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Application of ATR-IR measurements to predict the deinking efficiency of UV-cured inks, TAPPI Journal January 2022
ABSTRACT: In recent years, ultraviolet (UV)-curable ink has been developed and widely used in various printing applications. However, using UV-printed products (UV prints) in recovered paper recycling causes end-product dirt specks and quality issues. A new method was developed that can distinguish UV prints from other prints by means of attenuated total reflectance infrared (ATR-IR) spectroscopy. Application of this method could allow more efficient use of UV prints as raw materials for paper recycling.First, a mill trial was performed using UV prints alone as raw materials in a deinked pulp (DIP) process. Second, test prints were made with four types of UV inks: a conventional UV ink and three different highly-sensitive UV inks. Each print sample had four levels of four-color ink coverage patterns (100%, 75%, 50%, and 25%). Next, deinkability of all prints was evaluated by laboratory experiments. Finally, each print was measured using the ATR-IR method, and the relationship between the IR spectra and deinkability was investigated. Mill trial results showed that UV prints caused more than 20 times as many dirt specks as those printed with conventional oil-based ink. There were variations in recycling performance among UV prints taken from bales used for the mill trial. Lab tests clearly revealed that not all UV-printed products lead to dirt specks. In order to clarify the factors that affected deinkability of UV prints, the print samples were investigated by lab experiments. Key findings from lab experiments include: œ The number of dirt specks larger than 250 µm in diameter increased as the ink coverage increased. œ Higher ink coverage area showed stronger intensity of ATR-IR spectral bands associated with inks. These results indicate that deinkability of UV prints could be predicted by analysis of ATR-IR spectra. œ Finally, the method was applied for assessment of recovered paper from commercial printing presses. It was confirmed that this method made it possible to distinguish easily deinkable UV prints from other UV prints. Based on these findings, we concluded that the ATR-IR method is applicable for inspection of incoming recovered paper.
Journal articles
Magazine articles
Economic and competitive potential of lignin-based thermoplastics using a multicriteria decision-making method, TAPPI Journal September 2022
ABSTRACT: As a result of new lignin extraction plants hatching and increasing volumes of technical lignin becoming available, a variety of lignin derivatives, including phenolic resins and polyurethane (PU) foams, are reaching the marketplace or being used as intermediate products in many industrial applications. In the spectrum of possible lignin derivatives, thermoplastics appear particularly attractive due to a symbiosis of market, policy, and technology drivers. To assess the preferredness for lignin-based thermoplastics, this paper adapted a risk-oriented methodology formerly applied to assess lignin usage in various applications (phenol-formaldehyde [PF] resins, PU foams, and carbon fiber applications) to the case of lignin-based thermoplastics using hydroxypropylated lignin (HPL) and miscible blends of lignin and polyethylene oxide (PEO). The HPL is considered for garbage bags and agricultural films applications, while lignin-PEO blends are used as replacement for acrylonitrile butadiene styrene (ABS) in applications such as automotive parts. In the methodology, two phased-implementation strategies were defined for each thermoplastic derivative, considering perspectives for profit maximization (90 metric tons/day integrated units) and revenue growth (350 metric tons/day overall capacity), which were considered for implementation within a softwood kraft pulping mill. A set of six criteria representative of the main economic and market competitiveness issues were employed, and their respective importance weights were obtained in a multicriteria decision-making (MCDM) panel.Early-stage techno-economic estimates were done as a basis for the calculation of decision criteria. Compared to product derivatives previously assessed, capital investment for thermoplastic strategies appeared marginally higher due to the required lignin modification steps (on average 30% higher at similar capacity, and 6% for higher-scale revenue diversification strategies). Higher operating costs were also observed due to increased chemical expenses for all thermoplastic strategies, which are ultimately balanced by revenues associated with targeted thermoplastic products, leading to greater annual margins and cash flow generation over the project lifetime for thermoplastic strategies compared to other product applications (58% to 66% higher on average, at similar scale). Benefits of improved economics were reflected in economic criteria, internal rate of return (IRR), and cash flow on capital employed (CFCE), as well as in the price competitiveness criterion, CPC. Overall, the combination of relatively high lignin content in the plastic formulation and the less costly modification method contributed to lignin-PEO strategies, gaining the top two rankings. Based on their overall scores, both strategies defined for HPL would also integrate the group of “preferred” strategies, but are outranked by strategies that consider lignin positioning on PU foam applications.
