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A roadmap for future papermakers: Dr. Peter W. Hart’s TAPPI Journal contributions, TAPPI Journal December 2024
ABSTRACT: Dr. Peter W. Hart’s passing earlier this year, many of his fellow TAPPI Journal Editorial Board members, peers, and colleagues have reflected on the lasting significance of his contributions to TAPPI and the industry at large. In this special December tribute issue, we have compiled some of Peter’s past contributions to TAPPI Journal as selected by those individuals familiar with his research. Many of the papers highlight Peter’s dedication to collaborative work.
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Editorial: Special pulping and engineering issues of TAPPI Journal yield important recovery cycle research, TAPPI Journal June 2024
ABSTRACT: The June issue of TAPPI Journal, which is dominated by recovery cycle topics, is the last PEERS issue organized by Dr. Peter Hart, the former editor-in-chief who passed away this past May. Peter, who was heavily involved with TAPPI’s Pulp Manufacture Division and various pulping-related committees, also started working with conference technical program planning starting in 2005 with the Engineering, Pulping and Environmental (EPE) Conference, which was the precursor to the more recent Pulping, Engineering, Environmental, Recycling and Sustainability (PEERS) Conference. He was also involved with other conference planning, including that for the International Pulp Bleaching Conference. In addition, Peter was a yearly attendee of such conferences starting as far back as 1990.
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Factors affecting deposit formation in foul condensate stripping systems, TAPPI Journal June 2024
ABSTRACT: In kraft pulp mills, foul condensates are often steam-stripped to produce clean condensate for use as process water. The formation of organic deposits in the stripped condensate is a common problem. A systematic study was conducted to examine the deposit composition and the most likely operating parameters responsible for stripped condensate contamination experienced at a kraft mill in Brazil. Daily averaged data of 170 operating parameters over a 15-month period were analyzed by means of multivariate discriminant analysis and random forest classification analysis. The results showed that the deposit formation is related to high temperature, pressure, and dry solids operations in various evaporator effects. These conditions, combined with the poor demisting efficiency in these effects, may have increased black liquor carryover mist in the vapor. Deposit formation also appeared to be related to increased throughput of the foul condensate stripping system and increased pressure in the stripper. Results of Fourier transform infrared spectroscopy (FTIR) and pyrolysis-gas chromatography mass spectrometry (Py-GCMS) analyses show that the deposit consists of mostly organic matter that likely originated from wood extractives and lignin.
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Effect of high sulfate content on viscosity of recovery boiler molten smelt, TAPPI Journal March 2024
ABSTRACT: A systematic study was conducted to examine the effect of high sulfate content on the freezing temperature of molten smelt and how this may contribute to the formation of viscous jellyroll smelt in recovery boilers. The results show that even for recovery boilers with a smelt reduction as low as 70%, the sulfate content in smelt has no or little effect on smelt freezing temperature, and hence, on molten smelt fluidity. The perceived adverse effect of high sulfate content on smelt fluidity and on jellyroll smelt formation comes from the high sulfate content in deposits that have fallen from the upper furnace. Fallen deposits may or may not form jellyroll smelt, depending on whether or not they can melt and be well-mixed with molten smelt by the time they reach the smelt spouts. It is not the high sulfate content in smelt resulting from the low smelt reduction efficiency that makes molten smelt viscous and forms jellyroll smelt, but rather, it is the incomplete melting of fallen deposits that results in one of the proposed mechanisms for jellyroll smelt formation.
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Review of coating cracking and barrier integrity on paperboard substrates, TAPPI Journal November 2022
ABSTRACT: Barrier packaging formats are major growth areas for the pulp and paper industry. It is technically challenging to maintain barrier properties during converting and end-use applications. Improved manufacturing capabilities and coating formulation knowledge will help maintain barrier integrity and enable growth of barrier products in challenging applications. These improvements will accelerate product development and commercialization, and allow faster response to product performance issues such as cracking. The literature on coating cracking provides knowledge mostly on the effects of coating formulations and to a lesser extent on substrate effects. Despite a large number of publications dedicated to coating failures, the approach to improve coating cracking remains empirical, and the transferability between studies and to real life applications has not been well established. Model development that successfully predicts commercial performance is in its infancy. However, some of these simplified models do a fairly good job predicting experimental data. The current work reviews the state of understanding as regards coating and barrier cracking and highlights the need for more research on cracking and barrier integrity.
