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The role of gas dispersion in the oxygen delignification process, TAPPI Journal May 2021
ABSTRACT: Oxygen delignification is an essential part of the pulp production process. Delignification occurs with the aid of alkali and dissolved oxygen. Dissolved oxygen is obtained by dispersing oxygen gas into the pulp suspension by using efficient mixers. Little is known about the state of oxygen gas dispersion and its effect on oxygen delignification kinetics and efficiency. This paper will present the results for the effect of gas bubble size on the performance of oxygen delignification. The results are mainly based on detailed studies made in a Finnish hardwood mill where the oxygen bubble size distribution could be altered at the feed of the reactor. An essential aspect of these studies was the use of a new continuous inline gas bubble size measurement system to simultaneously determine the bubble size distribution at the feed and top of the reactor. Information about oxygen consumption in the reactor could also be obtained through the bubble size measurements. Accordingly, these studies quantify the effect of oxygen bubble size on the kappa reduction of the pulp. The effect of different chemical factors on the oxygen bubble size is also studied.Finally, the relationship between the gas bubble size and the liquid phase oxygen mass transfer coefficient (kLa) is presented. This connects the bubble size to the kappa reduction rate. Based on the presented modeling approach and the evaluation of practical factors that are not taken into account in the modeling, it was concluded that the volumetric average oxygen bubble size should preferably be smaller than 0.2 mm in practice.The information obtained with the new gas bubble size measurement system and the presented modeling approach give a very new basis for understanding, monitoring, adjusting, and designing oxygen delignification processes.
Journal articles
Effects of localized environment on eucalyptus clone chemica
Effects of localized environment on eucalyptus clone chemical composition, TAPPI JOURNAL September 2016
Journal articles
Magazine articles
In-process detection of fiber cutting in low consistency ref
In-process detection of fiber cutting in low consistency refining based on measurement of forces on refiner bars, TAPPI JOURNAL April 2017
Journal articles
Magazine articles
Functionalization of wood/plant-based natural celluslose fibers with nanomaterials: a review, TAPPI JOURNAL February 2018
Functionalization of wood/plant-based natural celluslose fibers with nanomaterials: a review, TAPPI JOURNAL February 2018
Journal articles
Magazine articles
Print quality of flexographic printed paperboard related to coating composition and structure, TAPPI Journal January 2018
Print quality of flexographic printed paperboard related to coating composition and structure, TAPPI Journal January 2018
Journal articles
Magazine articles
Evaluation of the out-of-plane response of fiber networks with a representative volume element model, TAPPI JOURNAL June 2018
Evaluation of the out-of-plane response of fiber networks with a representative volume element model, TAPPI JOURNAL June 2018
Journal articles
Magazine articles
Decreased water usage in a softwood ECF bleaching sequence— full mill simulations, TAPPI JOURNAL June 2018
Decreased water usage in a softwood ECF bleaching sequence— full mill simulations, TAPPI JOURNAL June 2018
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Photo-catalytic degradation of gaseous pollutants in paper mills of southern China, TAPPI JOURNAL March 2018
Photo-catalytic degradation of gaseous pollutants in paper mills of southern China, TAPPI JOURNAL March 2018
Journal articles
Magazine articles
Use of vent stack temperature as a feedforward variable for dissolver total titratable alkali (TTA) control, TAPPI JOURNAL May 2018
Use of vent stack temperature as a feedforward variable for dissolver total titratable alkali (TTA) control, TAPPI JOURNAL May 2018
Journal articles
Magazine articles
Water chemistry challenges in pulping and papermaking • fundamentals and practical insights: Part 1: Water chemistry fundamentals and pH, TAPPI Journal June 2022
ABSTRACT: Water is an essential component of the papermaking process. Nevertheless, papermakers often overlook its importance compared to fibers and chemical additives. A better understanding of water properties and chemical interactions associated with water at the wet end leads to a sound foundation for high-quality paper production and smooth operation. Not all fresh water and process water is the same. Fresh water varies from mill to mill, primarily due to the location and availability of water sources. Some industrial trends, such as enhancing water conservation and production yield, gradually shift process water quality over time. The current work serves as a primer on water and water chemistry fundamentals to help the papermaker prepare for the future challenges of increased contamination of process water associated with reduced fresh water usage. This paper focuses on basic water chemistry definitions and discusses the impact of pH on wet-end operation. It is clear that pH is a fundamental factor that directly affects the process and impacts other factors relevant to the papermaking process. It is crucial to understand what pH represents, how it is measured, how to select the proper pH and carefully control it, and how to closely maintain the process at target setpoints. Understanding the sensitivity of operation to pH change will lead to an appropriate focus on these issues. In addition to basic theory, we also review onsite experience and practical mill cases. It is imperative to stress that, although critical, pH is not the only chemical parameter impacting papermaking operations. Other factors, such as ionic concentration measured by conductivity, surface, soluble charge, and hardness, are critical and will be discussed in Part II of this series. As pH is a primary and independent factor that impacts various forms of charge and conductivity, the authors decided to start the current series of papers by discussing pH.