Journal articles
Paper strength factors in systems with nanofibrillated cellulose, cationic starch, colloidal silica, cationic acrylamide copolymer, and hydrodynamic shear, TAPPI Journal May 2025
ABSTRACT: Laboratory paper sheets were formed by first pretreating nanofibrillated cellulose (NFC) with cationic starch at the 5% level by mass. The treated NFC was then added to stock prepared from 100% recycled copy paper. The combined furnish was next optionally treated with a cationic retention aid (cPAM, 0.1%) and then colloidal silica (0.1% or 0.2%). Vacuum dewatering, fine-particle retention, and several paper properties were studied as a function of the colloidal silica level (zero, 1%, and 2%) and at different levels of shear stress applied just before forming the sheets. Dewatering and strength results were generally more favorable when using a medium charge cationic starch (~ 0.03 degree of substitution, DS) to pretreat the NFC rather than a high charge density cationic starch (~ 0.2 DS). In each case, the dewatering was further enhanced by subsequent treatments by cPAM (0.1% on whole furnish solids) and then even more with the final addition of colloidal silica (0.1% and 0.2% levels compared). However, the colloidal silica additions progressively hurt the tensile strength of the paper, especially in the case of the high charge cationic starch and at the higher level of colloidal silica. Though the dewatering performance was favorable, in such cases, the paper strength was not improved compared to paper made without any NFC. The fact that the systems involving cPAM treatment, and especially those involving both cPAM and colloidal silica, tended to reduce the resulting paper’s tensile strength supports a mechanism in which the additives result in the clustering of the NFC, possibly in multiparticle bunches. Evidence suggests that such bunches of clustered NFC particles, which are difficult to redisperse even at levels of hydrodynamic shear present in high-speed paper machine systems, are resistant to full integration into the sheet structure as the paper is being formed.
Journal articles
Magazine articles
Boiler retrofit improves efficiency and increases biomass firing rates, TAPPI Journal March 2021
ABSTRACT: Domtar’s fluff pulp mill in Plymouth, NC, USA, operates two biomass/hog fuel fired boilers (HFBs). For energy consolidation and reliability improvement, Domtar wanted to decommission the No. 1 HFB and refurbish/retrofit the No. 2 HFB. The No. 2 HFB was designed to burn pulverized coal and/or biomass on a traveling grate. The steaming capacity was 500,000 lb/h from coal and 400,000 lb/h from biomass. However, it had never sustained this design biomass steaming rate. As the sole power boiler, the No. 2 HFB would need to sustain 400,000 lb/h of biomass steam during peak loads. An extensive evaluation by a combustion and boiler technologies supplier was undertaken. The evaluation involved field testing, analysis, and computational fluid dynamics (CFD) modeling, and it identified several bottle-necks and deficiencies to achieving the No. 2 HFB’s biomass steam goal. These bottlenecks included an inadequate combustion system; insufficient heat capture; excessive combustion air temperature; inadequate sweetwater con-denser (SWC) capacity; and limited induced draft fan capacity.To address the identified deficiencies, various upgrades were engineered and implemented. These upgrades included modern pneumatic fuel distributors; a modern sidewall, interlaced overfire air (OFA) system; a new, larger economizer; modified feedwater piping to increase SWC capacity; replacement of the scrubber with a dry electrostatic precipitator; and upgraded boiler controls.With the deployment of these upgrades, the No. 2 HFB achieved the targeted biomass steaming rate of 400,000 lb/h, along with lowered stack gas and combustion air temperatures. All mandated emissions limit tests at 500,000 lb/h of steam with 400,000 lb/h of biomass steam were passed, and Domtar reports a 10% reduction in fuel firing rates, which represents significant fuel savings. In addition, the mill was able to decommission the No. 1 HFB, which has substantially lowered operating and maintenance costs.
