Search
Use the search bar or filters below to find any TAPPI product or publication.
Filters
Content Type
Publications
Level of Knowledge
Committees
Event Type
Collections
Journal articles
Magazine articles
Cross-flow separation characteristics and piloting of graphene oxide nanofiltration membrane sheets and tubes for kraft black liquor concentration, TAPPI Journal September 2023
ABSTRACT: Dewatering of weak black liquor (WBL) in the kraft cycle by evaporation is highly energy intensive. Membranes are an attractive alternative for energy-efficient dewatering, but existing commercial polymeric or ceramic membranes are either degraded in BL or have high capital costs. Our recent works have demonstrated the engineering of graphene oxide (GO) nanofiltration membranes, their stability and promising performance in BL conditions, and preliminary scale-up into sheets and tubes. Here, we describe in detail the separation characteristics of GO membrane sheets and tubes under real BL conditions and crossflow operation. Recycle-mode piloting of a GO tubular membrane showed average “production flux” of 16 L/m2/h (LMH) and high rejections of lignin (98.3%), total solids (66%), and total organic carbon (83%), with no signs of irreversible fouling identified. A corresponding GO sheet membrane produced an average flux of ~25 LMH and maintained high lignin rejection of ~97% during a slipstream pilot at a kraft mill site using WBL with ~16 wt% total solids (TS). Finally, we piloted a Dow/DuPont XUS1808 polyamide composite reverse osmosis (RO) membrane for last-mile processing of the GO nanofiltration membrane permeate. The RO membrane showed a steady state flux of 19 LMH at 65 bar and produced ~0.02 wt% TS water product, which is highly suitable for reuse in pulp washing operations in the kraft process. The results have strong positive implications for the industrial application of GO membranes in BL concentration and other related applications.
Journal articles
Magazine articles
Viscoelastic web curl due to storage in wound rolls, TAPPI Journal July 2020
ABSTRACT: Winding is often the final operation in a roll-to-roll manufacturing process. Web materials, i.e., materials that are thin compared to their length, are wound into rolls because this form is the only practical means to store them. The resulting bending strains and associated stresses are large for thick webs and laminates. As many webs are viscoelastic on some time scale, bending stresses lead to creep and inhomogeneous changes in length. When the web material is unwound and cut into discrete samples, a residual curvature remains. This curvature, called curl, is the inability for the web to lie flat at no tension. Curl is an undesirable web defect that causes loss of productivity in a subsequent web process. This paper describes the development and implementation of modeling and experimental tools to explore and mitigate curl in homogenous webs. Two theoretical and numerical methods that allow the prediction of curl in a web are developed: a winding software based on bending recovery theory, and the implementation of dynamic simula-tions of winding. One experimental method is developed that directly measures the curl online by taking advantage of the anticlastic bending resulting from the curl. These methods are demonstrated for a low-density polyethylene web.
Journal articles
Magazine articles
How to use total dissolved solids measurements to evaluate the performance of diffuser washers—A mill study, TAPPI Journal April 2020
ABSTRACT: Various types of pulp washing equipment are available. Each washing device has a unique mechanical construction, and the washing principle is often a combination of dilution, thickening, and displacement washing. In this work, the performance of the pressure diffuser washer is studied. In stepwise trials, the effect of the feed and discharge consistencies on the performance of the diffuser was studied. The effect of the downward velocity of the screen on the pressure diffuser’s washing efficiency was also studied. The measurement of total dissolved solids (TDS) by a process refractometer was used as a wash loss measurement unit and the refractometer’s results were used in the calculations of standardized Nordén efficiency (E10) values. The chemical oxygen demand (COD) and conductivity values were also measured and their results compared to the TDS results.The results indicated that feed consistency has a significant effect on the performance and effectiveness of the diffuser washers in the mill. It can also be stated that when the downward velocity of the screen is adjusted to too high a level, the washing efficiency of the pressure diffuser decreases. As a conclusion from the mill tests, it can be stated that even small process parameter changes can provide enhanced diffuser washing at the beginning of the washing line, which has a direct effect on the performance of post-oxygen washing.
Journal articles
Magazine articles
Understanding extensibility of paper: Role of fiber elongation and fiber bonding, TAPPI Journal March 2020
ABSTRACT: The tensile tests of individual bleached softwood kraft pulp fibers and sheets, as well as the micro-mechanical simulation of the fiber network, suggest that only a part of the elongation potential of individual fibers is utilized in the elongation of the sheet. The stress-strain curves of two actual individual pulp fibers and one mimicked classic stress-strain behavior of fiber were applied to a micromechanical simulation of random fiber networks. Both the experimental results and the micromechanical simulations indicated that fiber bonding has an important role not only in determining the strength but also the elongation of fiber networks. Additionally, the results indicate that the shape of the stress-strain curve of individual pulp fibers may have a significant influence on the shape of the stress-strain curve of a paper sheet. A large increase in elongation and strength of paper can be reached only by strengthening fiber-fiber bonding, as demonstrated by the experimental handsheets containing starch and cellulose microfibrils and by the micromechanical simulations. The key conclusion related to this investigation was that simulated uniform inter-fiber bond strength does not influence the shape of the stress-strain curve of the fiber network until the bonds fail, whereas the number of bonds has an influence on the activation of the fiber network and on the shape of the whole stress-strain curve.
Journal articles
Magazine articles
Kinetics of sulfur dioxide-alcohol-water (SAW) pulping of su
Kinetics of sulfur dioxide-alcohol-water (SAW) pulping of sugarcane straw (SCS), TAPPI JOURNAL June 2017
Journal articles
Magazine articles
Understanding the pulping and bleaching performances of eucalyptus woods affected by physiological disturbance, TAPPI Journal November 2018
Understanding the pulping and bleaching performances of eucalyptus woods affected by physiological disturbance, TAPPI Journal November 2018
Technical and Economic Analysis of Repurposing a Kraft Pulp and Paper Mill to the Production of Ethanol, 2008 Engineering, Pulping and Environmental Conference
Technical and Economic Analysis of Repurposing a Kraft Pulp and Paper Mill to the Production of Ethanol, 2008 Engineering, Pulping and Environmental Conference
The Fate of Silver from Recycled Printed Electronic Circuits, 2008 Engineering, Pulping and Environmental Conference
The Fate of Silver from Recycled Printed Electronic Circuits, 2008 Engineering, Pulping and Environmental Conference
Use of Urea as an Additive in Kraft Pulping of Eucalyptus, 2008 Engineering, Pulping and Environmental Conference
Use of Urea as an Additive in Kraft Pulping of Eucalyptus, 2008 Engineering, Pulping and Environmental Conference
Process Variables of Pulp Alkali Pretreatment, 2008 PAPERCON Conference
Process Variables of Pulp Alkali Pretreatment, 2008 PAPERCON Conference