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Journal articles
Magazine articles
Open Access
Impact of different calendering strategies on barrier coating pickup, TAPPI Journal November 2023

ABSTRACT: Paper was pre-calendered in a pilot scale configuration with a traditional soft nip calender and a metal belt calender. All calendering strategies reduced surface roughness and permeability of the samples, but different strategies affected the surface roughness and permeability differently. The metal belt calender seemed to have a larger effect on the large-scale variations compared to the soft nip calender. Six test points from the pilot calendered papers were chosen for laboratory coating studies. Uncalendered paper was included as reference samples. The calendered samples and the reference were pre-coated with a regular pigmented coating consisting of a ground calcium carbonate (GCC) pigment and a styrene acrylate (SA) latex. Both uncoated and pre-coated substrates were barrier coated with a polyvinyl alcohol (PVOH) in one and two layers. The coating pickup was determined gravimetrically, and the barrier properties were evaluated with TAPPI Standard Test Method T 454 grease resistance test. All samples needed two PVOH coating layers to form a grease barrier. The uncalendered sheets showed the best results with one coating layer, but this was at the expense of a higher coating pickup compared to the calendered sheets. The barrier coating pickup could be reduced by a combination of high temperature metal belt calendering and pre-coating. The high temperature and long residence time in the nip enabled plasticization of the fibers. This led to an irreversible deformation, even after water application. This meant that the smoothness obtained during calendering would be less affected by water-induced roughening during the coating operation.

Journal articles
Magazine articles
Open Access
Use of kaolin clay in aqueous barrier coating applications, TAPPI Journal November 2023

ABSTRACT: Paper-based packaging with barrier effect, as opposed to single use plastics, is gaining more prominence for sustainability reasons. At the same time, latex- or biopolymer-based aqueous barrier coating dispersions are increasingly being adopted as a better alternative to the traditional barrier coating materials, such as wax, surface active chemicals, and polyethylene. In this work, studies were performed to determine the influence of different kaolin clays in latex binder-based aqueous coatings on barrier properties, namely, oil and grease, water resistance, and water vapor transmission rate, by applying coatings to solid bleached sulfate (SBS) paperboard substrate in the laboratory. The aim was to explore potential benefits of using kaolin clay to replace some of the latex binder in coating and improve or maintain various types of barrier performance and blocking without negatively influencing the other performance attributes, including heat seal. The delaminated clay with the highest shape factor provided improved barrier properties over the clays of low shape factor. The ultrafine and non-delaminated clays required significantly higher coat weights to reach satisfactory barrier properties. Coatings with different latex levels indicated that a considerably high proportion of coarse delaminated clay can be incorporated to replace latex binder, while still achieving exceptional barrier properties. Furthermore, a change in binder system was found to significantly alter the barrier properties and the role that a mineral pigment can play. The results indicate that a proper selection of binder systems for each barrier property would be required while considering the clay/latex coating systems.

Journal articles
Magazine articles
Open Access
Kraft pulp viscosity as a predictor of paper strength: Its uses and abuses, TAPPI Journal October 2023

ABSTRACT: For bleached kraft pulps, two factors govern paper strength: the individual fiber strength, and the bond strength that adheres the individual fibers together in the paper matrix. Inherent fiber strength is related to the length of the carbohydrate polymers, also known as the degree of polymerization (DP). Average DP (DP) is inferred by performing pulp viscosity measurements. Under certain circumstances during kraft pulping and bleaching, the average polymer lengths can be shortened, resulting in lower pulp viscosity, and may indicate fiber damage. Fiber damage typically manifests itself as a reduction in tear strength for well-bonded handsheets.This paper will review the literature on how pulp viscosity can predict paper/fiber strength and how it can be used as a diagnostic tool. It can be a means to monitor pulp quality during pulping and bleaching, as well as to alert when such operations approach a critical threshold. However, viscosity losses must be carefully and judiciously analyzed. Like most diagnostic tools, viscosity measurements can be misused and abused, which can lead to incorrect inferences about intrinsic fiber strength. This review will also cover these misuses. The overall goal is to provide the papermaker a better understanding of what pulp viscosity is, how it correlates to potential sheet strength, and what its limitations are. It will be illustrated that when pulp viscosity drops below a critical value, it will indicate an appreciable deterioration in the paper’s tear and tensile strength.

