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Journal articles
Magazine articles
Open Access
Modeling and parameter optimization of the papermaking processes by using regression tree model and full factorial design, TAPPI Journal February 2021

ABSTRACT: One of the major challenges in the pulp and paper industry is taking advantage of the large amount of data generated through its processes in order to develop models for optimization purposes, mainly in the papermaking, where the current practice for solving optimization problems is the error-proofing method. First, the multiple linear regression technique is applied to find the variables that affect the output pressure controlling the gap of the paper sheet between the rod sizer and spooner sections, which is the main cause of paper breaks. As a measure to determine the predictive capacity of the adjusted model, the coefficient of determination (R2) and s values for the output pressure were considered, while the variance inflation factor was used to identify and eliminate the collinearity problem. Considering the same amount of data available by using machine learning, the regression tree was the best model based on the root mean square error (RSME) and R2. To find the optimal operating conditions using the regression tree model as source of output pressure measurement, a full factorial design was developed. Using an alpha level of 5%, findings show that linear regression and the regression tree model found only four independent variables as significant; thus, the regression tree model demonstrated a clear advantage over the linear regression model alone by improving operating conditions and demonstrating less variability in output pressure. Furthermore, in the present work, it was demonstrated that the adjusted models with good predictive capacity can be used to design noninvasive experiments and obtain.

Journal articles
Magazine articles
Open Access
Understanding wet tear strength at varying moisture content in handsheets, TAPPI Journal January 2021

ABSTRACT: A laboratory study was conducted looking at the effects of moisture content on wet tear strength in handsheets. Three different wetting techniques were used to generate the wet tear (Elmendorf-type) data at varying moisture levels, from TAPPI standard conditions (dry) to over 60% moisture content (saturated). Unbleached hardwood and softwood fiber from full-scale kraft pulp production were used. The softwood fiber was refined using a Valley beater to reduce freeness. Handsheets were made with a blend of hardwood and softwood and with refined softwood, without the addition of wet-end chemistry. The resulting grams-force tear data obtained from the test was indexed with basis weight and plotted versus both moisture content and dryness. As moisture content levels in the handsheets increased, the wet tear strength also increased, reaching a critical maximum point. This marked a transition point on the graph where, beyond a critical moisture content level, the tear strength began to decline linearly as moisture increased. This pattern was repeated in handsheets made from a blend of hardwood and softwood and from 100% refined softwood.

Journal articles
Magazine articles
Open Access
The effect of microfibrillated cellulose on the wet-web strength of paper, TAPPI Journal January 2021

ABSTRACT: The wet-web strength of paper immediately after the press section of a paper machine is a critical factor in determining machine runnability. However, it is difficult to determine at commercial scale, because the web has to be broken and production interrupted in order to obtain a sample for measurement. The use of microfibrillated cellulose (MFC) is believed to increase wet-web strength, as it has allowed filler level increases of 10% or more on many commercial paper machines. In this paper, we describe a laboratory method for estimating the effect of MFC on wet sheet strength after press-ing, as well as actual measurements of wet-web strength from a pilot paper machine trial. These experiments have demonstrated the positive effect of MFC. At solids contents in the range typically observed after pressing, sheets with MFC at fixed filler content are significantly stronger, but also wetter, than those without it. When the use of MFC is combined with a typical increase in filler content, the wet web remains slightly stronger, but also becomes drier than the reference condition. These results are compatible with the theory put forward by van de Ven that wet-web strength is mainly a result of friction between entangled fibers, and they also suggest that the presence of MFC increases this friction.

Journal articles
Magazine articles
Open Access
Investigation of the influencing factors in odor emission from wet-end white water, TAPPI Journal October 2020

ABSTRACT: Emission of malodorous gases, such as volatile organic compounds (VOCs), hydrogen sulfide (H2S), and ammonia (NH3) during pulping and papermaking has caused certain harm to the air environment and human health. This paper investigated the influencing factors of odor emission from wet-end white water during the production of bobbin paper in a papermaking mill using old corrugated containers (OCC) as raw material. The concentration of malodorous gases emitted from wet-end white water was determined with pump-suction gas detectors. The results indicated that low temperature could limit the release of malodorous gases from white water. Specifically, no total volatile organic compounds (TVOC), H2S, and NH3 was detected at a temperature of 15°C. The concentrations of malodorous gases were slightly increased when temperature increased to 25°C. When temperature was 55°C, the released concentrations of TVOC, H2S, and NH3 were 22.3 mg/m3, 5.91 mg/m3, and 2.78 mg/m3, respectively. Therefore, the content of malodorous gases significantly increased with the temperature increase. The stirring of white water accelerated the release of malodorous gases, and the release rate sped up as the stirring speed increased. However, the total amount of malodorous gases released were basically the same as the static state. Furthermore, the higher the concentration of white water, the greater the amount of malodorous gases released. The pH had little influence on the TVOC release, whereas it significantly affected the release of H2S and NH3. With the increase of pH value, the released amount of H2S and NH3 gradually decreased. When pH reached 9.0, the release amount of H2S and NH3 was almost zero, proving that an alkaline condition inhibits the release of H2S and NH3.

Journal articles
Magazine articles
Open Access
Creasing severity and reverse-side cracking, TAPPI Journal April 2020

ABSTRACT: Crease cracking can be detrimental to the functionality and appearance of paperboard-based packaging. The effect of creasing severity on the degree of reverse-side crease cracking (bead-side of the crease) of paperboard was investigated. Samples were creased with a range of rule and channel geometries, and the cracking degree was quantified as the percent of cracked length relative to the total length of the crease. The cracking degree was typically below 5% at low crease penetration depths, but was exponentially higher beyond a critical penetration depth. A rule and channel combination with a wider clearance shifted the critical depth to larger values. The creasing severity parameter, termed the creasing draw, converged the cracking degree data from different rule and channel combinations to a single curve. The creasing draw was derived from the same analytical expres-sions as the transverse shear strain and quantifies the length of paper that is drawn into the channel during creasing. The critical draw is defined as the draw at which cracking becomes greater than 5%, which corresponds with the point at which cracking becomes exponential. The critical draw is a material/system parameter that defines the level below which cracking is minimal.

