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Magazine articles
Open Access
Imagine more in coatings, TAPPI JOURNAL, May 2000, Vol. 83(5)

Imagine more in coatings, TAPPI JOURNAL, May 2000, Vol. 83(5)

Magazine articles
Open Access
Suppliers investing in pilot coater facilities, TAPPI JOURNAL, May 2000, Vol. 83(5)

Suppliers investing in pilot coater facilities, TAPPI JOURNAL, May 2000, Vol. 83(5)

Magazine articles
Open Access
Improving dryer performance, TAPPI JOURNAL, May 2000, Vol. 83(5)

Improving dryer performance, TAPPI JOURNAL, May 2000, Vol. 83(5)

Magazine articles
Open Access
Pitfalls of trading market pulp on the internet, TAPPI JOURNAL, November 2000, Vol. 83(11)

Pitfalls of trading market pulp on the internet, TAPPI JOURNAL, November 2000, Vol. 83(11)

Magazine articles
Open Access
Paper companies adopt sophisticated techniques to win customers, TAPPI JOURNAL, October 2000, Vol. 83(10)

Paper companies adopt sophisticated techniques to win customers, TAPPI JOURNAL, October 2000, Vol. 83(10)

Magazine articles
Open Access
The role of science in setting the environmental agenda, TAPPI JOURNAL, September 2000, Vol. 83(9)

The role of science in setting the environmental agenda, TAPPI JOURNAL, September 2000, Vol. 83(9)

Magazine articles
Open Access
The r & t system: everyone is responsible for innovation, TAPPI JOURNAL, September 2000, Vol. 83(9)

The r & t system: everyone is responsible for innovation, TAPPI JOURNAL, September 2000, Vol. 83(9)

Magazine articles
Open Access
A financial analysis of north american pulp and paper companies, TAPPI JOURNAL, July 2000, Vol. 83(7)

A financial analysis of north american pulp and paper companies, TAPPI JOURNAL, July 2000, Vol. 83(7)

Journal articles
Magazine articles
Open Access
Comparative study of guar gum and its cationic derivatives as pre-flocculating polymers for PCC fillers in papermaking applications, TAPPI Journal April 2022

ABSTRACT: In this work, gums from guar seeds were evaluated as a potential precipitated calcium carbonate (PCC) filler pre-flocculant to induce functional filler in papermaking applications. In recent years, guar has been conidered one of the promising wet-end additives due to its abundance, rich source of hemicellulose content, and bio-degradability. However, application of guar gum in filler pretreatment methods for producing high ash paper has scarcely been reported. In this paper, the flocculating ability of three types of guar gum was established with charge analysis and turbidity (NTU) of the system at 1% and 5% for each gum: native gum (NG) having a degree of substitution (DS) of 0, and cationic gums having a DS value of 0.07 (CL) and 0.15 (CH). It was interesting to observe that even at a 5% dose of G, the charge density of PCC did not deviate much from the initial values. The system carried a weak negativeharge, resulting in an unstable colloidal suspension that led to PCC-PCC particle bridging. On the other hand, the operative mechanism of CL and CH during adsorption and PCC flocculation was predicted to be charge neutralization and electrostatic-patch formation, accompanied by particle bridging. Note that CL, with a maximum 47.5% eduction in residual turbidity of PCC at a 1% dose, was much more efficient in doing so than the other two gums; NG had a 40% maximum reduction in residual turbidity at a 5% dose and CH had a maximum 30% reduction at a 1% ose. Later on, floc formation and structure were correlated with optical and field emission scanning electron microscopy (FE-SEM) images. In the next set of trials, paper properties were determined by varying the different gum dosages from 0.2% to 5% at a constant dose of 20% filler. It is also noteworthy to mention that with 1% CL (low DS) dose, PCC retention increased by 39%, which also enhanced the tensile, tear, burst, and opacity properties by 11%, 19%, 5%, and 4.4%, respectively, without significantly affecting the bulk properties. Further, wide-angle X-ray diffraction (XRD) analysis nd Fourier transform infrared (FTIR) analysis revealed that pre-flocculating PCC with a 1% gum dose did not induce any change in crystalline transformation. Based on observation, it was found that cationic gums with low DS values re a better choice for maximizing the strength of paper while maintaining bulk and high opacity when pre-flocculaion is adopted to increase the filler retention in paper.

Journal articles
Magazine articles
Open Access
Tetraethyl orthosilicate-containing dispersion coating — water vapor and liquid water barrier properties, TAPPI Journal September 2021

ABSTRACT: An aqueous styrene-butadiene latex dispersion coating containing in-situ processed tetraethyl orthosilicate (TEOS) applied on paperboard demonstrated improved water barrier performance. Coatings containing TEOS equivalent to 0.8% silicon dioxide (SiO2; dry basis) exhibited water vapor performance of < 25 g/m2/day (23°C, 50% relative humidity [RH]) and liquid water barrier performance Cobb 1800 s of < 6 g/m2, when applied as a single-layer 18 g/m2 coating. Cobb 1800 s barrier performance was still good (< 11 g/m2) at coat weights of 7•10 g/m2. The use of filler materials such as kaolin improved the vapor barrier properties of the coating, but this was not critical to the liquid water barrier properties.

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