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Effectiveness of masks in the suppression of COVID-19 cases during the ongoing pandemic in India, TAPPI Journal October 2022
ABSTRACT: Perhaps the worst predicament faced by humanity in the twenty-first century is the COVID-19 pandemic, which is caused by the SARS-CoV-2 virus. Most parts of the world, including India, went into lockdowns for some period because of the massive increase in cases throughout 2020. Face masks became an important counter-measure for protecting the populace, health professionals, and medics, particularly during the period prior to the mass availability of vaccines. This study intends to evaluate the effectiveness of face masks in limiting the spread of the virus. The data for the number of COVID-19 cases was analyzed from January 1, 2022 to May 31, 2022, using Python programming. This timeframe involved face mask mandates and no mask requirement, and hence was considered to be ideal for analyzing the usefulness of face masks. A decline in cases during the mandate was observed, while the opposite occurred without the mandate. The outcome of the research showed that face masks are effective additional measures against the spread of SARS-CoV-2. This study elevates the value of personal protective equipment (PPE), such as face masks, made with nonwovens and other fabrics, as lifesavers in the case of airborne diseases such as COVID-19 and other pulmonary disorders.
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Utilization of palm fiber as papermaking materials: Microscopic structure and chemical pulping, TAPPI Journal October 2022
ABSTRACT: The microscopic structure and pulping properties of palm fiber were explored. Soda cooking and sulfate cooking were conducted and compared in terms of physical strength of the obtained pulps. Sulfate pulp showed better performance than soda pulp, as indicated by the 23% higher tensile index, 49% higher tear index, and 36% higher burst index. To further elevate physical strength, long fibered pulp (LFP), namely commercial softwood sulfate pulp, was mixed with sulfate pulp of palm fiber at levels from 20% to 50%. At the blend level of 50%, tensile index of 52.13 Nœm/g, tear index of 15.63 mNœm2/g, and burst index of 3.42 kPaœm2/g were attained. The lignin in spent liquor from pulping was isolated and characterized. Soda lignin of palm fiber was mainly composed of guaiacyl and syringyl units, and showed weight-average molecular weight of 3616 g/mol.
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Research on improving the basis weight measurement accuracy of tissue paper based on PSO-BP neural network, TAPPI Journal October 2022
ABSTRACT: The near-infrared (NIR) sensor can be used for measuring the basis weight and moisture of tissue paper, but the measurement accuracy is not ideal for this paper grade. The weight range of the tissue is 10~30 g/m2, indicating that it is a low gram weight paper. The temperature and humidity of the production environment significantly impact an NIR sensor. This paper focuses on improving the measurement accuracy of tissue paper basis weight. In order to reduce the influences of temperature and humidity, a mathematical model based on a particle swarm optimization back propagation (PSO-BP) neural network is proposed. In comparison with multiple linear regression measurement models, the basis weight measurement error with the PSO-BP model is within ± 0.5 g/m2. This model can effectively improve the measurement accuracy and has a good effect on overcoming the basis weight nonlinear effect caused by the changes in ambient temperature and humidity.
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Nanocellulose•cationic starch• colloidal silica systems for papermaking: Effects on process and paper properties, TAPPI Journal October 2022
ABSTRACT: Laboratory tests were conducted to better understand effects on the papermaking process and handsheets when recycled copy paper furnish was treated with combinations of nanofibrillated cellulose (NFC), cationic starch, colloidal silica, and cationic retention aid (cPAM; cationic polyacrylamide). Dosage-response experiments helped to define conditions leading to favorable processing outcomes, including dewatering rates and the efficiency of fine-particle retention during papermaking. Effects were found to depend on the addition amounts of cationic starch and colloidal silica added to the system. It was shown that the presence of a polymer additive such as cationic starch was essential in order to achieve large strength gains with simultaneous usage of NFC.
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PEERS 2023 Poster Session: a competition for students and young professionals, TAPPI Journal April 2023
ABTRACT: Originating in the field of scientific research and academia, poster sessions at conferences may date back to the mid-20th century, although the origins aren’t quite clear. Some sources have said as early as the 1950s and others later, while the term “poster session” itself may not have been coined until the 1975 American Physics Conference. The original concept behind poster sessions was to provide a platform for researchers to share their work in a more visual and interactive format as compared to the traditional long-form oral presentation.