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Journal articles
Magazine articles
Open Access
Lignin-based resins for kraft paper applications, TAPPI Journal November 2019

ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.

Journal articles
Open Access
TRS inventories and air dispersion modeling for odor reduction at a kraft mill with an activated sludge treatment plant, TAPPI JOURNAL, April 2002 (281KB)

TRS inventories and air dispersion modeling for odor reduction at a kraft mill with an activated sludge treatment plant, SOLUTIONS! & TAPPI JOURNAL, April 2002 (281KB)

Journal articles
Open Access
Catalysis and activation of oxygen and peroxide delignification of chemical pulps: A review, TAPPI JOURNAL, April 2002 (38KB)

Catalysis and activation of oxygen and peroxide delignification of chemical pulps: A review, SOLUTIONS! & TAPPI JOURNAL, April 2002 (38KB)

Journal articles
Open Access
Oxygen delignification as a pretreatment for acetosolv pulps bleaching, TAPPI JOURNAL, April 2002, Vol. 1(2) (221KB)

Oxygen delignification as a pretreatment for acetosolv pulps bleaching, TAPPI JOURNAL, April 2002, Vol. 1(2) (221KB)

Journal articles
Open Access
NCASI technical studies of environmental issues affecting fiber supplies, TAPPI JOURNAL, November 2000, Vol. 83(11)

NCASI technical studies of environmental issues affecting fiber supplies, TAPPI JOURNAL, November 2000, Vol. 83(11)

Journal articles
Open Access
Influence of hexenuronic acids on us bleaching operations, TAPPI JOURNAL, November 2000, Vol. 83(11)

Influence of hexenuronic acids on us bleaching operations, TAPPI JOURNAL, November 2000, Vol. 83(11)

Journal articles
Open Access
Hesperaloe funifera - an excellent reinforcement fiber for mechanical paper grades, TAPPI JOURNAL, November 2000, Vol. 83(11)

Hesperaloe funifera - an excellent reinforcement fiber for mechanical paper grades, TAPPI JOURNAL, November 2000, Vol. 83(11)

Journal articles
Open Access
Differentiated permeability surface layer (dpsl) pressing theory, TAPPI JOURNAL, November 2000, Vol. 83(11)

Differentiated permeability surface layer (dpsl) pressing theory, TAPPI JOURNAL, November 2000, Vol. 83(11)

Journal articles
Open Access
Neutral enzyme assisted deinking of xerographic office waste with a cellulase/amylase mixture, TAPPI JOURNAL, November 2000, Vol. 83(11)

Neutral enzyme assisted deinking of xerographic office waste with a cellulase/amylase mixture, TAPPI JOURNAL, November 2000, Vol. 83(11)

Journal articles
Open Access
Infrared analysis for process control in the pulp and paper industry, TAPPI JOURNAL, October 2000, Vol. 83(10)

Infrared analysis for process control in the pulp and paper industry, TAPPI JOURNAL, October 2000, Vol. 83(10)