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Control of malodorous gases emission from wet-end white water with hydrogen peroxide, TAPPI Journal October 2021
ABSTRACT: White water is highly recycled in the papermaking process so that its quality is easily deteriorated, thus producing lots of malodorous gases that are extremely harmful to human health and the environment. In this paper, the effect of hydrogen peroxide (H2O2) on the control of malodorous gases released from white water was investigated. The results showed that the released amount of total volatile organic compounds (TVOC) decreased gradually with the increase of H2O2 dosage. Specifically, the TVOC emission reached the minimum as the H2O2 dosage was 1.5 mmol/L, and meanwhile, the hydrogen sulfide (H2S) and ammonia (NH3) were almost completely removed. It was also found that pH had little effect on the release of TVOC as H2O2 was added, but it evidently affect-ed the release of H2S and NH3. When the pH value of the white water was changed to 4.0 or 9.0, the emission of TVOC decreased slightly, while both H2S and NH3 were completely removed in both cases. The ferrous ions (Fe2+) and the copper ions (Cu2+) were found to promote the generation of hydroxyl radicals (HOœ) out of H2O2, enhancing its inhibition on the release of malodorous gases from white water. The Fe2+/H2O2 system and Cu2+/H2O2 system exhibited similar efficiency in inhibiting the TVOC releasing, whereas the Cu2+/H2O2 system showed better perfor-mance in removing H2S and NH3.
Journal articles
Magazine articles
Can carbon capture be a new revenue opportunity for the pulp and paper sector?, TAPPI Journal August 2021
ABSTRACT: Transition towards carbon neutrality will require application of negative carbon emission technologies (NETs). This creates a new opportunity for the industry in the near future. The pulp and paper industry already utilizes vast amounts of biomass and produces large amounts of biogenic carbon dioxide. The industry is well poised for the use of bioenergy with carbon capture and storage (BECCS), which is considered as one of the key NETs. If the captured carbon dioxide can be used to manufacture green fuels to replace fossil ones, then this will generate a huge additional market where pulp and paper mills are on the front line. The objective of this study is to evaluate future trends and policies affecting the pulp and paper industry and to describe how a carbon neutral or carbon negative pulp and paper production process can be viable. Such policies include, as examples, price of carbon dioxide allowances or support for green fuel production and BECCS implementation. It is known that profitability differs depending on mill type, performance, energy efficiency, or carbon dioxide intensity. The results give fresh understanding on the potential for investing in negative emission technologies. Carbon capture or green fuel production can be economical with an emission trade system, depending on electricity price, green fuel price, negative emission credit, and a mill’s emission profile. However, feasibility does not seem to evidently correlate with the performance, technical age, or the measured efficiency of the mill.
Journal articles
Qualification of Welding Procedures for Duplex Stainless Ste
Qualification of Welding Procedures for Duplex Stainless Steels, 1999 Engineering Conference Proceedings
Journal articles
Pulping and Papermaking Properties of Managed Second-Growth
Pulping and Papermaking Properties of Managed Second-Growth Softwoods, 1995 Pulping Conference Proceedings
Journal articles
Influence of oxidation and cationization on the properties of thermomechanical pulp fibers, TAPPI JOURNAL October 2010
Influence of oxidation and cationization on the properties of thermomechanical pulp fibers, TAPPI JOURNAL October 2010
Journal articles
Characterization of spruce thermomechanical pulps at the fiber cell wall level: a method for quantitatively assessing pulp fiber development using Simonsâ?? stain, TAPPI JOURNAL October 2010
Characterization of spruce thermomechanical pulps at the fiber cell wall level: a method for quantitatively assessing pulp fiber development using Simons’ stain, TAPPI JOURNAL October 2010
Journal articles
3-D Computational Simulation of Paper Handsheet Structure and Prediction of Apparent Density, TAPPI JOURNAL September 2009
3-D Computational Simulation of Paper Handsheet Structure and Prediction of Apparent Density, TAPPI JOURNAL September 2009
Journal articles
Decreasing specific energy of thermomechanical pulps from reduction of raw materials variability, TAPPI JOURNAL September 2009
Decreasing specific energy of thermomechanical pulps from reduction of raw materials variability, TAPPI JOURNAL September 2009
Journal articles
Retention of PCC and GCC Fillers on Chemical Pulp Fines Surfaces, TAPPI JOURNAL September 2009
Retention of PCC and GCC Fillers on Chemical Pulp Fines Surfaces, TAPPI JOURNAL September 2009
Journal articles
Kraft pulping and papermaking properties of hot-water pre-extracted loblolly pine in an integrated forest products biorefinery, TAPPI JOURNAl, July 2008
Kraft pulping and papermaking properties of hot-water pre-extracted loblolly pine in an integrated forest products biorefinery, TAPPI JOURNAl, July 2008