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Journal articles
Magazine articles
Open Access
Stiffness and strength properties of five paperboards and their moisture dependency, TAPPI Journal February 2020

ABSTRACT: Five commercial multiply folding boxboards made on the same paperboard machine have been analyzed. The paperboards were from the same product series but had different grammage (235, 255, 270, 315, 340 g/m2) and different bending stiffness. The paperboards are normally used to make packages, and because the bending stiffness and grammage varies, the performance of the packages will differ. Finite element simulations can be used to predict these differences, but for this to occur, the stiffness and strength properties need to be deter-mined. For efficient determination of the three-dimensional properties in the machine direction (MD), cross direction (CD), and Z direction (ZD), it is proposed that the paperboard should be characterized using in-plane tension, ZD-tension, shear strength profiles, and two-point bending. The proposed setups have been used to determine stiff-ness and strength properties at different relative humidity (20,% 50%, 70%, and 90% RH), and the mechanical proper-ties have been evaluated as a function of moisture ratio.There was a linear relation between mechanical properties and moisture ratio for each paperboard. When the data was normalized with respect to the standard climate (50% RH) and plotted as a function of moisture ratio, it was shown that the normalized mechanical properties for all paperboards coincided along one single line and could therefore be expressed as a linear function of moisture ratio and two constants.Consequently, it is possible to obtain the mechanical properties of a paperboard by knowing the structural properties for the preferred level of RH and the mechanical property for the standard climate (50% RH and 23°C).

Journal articles
Magazine articles
Open Access
Use of fines-enriched chemical pulp to increase CTMP strength, TAPPI Journal April 2021

ABSTRACT: In this study, fines-enriched pulp (FE-pulp)—the fine fraction of highly-refined kraft pulp—was benchmarked against highly-refined kraft pulp (HRK-pulp) as a strength agent in eucalyptus chemithermomechanical pulp (CTMP). Both the FE-pulp and the HRK-pulp were produced from unbleached softwood kraft pulp, and equal amounts of those strength agents were added to the original CTMP, as well as to washed CTMP, where most of the fines had been removed. The effects of the added strength agents were evaluated with laboratory handsheets.The FE-pulp proved to be twice as effective as HRK-pulp. Both HRK-pulp and FE-pulp increased the strength of the CTMP handsheets. The bulk of the handsheets decreased, however, as well as the drainability. The addition of 5% FE-pulp resulted in the same strength increase as an addition of 10% HRK-pulp, as well as the same decrease in bulk and CSF. For the handsheets of washed CTMP, the strengths were not measurable; the CTMP lost the sheet strength when the CTMP-fines content was reduced through washing. The reduced strength properties were compensated for by the addition of chemical pulp fines that proved to be an efficient strength agent. The addition of 5% FE-pulp restored the strength values, and at a higher bulk and higher drainability.

Journal articles
Magazine articles
Open Access
Formic acid pulping process of rice straw for manufacturing of cellulosic fibers with silica, TAPPI Journal August 2021

ABSTRACT: Emerging technology has the potential to develop entirely new approaches for producing cellulose fiber-based materials along with fuels and chemical raw materials like lignin and furfural. Rice straw is a rich source of cellulosic fibers and inorganic micronic-sized particles termed as ash. They can prove helpful in development of new or enhanced agricultural residue-based materials and products that offer cost effective substitutes for nonrenewable materials used in different domestic and industrial applications. Lignocellulose is an abundant material that is submicronic at the basic level. Rice straw is a fibrous lignocellulosic material obtained as agricultural residue, but it differs from most crop residues in its high content of silicon dioxide (SiO2). Ash content on a dry weight basis ranges from 13% to 20%, varying according to the state of conservation of the straw after harvest. The ash in rice straw has nearly 75% SiO2. The particle size analysis shows variation from a few microns to hundreds of microns for inorganic residues left after burning at high temperatures above 550°C. Proximate analysis of rice straw shows that it contains 54% to 56% holocellulose and 15% to 18% lignin, both of which are natural biopolymers. The compound analysis shows the different compounds present in rice straw ash.Rice straw is available in hundreds of million tons in India and other Asian countries, so suitable technologies are required to convert rice straw from a biomass waste to useful bioproducts like pulp, paper, and paperboard. This research paper is intended to obtain pulp with fibers having inherent silica present in it to give high opacity paper and better bonding between fibers.

