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Lignin-based resins for kraft paper applications, TAPPI Journal November 2019
ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.
Journal articles
Purification of Peroxide-Bleached TMP Waterby Dissolved Air
Purification of Peroxide-Bleached TMP Waterby Dissolved Air Flotation, TAPPI JOURNAL, May 2006, Vol. 5(5) (395 KB)
Journal articles
Characterizing Liquid-Vapor Phase Change Phenomena in Impuls
Characterizing Liquid-Vapor Phase Change Phenomena in Impulse Technology With Resistivity Probes, TAPPI JOURNAL, May 2006, Vol. 5(5) (280 KB)
Journal articles
Editor's Notes: Ready for a Test Drive, TAPPI JOURNAL, Novem
Editor's Notes: Ready for a Test Drive, TAPPI JOURNAL, November, 2006
Journal articles
Effect of PCC filler on dewatering of fiber suspension
Effect of PCC filler on dewatering of fiber suspension, TAPPI JOURNAL, November 2006
Journal articles
Image analytical monitoring of paper quality - a feasibility
Image analytical monitoring of paper quality - a feasibility study, TAPPI JOURNAL, November 2006
Journal articles
Use of enzymes for reduction in refining energy - laboratory
Use of enzymes for reduction in refining energy - laboratory studies, TAPPI JOURNAL, November 2006
Journal articles
The Effectiveness of TAED on the Peroxide Bleaching
The Effectiveness of TAED on the Peroxide Bleaching of Mechanical, Chemical, and Recycled Pulp
Journal articles
3-D Computational Simulation of Paper Handsheet Structure and Prediction of Apparent Density, TAPPI JOURNAL September 2009
3-D Computational Simulation of Paper Handsheet Structure and Prediction of Apparent Density, TAPPI JOURNAL September 2009
Journal articles
Decreasing specific energy of thermomechanical pulps from reduction of raw materials variability, TAPPI JOURNAL September 2009
Decreasing specific energy of thermomechanical pulps from reduction of raw materials variability, TAPPI JOURNAL September 2009