Journal articles
Magazine articles
Commercially relevant water vapor barrier properties of high amylose starch acetates: Fact or fiction?, TAPPI Journal September 2021
ABSTRACT: Starches have recently regained attention as ecofriendly barrier materials due to the increased demand for sustainable packaging. They are easily processable by conventional plastics processing equipment and have been utilized for oil and grease barrier applications. While starches have excellent oxygen barrier properties and decent water barrier properties at low relative humidity (RH), they are moisture sensitive, as demonstrated by the deterioration of the barrier properties at higher RH values. Starch esters are chemically modified starches where the hydroxyl group of the starch has been substituted by other moieties such as acetates. This imparts hydrophobicity to starches and has been claimed as a good way of retaining water vapor barrier properties of starches, even at high RH conditions. We studied the water vapor barrier properties of one class of starch esters, i.e., high amylose starch acetates that were assumed to have good water vapor barrier properties. Our investigations found that with a high degree of substitution of hydroxyl groups, the modified starches did indeed show improvements in water vapor response as compared to pure high amylose starch films; however, the barrier properties were orders of magnitude lower than commercially used water vapor barriers like polyethylene. Even though these materials had improved water vapor barrier response, high amylose starch acetates are likely unsuitable as water vapor barriers by themselves, as implied by previous literature studies and patents.
Journal articles
Exploratory study on how sub-ply fiber orientation affects t
ABSTRACT: The transition to 100% biobased packaging presents considerable challenges, particularly in the development of a petroleum-free barrier. Generally, biobased barriers exhibit lower flexibility compared to traditional barriers, thereby increasing the risk of cracking during the converting process. The present study examines the possibility of optimizing the substrate to reduce cracking in brittle barriers. Five three-ply composites were fabricated using commercial paperboard to enable a composite with different fiber orientation in the individual plies. The different orientations achieved varying mechanical properties, including strain-atbreak and folding resistance, with a ranking that is comparable to a standard multi-ply paperboard. The composites were subjected to creasing at five distinct depths to assess the area percent of barrier cracks across the crease bead. Micro-cracks appeared on the surface before larger coating cracks were registered. As expected, the area percent of barrier cracks increased significantly with greater creasing depths. The orientation of the bulky middle ply showed little difference in the cracking propensity. However, by replacing the stiffer bottom ply with a ply of lower stiffness, the cracking propensity was significantly reduced without a substantial loss in mechanical properties. Hence, these findings indicate that it is possible to reduce the cracks in the barrier by modifying the fiber orientation in the different plies.
Journal articles
Improving barrier performance of coated paper and paperboard
ABSTRACT: Market demand for barrier coated packaging paper and paperboard has been on a steady rise and is forecasted to further increase. As a result, there is a continued interest in improving barrier coating functionalities, which is currently an active area of investigation. In this work, a multi-layer approach was adopted that involved applying a biowax emulsion, latex, or a combination of biowax and latex top coating layer onto the kaolin/latex (20/80, 50/50, 65/35, or 70/30) precoated solid bleached sulfate (SBS) paperboard. Our main objective was to demonstrate the effect of these top coating layers on various barrier properties, especially water vapor transmission rate (WVTR) at high relative humidity (RH) and high temperature (90% RH; 38°C), known as tropical/jungle test conditions. While the top coat with latex and/or biowax showed dramatic improvement in both water resistance (Cobb) and WVTR, the biowax coating increased contact angle significantly compared to the latex top coat. Contact angle increased from about 65° for the latex top coat to as high as 96° for the biowax top coat. Generally, it is much more difficult to improve WVTR at the jungle conditions below 100 g/m2/day, even with the high aspect ratio platy pigment. However, using the coating strategies adopted in this study, we were able to achieve WVTR values notably below 50 g/m2/day at the tropical test conditions, as well as significant improvements in regard to fold crack barrier integrity at high kaolin clay usage.
