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Using novel DNA methods to achieve higher process efficiency and performance, TAPPI Journal January 2023
ABSTRACT: Uncontrolled microbiological activity is a challenge for recycled fiber (RCF) mills as it can have negative effects on production and end-product quality. The microbes that exist in these systems have been largely unknown, and the strategies employed to control microbiology have been non-specific. Understanding the specific microbial groups present in RCF mills, their properties, and where they exist, as well as having the ability to accurately measure the true troublemakers, are key to targeted control of the bad actors. In this study, we present the results of a global survey of over 40 RCF paper machines. The same RCF-specific problem-causing bacterial groups were found on different continents, including large densities of newly identified bacteria in paper processes. Those can degrade cellulose and starch, produce acids and odorous substances, and have a significant impact on fiber strength and additive consumption. We also demonstrate how modern DNA tools can quantify the impact of biocidal countermeasures against the actual troublemakers, including bacteria found to degrade cellulose during RCF pulp storage, which may be linked to a negative impact on end-product strength. These novel DNA tools give producers updated biocide program key performance indicators (KPIs) and actionable information to more effectively design and adjust microbiological control to achieve higher process efficiency and performance.
Journal articles
Magazine articles
Editorial: Critical literature reviews in open source journals, TAPPI Journal June 2023
ABSTRACT: We stand on the shoulders of giants” is a famous metaphor used by Sir Isaac Newton. This testifies to the fact that new information or discoveries are built on understanding and analyzing earlier information. Particularly in science, technology, engineering, and math (STEM) fields, it is important to have thorough analysis of earlier research activities in a particular field to propose a new direction of research, to evolve new ideas, and to develop new test methods and standards. It is a mandatory and required aspect of every original research paper to have a Literature Review section in the introductory part of the paper.
Journal articles
Magazine articles
Non-process elements in the recovery cycle of six Finnish kraft pulp mills, TAPPI Journal March 2023
ABSTRACT: In this work, the aim was to study the distribution and accumulation of the non-process elements (NPEs) in the recovery cycle of Finnish pulp mills and look at whether the geographical location (North vs. South) correlates with the current Finnish NPE levels. In addition, a comparison to older similar Finnish measurements was made with an attempt to analyze the reasons behind differences in the most typical non-process elements, aluminum (Al), silicon (Si), calcium (Ca), phosphorus (P), magnesium (Mg), manganese (Mn), chlorine (Cl), and potassium (K), taking into account the main elements in the white liquor, sodium (Na) and sulfur (S). The extensive laboratory results gained in this study are from seven sampling points at six pulp mills and present analytical data of metal concentrations. The data obtained presents an update to previous NPE studies. The levels found did not statistically differ between North and South Finland. The NPE levels, apart from phosphorus, found in Finnish pulp mills today have not changed considerably compared to the levels in earlier investigations in the 1990s. In the newest data, the phosphorus concentration was consistently higher in the as fired black liquor, electrostatic precipitator (ESP) ash, lime mud, and green liquor than in the previous results. In addition, the levels of Al, Si, Ca, P, and Mg in recovery boiler ESP ash were consistently higher compared to the older results. As the mills start to close their systems more, a stronger accumulation of NPEs can be expected, increasing the likelihood of more operational problems in the process. Further understanding of where the NPEs accumulate and how they can be most effectively removed will be valuable knowledge in the future.
Journal articles
Magazine articles
Dissolution of wood components during hot water extraction of spruce, TAPPI Journal May 2023
ABSTRACT: The purpose of this study was to investigate the autohydrolysis of softwood, which is the main chemical operation in both hot water extraction and steam explosion. Control of the process and monitoring its course were ensured by the careful choice of experimental setup and conditions: a milled spruce material was extracted in a small flow-through reactor to minimize degradation of the dissolved material and to enable analysis of the resulting liquors extracted at selected time points. The obtained liquid and solid fractions were analyzed for sugar composition and acetic acid concentration. The results showed that partially degraded hemicelluloses were extracted; hemicelluloses side chains were cleaved off and detected as monomers, while deacetylation was limited. Chain scissions of cellulose were observed as a result of autohydrolysis.