Journal articles
Magazine articles
Open Access
Stiffness and strength properties of five paperboards and their moisture dependency, TAPPI Journal February 2020

ABSTRACT: Five commercial multiply folding boxboards made on the same paperboard machine have been analyzed. The paperboards were from the same product series but had different grammage (235, 255, 270, 315, 340 g/m2) and different bending stiffness. The paperboards are normally used to make packages, and because the bending stiffness and grammage varies, the performance of the packages will differ. Finite element simulations can be used to predict these differences, but for this to occur, the stiffness and strength properties need to be deter-mined. For efficient determination of the three-dimensional properties in the machine direction (MD), cross direction (CD), and Z direction (ZD), it is proposed that the paperboard should be characterized using in-plane tension, ZD-tension, shear strength profiles, and two-point bending. The proposed setups have been used to determine stiff-ness and strength properties at different relative humidity (20,% 50%, 70%, and 90% RH), and the mechanical proper-ties have been evaluated as a function of moisture ratio.There was a linear relation between mechanical properties and moisture ratio for each paperboard. When the data was normalized with respect to the standard climate (50% RH) and plotted as a function of moisture ratio, it was shown that the normalized mechanical properties for all paperboards coincided along one single line and could therefore be expressed as a linear function of moisture ratio and two constants.Consequently, it is possible to obtain the mechanical properties of a paperboard by knowing the structural properties for the preferred level of RH and the mechanical property for the standard climate (50% RH and 23°C).

Journal articles
Magazine articles
Open Access
Rheological characterization of tack and viscoelasticity of compositions of crepe coating used in the Yankee dryer, TAPPI Journal November 2019

ABSTRACT: The vast majority of tissue production uses creping to achieve the required set of properties on the base sheet. The Yankee coating helps to develop the desired crepe that in turn determines properties such as bulk and softness. The adhesion of the sheet to the Yankee surface is a very important characteristic to consider in achieving the desired crepe. The coating mix usually consists of the adhesive, modifier, and release. A good combination of these components is essential to achieving the desired properties of the tissue or towel, which often are determined by trials on the machine that can be time consuming and lead to costly rejects. In this paper, five compo-sitions of an industrial Yankee coating adhesive, modifier, and release were examined rheologically. The weight ratio of the adhesive was kept constant at 30% in all five compositions and the modifier and release ratios were varied. The normal force and work done by the different compositions have been shown at various temperatures simulating that of the Yankee surface, and the oscillatory test was carried out to explain the linear and nonlinear viscoelastic characteristic of the optimal coating composition.

Journal articles
Magazine articles
Open Access
A novel predictive method for filler coflocculation with cellulose microfibrils, TAPPI Journal November 2019

ABSTRACT: Different strategies aimed at reducing the negative impact of fillers on paper strength have been the objective of many studies during the past few decades. Some new strategies have even been patented or commercialized, yet a complete study on the behavior of the filler flocs and their effect on retention, drainage, and formation has not been found in literature. This type of research on fillers is often limited by difficulties in simulating high levels of shear at laboratory scale similar to those at mill scale. To address this challenge, a combination of techniques was used to compare preflocculation (i.e., filler is flocculated before addition to the pulp) with coflocculation strategies (i.e., filler is mixed with a binder and flocculated before addition to the pulp). The effect on filler and fiber flocs size was studied in a pilot flow loop using focal beam reflectance measurement (FBRM) and image analysis. Flocs obtained with cationic polyacrylamide (CPAM) and benonite were shown to have similar shear resistance with both strategies, whereas cationic starch (CS) was clearly more advantageous when coflocculation strategy was used. The effect of flocculation strategy on drainage rate, STFI formation, ash retention, and standard strength properties was measured. Coflocculation of filler with CPAM plus bentonite or CS showed promising results and produced sheets with high strength but had a negative impact on wire dewatering, opening a door for further optimization.

Journal articles
Magazine articles
Open Access
Lignin-based resins for kraft paper applications, TAPPI Journal November 2019

ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.

Journal articles
Magazine articles
Open Access
Creating adaptive predictions for packaging-critical quality parameters using advanced analytics and machine learning, TAPPI Journal November 2019

ABSTRACT: Packaging manufacturers are challenged to achieve consistent strength targets and maximize pro-duction while reducing costs through smarter fiber utilization, chemical optimization, energy reduction, and more. With innovative instrumentation readily accessible, mills are collecting vast amounts of data that provide them with ever increasing visibility into their processes. Turning this visibility into actionable insight is key to successfully exceeding customer expectations and reducing costs. Predictive analytics supported by machine learning can provide real-time quality measures that remain robust and accurate in the face of changing machine conditions. These adaptive quality “soft sensors” allow for more informed, on-the-fly process changes; fast change detection; and process control optimization without requiring periodic model tuning.The use of predictive modeling in the paper industry has increased in recent years; however, little attention has been given to packaging finished quality. The use of machine learning to maintain prediction relevancy under ever-changing machine conditions is novel. In this paper, we demonstrate the process of establishing real-time, adaptive quality predictions in an industry focused on reel-to-reel quality control, and we discuss the value created through the availability and use of real-time critical quality.