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Lignin-based resins for kraft paper applications, TAPPI Journal November 2019
ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.
Journal articles
Fundamental study on developing wood powder as an additive of paperboard, TAPPI JOURNAL November 2014
Fundamental study on developing wood powder as an additive of paperboard, TAPPI JOURNAL November 2014
Journal articles
Editorial: TJ editorial board members review 2013 PEERS, IBBC and Research Forum on Recycling, TAPPI JOURNAL September 2013
Editorial: TJ editorial board members review 2013 PEERS, IBBC and Research Forum on Recycling, TAPPI JOURNAL September 2013
Journal articles
Evaluation of Various Mechanical Pulping Processes for Mature and Juvenile Loblolly Pine in Lightweight Coated Paper, TAPPI JOURNAL March 2009
Evaluation of Various Mechanical Pulping Processes for Mature and Juvenile Loblolly Pine in Lightweight Coated Paper, TAPPI JOURNAL March 2009
Journal articles
Prediction of the Solubility of Recovery Boiler Precipitator Ash, TAPPI JOURNAL May 2009
Prediction of the Solubility of Recovery Boiler Precipitator Ash, TAPPI JOURNAL May 2009
Journal articles
Linking Pulp Variations to TMP Operation by Better Selection
Linking Pulp Variations to TMP Operation by Better Selection and Treatment of Process Data
Journal articles
The influence of pigment particle shape on the in-plane tensile strength properties of kaolin-based coating layers, TAPPI JOURNAL
The influence of pigment particle shape on the in-plane tensile strength properties of kaolin-based coating layers, TAPPI JOURNAL
Journal articles
Application of lipase to reduce ONP flotation rejects: Part 2. Reduction of flotation rejects, TAPPI JOURNAL, August 2008
Application of lipase to reduce ONP flotation rejects: Part 2. Reduction of flotation rejects, TAPPI JOURNAL, August 2008
Journal articles
The Effectiveness of TAED on the Peroxide Bleaching
The Effectiveness of TAED on the Peroxide Bleaching of Mechanical, Chemical, and Recycled Pulp
Journal articles
Spectroscopic imaging ellipsometry of wood fiber cell walls: a comparison with confocal microscopy, TAPPI JOURNAL, August 2007
Spectroscopic imaging ellipsometry of wood fiber cell walls: a comparison with confocal microscopy, TAPPI JOURNAL, August 2007