Journal articles
Magazine articles
Open Access
Can carbon capture be a new revenue opportunity for the pulp and paper sector?, TAPPI Journal August 2021

ABSTRACT: Transition towards carbon neutrality will require application of negative carbon emission technologies (NETs). This creates a new opportunity for the industry in the near future. The pulp and paper industry already utilizes vast amounts of biomass and produces large amounts of biogenic carbon dioxide. The industry is well poised for the use of bioenergy with carbon capture and storage (BECCS), which is considered as one of the key NETs. If the captured carbon dioxide can be used to manufacture green fuels to replace fossil ones, then this will generate a huge additional market where pulp and paper mills are on the front line. The objective of this study is to evaluate future trends and policies affecting the pulp and paper industry and to describe how a carbon neutral or carbon negative pulp and paper production process can be viable. Such policies include, as examples, price of carbon dioxide allowances or support for green fuel production and BECCS implementation. It is known that profitability differs depending on mill type, performance, energy efficiency, or carbon dioxide intensity. The results give fresh understanding on the potential for investing in negative emission technologies. Carbon capture or green fuel production can be economical with an emission trade system, depending on electricity price, green fuel price, negative emission credit, and a mill’s emission profile. However, feasibility does not seem to evidently correlate with the performance, technical age, or the measured efficiency of the mill.

Journal articles
Open Access
Physico-mechanical and ethylene scavenging properties of active packaging from Bambusa fibers modified with TiO2 /Cu2O composite, TAPPI Journal February 2026

ABSTRACT: The physico-mechanical and ethylene scavenging properties of active packaging consisting of paper prepared from bamboo (Bambusa vulgaris) fibers loaded with varying concentrations of nano titanium dioxide/cuprous oxide (TiO2/Cu2O) composite was investigated for its ability to delay ripening of Philippine climacteric fruits. Tests of paper containing 1% to 5% TiO2/Cu2O showed no or limited negative impact on its physical, optical, and mechanical properties. Images from a field emission scanning electron microscope equipped with energy-dispersive X-ray spectroscopy (FESEM-EDS) showed dispersion and agglomeration of TiO2/Cu2O nanoparticles on the paper surface. The percent weight of titanium and copper increased with increasing metal oxide composite concentration used in this study. Attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy indicated small shifts in band intensity at 3330 cm-1 and 1100 cm-1 in the hydroxyl (O-H) and C-O regions, respectively, suggesting possible chemical or physical interactions between the metal oxide and paper. Contact angle measurement suggest- ed that TiO2/Cu2O nanoparticles may have imparted paper hydrophobicity at 3% & 5% concentration, possibly through increased microscale roughness. The ethylene scavenging experiment indicated that there was a significant delay in the ripening process of mango and tomato when packed in paper doped with 3% and 5% TiO2/Cu2O. The fruits were greener with a firmer texture compared with untreated control after three days of storage under natural light and ambient condition. The preliminary results suggested that 3% &5% TiO2/Cu2O active packaging modification can remove ethylene from the fruit's storage environment, extending shelf life and maintain quality for three days. This simple technique could have potential economic benefits for the fruit industry by directly reducing post-harvest waste, and the delayed ripening could provide flexibility in supply chain management.

Journal articles
Open Access
Pre-damping effects on water absorption and drying dynamics in flexographic printing, TAPPI Journal November 2025

ABSTRACT: Optimizing flexographic printability can involve the ink and the substrate, as well as the printing process. It has been widely reported in the literature that controlling topography of the substrate and its porosity are vital for good flexographic printability, especially when using water-based inks. This study focuses on how pre-damping a surface impacts liquid absorption and improves wet trapping (ink on ink with no intermediate drying) in flexographic printing. A Prüfbau universal print tester was adapted to analyze flexographic wet-on-wet ink printing and trapping using yellow and magenta inks for contrast. Slow drying of the first ink layer (yellow) leads to mottle when the second layer (magenta) is applied. The study explores the “wet sponge” hypothesis: a pre-damped surface should absorb liquid faster. The Lucas- Washburn equation describes long-term absorption, but it does not capture short-term uptake, which instead follows a linear dependence on time.

Journal articles
Open Access
Effects of biopolymer coatings on paper permeability and capillarity for paper-based rapid diagnostic test devices, TAPPI Journal September 2025

ABSTRACT: Rapid diagnostic test (RDT) devices are widely used for diagnostics due to their affordability, portability, and user-friendliness. However, conventional assays typically rely on nitrocellulose membranes and plastic casings. These materials raise environmental concerns due to their non-renewable nature, energy-intensive production methods, and poor biodegradability. This study explores the development of fully bio-based RDT substrates using a sustainable alternative: softwoodderived microfibrillated cellulose (MFC), cellulose nanocrystals (CNC), and chitosan as surface modifiers to improve paper properties and enhance RDT sustainability. Cotton filter paper substrates were coated with different biopolymer formulations using a manual blade coater: bleached MFC (BMFC), lignin-containing MFC (LMFC), BMFC combined with CNC, LMFC combined with CNC, and chitosan. Evaluation of the most relevant physical properties concerning RDT performance was conducted, including wetting, water retention value, air permeability, capillary flow rate, and surface morphology. Results showed that biopolymer- based coatings can effectively modify surface properties by reducing pore size and tuning hydrophilicity, while maintaining the renewable and bio-based characteristics of the substrate. The LMFC-coated paper exhibited the best overall performance among all formulations, reducing flow time by 50% (3.00 mm/s vs. 1.5 mm/s) compared to the uncoated paper, yet preserving high water retention. The BMFC+CNC coating also significantly improved flow rate, showing a 36.7% reduction (2.37 mm/s vs. 1.5 mm/s), and enhanced porosity uniformity. In contrast, the flow rate of chitosan-coated paper decreased by over 5,000% (0.027 mm/s), reflecting its strong barrier properties and hydrophobic surface (highest contact angle: 91.4°). These findings suggest that MFC-based coatings are promising ecofriendly alternatives to nitrocellulose, offering optimized capillary transport and structural adaptability. This paves the way for the development of sustainable, high-performance, rapid diagnostic tests.

