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Journal articles
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Editorial: New coating grades require new tests: Barrier performance inside the package, TAPPI Journal November 2024

The TAPPI Journal special Coating issue is an annual issue that focuses on paper coating and coated papers. It is drawn from presentations at TAPPICon and from other submissions on the topic of paper coating. The TAPPICon 2024 Coating track was rich in high-quality technical content. In fact, the papers were of such significance that Coating members of the TAPPI Journal Editorial Board, which include me, Gregg Reed, and Gregory Welsch, decided that a second paper coating-related special issue would be appropriate for the TAPPI Journal editorial calendar. In addition to the current issue on Barrier Coating Testing, there will be another issue on Coating Fundamentals in early 2025.

Journal articles
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Open Access
Test method and coating composition impact on measured moisture vapor transmission rate for waterborne coatings on paper, TAPPI Journal November 2024

ABSTRACT: Moisture vapor barrier is one of the necessary performance attributes for paper packages. Two methods are typically employed to assess the moisture vapor transmission rate (MVTR): the gravimetric cup method (ASTM E96) and the MOCON method (ASTM F1249). While those tests have been compared for free standing polymeric films, less is understood about their application in coated paper. Our results show that, despite a general agreement between the two methods, discrepancies exist where test protocols and material properties of coated paper impact the MVTR measurement. The measurement discrepancies can be explained by differences in local moisture concentration. Our study provides new insights on moisture vapor barrier assessment of waterborne coatings on paper and implications for achieving paper packages with improved barrier performance.

Journal articles
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Open Access
Evaluation of folding effects on coating damage, TAPPI Journal November 2024

ABSTRACT: Barrier coatings on paperboard need to maintain integrity during converting and end-use for effective barrier performance. Folding is one of the most common deformations during converting; however, factors that affect damage during folding are not well defined. This is partly because methods to fold specimens and characterize damage are not standardized and the results are generally not transferable. In this work, we describe a method to fold paper specimens precisely and reproducibly. The keys to folding include using a defined geometry and controlled deformation. Multiple methods can be used to quantify damage; in this case, we use differences in permeability as a measure of how the coating becomes more open. Damage is sensitive to the degree of compression after the initial folding. Using a shim for support provides a defined amount of compression and minimizes the sensitivity to the applied pressure.

Journal articles
Magazine articles
Open Access
Spraying starch on the Fourdrinier— An option between wet end starch and the size press, TAPPI Journal January 2021

ABSTRACT: Technology to apply suspensions of starch grains to the wet surface of paper, during the dewatering process, is reviewed. Though the technology is not new, it continues to attract the attention of papermakers as a means to increase bonding strength. Starch grains that are sprayed onto the wet-web of paper can be retained at levels exceeding what can be effectively added to the fiber suspension at the wet end. Unlike adding a starch solution at a size press, no additional drying capacity is required on the paper machine. To be effective, the starch needs to be able to swell and develop bonding during the paper drying process. Paperboard applications with recycled fibers appear to be a good fit. There is potential to increase bonding by processes that favor fuller gelatinization of the starch grains by the time the paper becomes dry.

Journal articles
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Open Access
Probing the molecular weights of sweetgum and pine kraft lignin fractions, TAPPI Journal June 2021

ABSTRACT: The present investigation undertook a systematic investigation of the molecular weight (MW) of kraft lignins throughout the pulping process to establish a correlation between MW and lignin recovery at different extents of the kraft pulping process. The evaluation of MW is crucial for lignin characterization and utilization, since it is known to influence the kinetics of lignin reactivity and its resultant physico-chemical properties. Sweetgum and pine lignins precipitated from black liquor at different pHs (9.5 and 2.5) and different extents of kraft pulping (30•150 min) were the subject of this effort. Gel permeation chromatography (GPC) was used to determine the number average molecular weight (Mn), mass average molecular weight (Mw), and polydispersity of the lignin samples. It was shown that the MW of lignins from both feedstocks follow gel degradation theory; that is, at the onset of the kraft pulping process low molecular weight-lignins were obtained, and as pulping progressed, the molecular weight peaked and subsequently decreased. An important finding was that acetobromination was shown to be a more effective derivatization technique for carbohydrates containing lignins than acetylation, the technique typically used for derivatization of lignin.