Journal articles
Magazine articles
Paper bending stiffness and web tension measurement from a running web using a vacuum and computer imaging, TAPPI Journal May 2023
ABSTRACT: A novel method for measuring the bending stiffness of paper online during manufacturing is introduced. The method uses photometric stereo imaging to detect the shape of the deflection surface caused by a controllable pressure difference over the paper’s surfaces. The hardware for the measurement is based on a combination of two existing sensors, which has accelerated and facilitated the development of the implementation. The deflection and loads are tied together by the governing differential equation for the bending of an orthotropic elastic plate with selected simplifications. An approach to resolve material parameters and in-plane loads without knowledge of traditional boundary conditions is suggested. The presented method was tested in a paper mill during manufacturing. For bending stiffnesses measured online, correlation coefficients 0.88 and 0.92 were obtained compared to state-of-the-art laboratory measurements. However, the results gained from a moving web are noisy and the data requires correction of the slope and an off-set. Although several issues remain to be resolved before the method can be considered as an accurate measurement for industrial use, the theoretical background, the performance of online implementation, and the results are promising. Possible causes for the observed discrepancies and the future development of the method are discussed.
Journal articles
Magazine articles
Editorial: Special coating issue contains highlighted works from TAPPICon 2023, TAPPI Journal November 2023
ABSTRACT: Did you know that TAPPI’s Coating and Graphic Arts Division has changed its name to Coating, Printing, and Surface Enhancement (CPSE) Division? This change occurred mid-year, as our members realized that the new name fits much better with the day-to-day workings of the Division, as well as the broader activities to functionalize and add value to paper and paperboard that continue to expand into new arenas.
Journal articles
Magazine articles
Surface modification of TiO2 with MPS and its effects on the wettability and physical properties of Kawayan Kiling (Bambusa vulgaris Schrad ex. Wendl) handsheets, TAPPI Jouranl April 2024
ABSTRACT: The need for hydrophobic papers has steadily increased over past years. These papers are often sought after as packaging materials and have high demand in the food industry and medicine. In this study, various concentrations of surface-modified TiO2-MPS were added to Kawayan Kiling (B. vulgaris) pulp at the wet-end section of handsheet formation. Surface-modified TiO2-MPS was made from nano-titanium (IV) oxide using 3-(trimethoxysilyl)propyl methacrylate as a coupling agent. The wettability of handsheets and physical properties were tested using various standard methods. Results reveal that the handsheets without surface-modified TiO2-MPS had the lowest water contact angle (WCA), while the handsheet with 12.34% (w/w) surface-modified TiO2-MPS had the highest WCA. At 17% (w/w) surfacemodified TiO2-MPS, the WCA rapidly declined. Handsheets with surface-modified TiO2-MPS have a rougher surface compared to the handsheets without chemicals and handsheets with unmodified TiO2. This roughness made the handsheet hydrophobic. The handsheet with 12.34% (w/w) unmodified TiO2 has a smoother surface than the control handsheet. Energy-dispersive X-ray spectroscopy (EDS) analysis shows that the handsheet with 12.34% (w/w) unmodified TiO2 contained titanium, while the handsheet with 12.34% (w/w) surface-modified TiO2-MPS contained both titanium and silicon. Generally, the physical properties of handsheets improved with surface-modified TiO2- MPS, especially grammage, bulk thickness, tensile index, and water absorptiveness, which showed statistically significant differences across treatments. The tear index did not differ between treatments.
Magazine articles
Calcium based sulfur recovery process for kraft black liquor gasification - proof of concept', TAPPI JOURNAL, July 2000, Vol. 83(7)
Calcium based sulfur recovery process for kraft black liquor gasification - proof of concept', TAPPI JOURNAL, July 2000, Vol. 83(7)
Magazine articles
Shop talk: concerning coefficient of friction, TAPPI JOURNAL, June 2000, Vol. 83(6)
Shop talk: concerning coefficient of friction, TAPPI JOURNAL, June 2000, Vol. 83(6)
Magazine articles
Reliability of stainless alloy equipment in chlorine dioxide bleaching, TAPPI JOURNAL, November 2000, Vol. 83(11)
Reliability of stainless alloy equipment in chlorine dioxide bleaching, TAPPI JOURNAL, November 2000, Vol. 83(11)