier properties. Our investigations found that with a high degree of substitution of hydroxyl groups, the modified starches did indeed show improvements in water vapor response as compared to pure high amylose starch films; however, the barrier properties were orders of magnitude lower than commercially used water vapor barriers like polyethylene. Even though these materials had improved water vapor barrier response, high amylose starch acetates are likely unsuitable as water vapor barriers by themselves, as implied by previous literature studies and patents.

Magazine articles
Open Access
A guide to developing a best management practices (bmp) plan for spent liquor, part II, TAPPI JOURNAL, December 1999, Vol. 82(12)

A guide to developing a best management practices (bmp) plan for spent liquor, part II, TAPPI JOURNAL, December 1999, Vol. 82(12)

Magazine articles
Open Access
Photographic life-prediction matrix for forming fabrics, TAPPI JOURNAL, November 1997, Vol. 80(11)

Photographic life-prediction matrix for forming fabrics, TAPPI JOURNAL, November 1997, Vol. 80(11)

Magazine articles
Open Access
Recycling 'low value' post-consumer fibers to improve quality and reduce costs, TAPPI JOURNAL, September 1997, Vol. 80(9)

Recycling 'low value' post-consumer fibers to improve quality and reduce costs, TAPPI JOURNAL, September 1997, Vol. 80(9)

Magazine articles
Open Access
English as a first and second language - part 7: a strategy for spelling, TAPPI JOURNAL, October 1998, Vol.81(10)

English as a first and second language - part 7: a strategy for spelling, TAPPI JOURNAL, October 1998, Vol.81(10)

Magazine articles
Open Access
The industry: beyond 2000, TAPPI JOURNAL, October 1998, Vol.81(10)

The industry: beyond 2000, TAPPI JOURNAL, October 1998, Vol.81(10)

Magazine articles
Open Access
Indonesian update: a country in change, an industry in recovery, TAPPI JOURNAL, September 1998, Vol. 81(9)

Indonesian update: a country in change, an industry in recovery, TAPPI JOURNAL, September 1998, Vol. 81(9)

Magazine articles
Open Access
An overview of the south african pulp and paper industry, TAPPI JOURNAL, April 1999, Vol. 82(4)

An overview of the south african pulp and paper industry, TAPPI JOURNAL, April 1999, Vol. 82(4)

Magazine articles
Open Access
Retention aids for highspeed paper machines, TAPPI JOURNAL, April 1999, Vol. 82(4)

Retention aids for highspeed paper machines, TAPPI JOURNAL, April 1999, Vol. 82(4)

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