Journal articles
Prediction of residual calcium carbonate (CaCO3) in the lime
ABSTRACT: In a kraft pulp mill, the rotary lime kiln is responsible for converting calcium carbonate (CaCO3) into calcium oxide (CaO) to be reused in the causticizing plant. An important parameter of the calcination efficiency and the product quality is the amount of CaCO3 not converted to CaO, commonly defined as residual carbonate. This parameter is usually determined through laboratory analysis, which introduces delays in process control and limits the ability to make timely operational adjustments. This work presents a predictive model that functions as a soft sensor for the residual carbonate in a lime kiln of a Brazilian kraft pulp mill. This model was able to estimate residual CaCO3 every 30 min using routinely measured online process variables, which is a considerable reduction from the 6-h average laboratory measurement. The correlation coefficient (r) between the model predictions and the mill values was 0.83, with a mean absolute error (MAE) of 0.33%. Considering the effect of the residence time throughout the lime kiln proved to be decisive in obtaining a satisfactory prediction result. After model validation, a variable importance analysis showed that the carbon monoxide (CO) concentration in the stack flue gas (in ppm), secondary air temperature (in oC), and fan speed (in %) were the most influential variables in predicting the residual carbonate content. Combined with commonly used operation expertise, this subset of variables can serve as additional information to achieve smoother lime kiln operation.
Journal articles
ABSTRACT: This study investigates the impact of pulp screening on oxygen delignification of high lignin content kraft pulps from spruce wood. An alternative process is proposed: terminating kraft cooking at higher kappa numbers and applying oxygen deligni
ABSTRACT: This study investigates the impact of pulp screening on oxygen delignification of high lignin content kraft pulps from spruce wood. An alternative process is proposed: terminating kraft cooking at higher kappa numbers and applying oxygen delignification directly to unscreened and non-defibrated pulp. The objective is to evaluate whether this non-standard approach can maintain delignification efficiency while improving yield and reducing energy input. The findings demonstrate that screening prior to oxygen delignification is not essential for effective lignin removal or pulp quality. Similar delignification degrees and ISO brightness levels were obtained after oxygen delignification, whether it was performed on screened or unscreened pulps. Notably, the delignification rate in the oxygen stage was the same for the non-standard procedure as for pulp from the standard procedure with the reject fractionremoved prior to the oxygen stage. No significant differences were seen in fiber morphology, brightness level, orbrightness stability. The amount of total fiber charges in pulps not screened before oxygen delignification was slightly higher than in screened pulps.
Journal articles
ABSTRACT: Lignin’s potential as a source of sustainable aromatic compounds is significant, but its utilization is currently limited by its chemical reactivity. Chemical reactivity of lignin depends on the present functional groups, such as hydroxyl, metho
ABSTRACT: Lignin’s potential as a source of sustainable aromatic compounds is significant, but its utilization is currently limited by its chemical reactivity. Chemical reactivity of lignin depends on the present functional groups, such as hydroxyl, methoxy, and carbonyl groups. Therefore, in this study, multivariate analysis-based chemometric models have been developed for rapid determination of aliphatic hydroxyl (Alp-OH) and phenolic hydroxyl (Ph-OH) groups in lignin samples. Two chemometric models, principal component regression (PCR) and partial least squares regression (PLSR), were established with Fourier transform infrared spectroscopy (FTIR) spectral data of 28 lignin samples. Both the models were developed based on raw and pretreated spectroscopic data with Savitky-Golay (S-G) filtering and standard normal variate (SNV) and multiplicative scatter correction (MSC). The predictive performance of the PLSR model is better for predicting Alp-OH (R2 = 0.94%), syringyl-OH (R2 = 0.96%), guaiacyl-OH (R2 = 0.98%), p-hydroxyphenyl (R2 = 0.93%), and total Ph-OH groups (R2 = 0.97%) with the data pretreated by MSC. Finally, the predicted results of these parameters for three new samples for the developed models are found to be very close to the estimated values by NMR.