Journal articles
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Open Access
Three-dimensional pore structure visualization and character

Three-dimensional pore structure visualization and characterization of paper using X-ray computed tomography, TAPPI JOURNAL September 2017

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Open Access
On the nominal transverse shear strai to characterize the severity of creasing, TAPPI JOURNAL April 2018

On the nominal transverse shear strai to characterize the severity of creasing, TAPPI JOURNAL April 2018

Journal articles
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Open Access
On increasing wet-web strength with adhesive polymers, TAPPI JOURNAL February 2020

ABSTRACT: Fiber-fiber adhesion, called “bonding” in the old paper physics literature, is a critical component of the overall strength of dry paper. With freshly formed very wet pulp fiber webs, all evidence suggests there are no fiber-fiber crossings with significant adhesive joint strength. With water removal, a point will be reached where fiber-fiber adhesion starts to contribute to the overall wet-web strength.The literature reveals very few examples of polymers that increase fiber-fiber joint strength in freshly formed webs. Here, we summarize the literature and explain why it is so difficult to promote fiber-fiber wet adhesion with polymers. Nevertheless, ongoing research in areas as diverse as tissue engineering scaffolds and biomimetic adhesives gives clues to future developments. Advances in paper machine engineering have lessened the importance of wet-web strength. By contrast, a critical issue in many of the evolving nanocellulose technologies is the strength of objects first formed by aqueous processing, the green strength—the strength of wet bodies before drying. For exam-ple, 3-D printed nanocellulose objects and ultralow density cellulosic aerogels can be destroyed by capillary forces during drying. There is a need for adhesives that strengthen freshly formed, wet lignocellulosic joints.

Journal articles
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Open Access
Effects of different ammonium lignosulfonate contents on the crystallization, rheological behaviors, and thermal and mechanical properties of ethylene propylene diene monomer/polypropylene/ammonium lignosulfonate composites, TAPPI Journal January 2020

ABSTRACT: Thermoplastic elastomer (TPE), made from ethylene propylene diene monomer (EPDM) and polypropylene (PP) based on reactive blending, has an excellent processing performance and characteristics and a wide range of applications. However, there are currently no reports in the literature regarding the usage of TPE in making composite boards. In this paper, EPDM, PP, and ammonium lignosulfonate (AL) were used as the raw materials, polyethylene wax was used as the plasticizer, and a dicumyl peroxide vulcanization system with dynamic vulcanization was used to make a new kind of composite material. This research studied the influences of the AL contents on the crystallization behaviors, rheological properties, thermal properties, and mechanical properties of the composites. The results showed that the AL content had a noticeable impact on the performance of the composite board. Accordingly, this kind of composite material can be used as an elastomer material for the core layer of laminated flooring.

Journal articles
Magazine articles
Open Access
Calender barring review with experiences, TAPPI Journal July 2022

ABSTRACT: Excessive calender vibration affects all styles of calender stacks from single to multi-nip, all hard rolls, or a combination of hard and soft rolls. Calender vibration can be forced vibration or self-excited vibration. Forced vibration occurs at the first few harmonics of the calender roll rotational speeds and is caused by imbalance, misalignment, eccentricity, etc. Self-excited vibration, the focus of this paper, occurs at higher frequencies. Feedback paths for self-excited vibration must be understood in order to ameliorate the problem. This is presented in the context of the historical development of the theory of self-excited feedback mechanisms, followed by a survey of self-excited feedback mechanisms in various types of calender stacks. Methodology to determine which feed-back path is present and techniques to control or eliminate the resulting vibration follow. To obtain a flavor of the types of problems faced and practical remedial actions, a variety of experiences with barring issues are provided.