Journal articles
Magazine articles
Open Access
Ultrastructural Behavior of Cell Wall Polysaxxharides, TAPPI Journal April 2022

ABSTRACT: Considerable information on the ultrastructural organization of the plant cell wall and the supermolecular arragement of the cell wall components, in particular of cellulose, has been obtained with the electron microscope.

Journal articles
Magazine articles
Open Access
The chemistry of aluminu salts in papermaking, TAPPI Journal April 2022

ABSTRACT: Alum and related aluminum salts are used exxtensively in a variety of papermaking operations. The versatility of these aluminum additives stems from the ability of the various aluinum species to adsorb and interact with the other materials in the papermaking system.

Journal articles
Magazine articles
Open Access
Furnishing autohydrolyzed poplar weakly alkaline P-RC APMP to make lightweight coated base paper, TAPPI Journal February 2022

ABSTRACT: This work investigated the effects of autohydrolysis pretreatment severity on poplar (Populus tomentosa Carr.) woodchips used to make a type of high-yield pulp (HYP) known as preconditioning followed by refiner chemical treatment, alkaline peroxide mechanical pulp (P-RC APMP). It also investigated the ratios for partially replacing sodium hydroxide (NaOH) with magnesium oxide (MgO) in the high-consistency (HC) retention stage of the P-RC APMP process on the obtained HYP’s properties. The results show that the pretreatment severity of autohydrolysis at combined hydrolysis factor (CHF) = 10.77 and the 50 wt% ratio for partially substituting NaOH with MgO were the optimum conditions for making light-weight coated (LWC) base paper. Compared to the conventional P-RC APMP, the optimized P-RC APMP had similar bulk and higher tensile, burst, and tear indices, as well as opacity, but a slightly lower ISO brightness. When the optimized P-RC APMP and commercial softwood bleached sulfate pulp (SBKP) were blended to make LWC base paper, the most favorable pulp furnish was comprised of 50% optimized P-RC APMP and 50% commercial SBKP. The obtained LWC base paper handsheet had better bulk, and its other properties could also meet the require-ments of LWC base paper.

Journal articles
Magazine articles
Open Access
Black liquor evaporators upgrade — How many effects?, TAPPI Journal April 2023

ABSTRACT: Black liquor evaporation is generally the most energy intensive unit operation in a pulp and paper manufacturing facility. The black liquor evaporators can represent a third or more of the total mill steam usage, followed by the paper machine and digester. When considering an evaporator rebuild or a new system, the key design question is how many effects to include in the system. The number of effects is the main design feature that deter-mines the economy of the system and the steam usage for a given evaporation capacity. A higher number of effects increases steam economy and reduces energy cost to a point, but additional effects also have higher initial capital cost and increased power costs. This research paper uses life-cycle cost analysis (LCCA) as a method to determine the optimum number of evaporator effects for a new evaporator system. The same basic principles and method can also apply to existing evaporator rebuild projects.

Journal articles
Open Access
A comparison of five optical surface topography measurement methods 15-Jan-27

A comparison of five optical surface topography measurement methods, TAPPI JOURNAL January 2015

Journal articles
Open Access
Upgrading aeration system performance in secondary basins treating pulp and paper wastewater: A review, TAPPI JOURNAL June 2015

Upgrading aeration system performance in secondary basins treating pulp and paper wastewater: A review, TAPPI JOURNAL June 2015

Journal articles
Open Access
Facile preparation of nanofiller-paper using mixed office paper without deinking, TAPPI JOURNAL 2015 March - 15MAR167

Facile preparation of nanofiller-paper using mixed office paper without deinking, TAPPI JOURNAL March 2015