Journal articles
Open Access
In-situ process monitoring in deep-drawing of paper using partially transparent tools, TAPPI Journal August 2025

ABSTRACT: The production of three-dimensionally formed packaging from paper by deep drawing usually leads to the occurrence of wrinkles, which result from the high tangential compressive stresses in the flange area and the limited flowability of the material. Wrinkles, although mostly tolerated in industry, end in both a reduced visual appearance and a reduction in usability for packaging, as with, for example, when gas-tightness is required. Previous research efforts have been limited to determining the wrinkle distribution after completion of forming and removal of the formed part. Consequently, the possibility of understanding the sequence of formation of individual wrinkles in the inhomogeneous material is lost. To remedy this situation, a method for local in-situ process monitoring is presented. Using a transparent die and an industrial camera, the flange area can be observed during the forming process. An image processing algorithm is applied to analyze the local development of the deep drawing process from the continuously recorded image data. The method described can be used to analyze the draw-in behavior and wrinkle formation locally and continuously over the drawing depth. The blank holder force influences the draw-in and the wrinkle pattern both locally and throughout the drawing process. A more precise understanding of the wrinkle formation will allow for more efficient process control in the future.

Journal articles
Open Access
Colloidal silica and its effects during formation of paper sheets in the presence of nanofibrillated cellulose, cationic starch, and cationic acrylamide copolymer, TAPPI Journal May 2025

ABSTRACT: This work considered effects of colloidal silica addition during laboratory preparation of paper sheets containing nanofibrillated cellulose (NFC) that had been pretreated with cationic starch. The emphasis was on process performance issues, including dewatering rates, fine particle retention, and the extent of fiber flocculation. In addition, micrographs were obtained to show what was happening to the NFC upon treatments with cationic starch and subsequent application of hydrodynamic shear. Contrasting results were obtained, depending on the charge density of the cationic starch. Pretreatment of the NFC with a high charge density cationic starch (degree of substitution 0.2) resulted in strong interactions with the colloidal silica, enhancing the dewatering rate and contributing to fine-particle retention. The medium charge cationic starch pretreatment led to effects suggesting a bridging mechanism of action, and subsequent colloidal silica had no significant effect on dewatering. Treatment of that system with a high level of colloidal silica (0.2%) resulted in lower retention. In general, the final colloidal silica treatments tended to decrease the level of flocculation in the suspensions, giving more uniform handsheets. Mechanisms, some of them related to the clustering and dispersion of cationic starch-treated NFC, were proposed to account for the observed effects.

Journal articles
Magazine articles
Open Access
Numerical analysis of the impact of rotor and screen hole plate design on the performance of a vertical pulper, TAPPI Journal April 2025

ABSTRACT: The dissolving of mechanical pulp is one of the most important process steps in stock preparation, since pulping occurs at the very beginning of the papermaking process. Efficient mixing of the pulp in a short amount of time is essential to achieve high furnish volume flow rates. The design of the rotor, as well as the pulper vat and inserts, significantly affects the overall performance of the pulper, such as mixing efficiency and power demand. Using advanced numerical methods such as computational fluid dynamics (CFD) can accelerate the development process. The CFD simulations allow for detailed analysis of flow phenomena, making it possible to study a real-size machine numerically. This approach is particularly advantageous because it can reduce the need for timeconsuming and costly experiments associated with scaling up test rigs. In this study, we compared two different rotor designs utilized in a vertical pulper and evaluated the numerical results with experimental data. Rotor A is designed for low turbulence and low power demand, while rotor B is designed for high turbulence with high power demand. The CFD results showed good agreement with the experimental measurements. We investigated how the rotor design influences the free fluid surface and the mixing efficiency. Our study also highlights the differences in results depending on whether water or furnish is simulated, which exhibit Newtonian or, respectively, non-Newtonian fluid behavior. Additionally, a detailed numerical investigation of various screen hole plate designs revealed that the newly developed hole design significantly reduces pressure loss compared to a standard drilled hole. This outcome was consistent for both types of fluids investigated: water and furnish.