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Factors affecting the free shrinkage of handsheets: apparent density, fines content, water retention value, and grammage, TAPPI JOURNAL June 2018
Factors affecting the free shrinkage of handsheets: apparent density, fines content, water retention value, and grammage, TAPPI JOURNAL June 2018
Journal articles
Magazine articles
Using online bubble size and total dissolved solids measurements to investigate the performance of oxygen delignification, TAPPI JOURNAL June 2018
Using online bubble size and total dissolved solids measurements to investigate the performance of oxygen delignification, TAPPI JOURNAL June 2018
Journal articles
Magazine articles
Using multistage models to evaluate how pulp washing after the first extraction stage impacts elemental chlorine-free bleach demand, TAPPI Journal November 2018
Using multistage models to evaluate how pulp washing after the first extraction stage impacts elemental chlorine-free bleach demand, TAPPI Journal November 2018
Journal articles
Magazine articles
Production of polyhydroxyalkanoates (PHA)-based renewable packaging materials using photonic energy: A bench and pilot-scale study, TAPPI Journal October 2018
Production of polyhydroxyalkanoates (PHA)-based renewable packaging materials using photonic energy: A bench and pilot-scale study, TAPPI Journal October 2018
Journal articles
Magazine articles
A guide to eliminating baggy webs, TAPPI Journal June 2021
ABSTRACT: Slack or baggy webs can cause misregistration, wrinkles, and breaks in printing and converting operations. Bagginess appears as non-uniform tautness in the cross direction (CD) of a paper web. The underlying cause is uneven CD tension profiles, for which there are few remedies once the paper is made. Precision measurements of CD tension profiles combined with trials on commercial paper machines have shown that uniform CD distribution of moisture, basis weight, and caliper profiles at the reel are key to avoiding bagginess. However, the most important but infrequently measured factor is the CD moisture profile entering the dryer section. Wetter areas entering the dryers are permanently elongated more than dry areas, leading to greater slackness in the finished paper. In storage, wound-in tension can amplify baggy streaks in paper near the surface of a roll and adjacent to the core. Unwrapped or poorly wrapped rolls exposed to low humidity environments may have baggy centers caused by moisture loss from the roll edges.All of the factors that impact bagginess have been incorporated in a mathematical model that was used to interpret the observations from commercial trials and can be used as a guide to solve future problems.
Journal articles
Magazine articles
Investigation of the influencing factors in odor emission from wet-end white water, TAPPI Journal October 2020
ABSTRACT: Emission of malodorous gases, such as volatile organic compounds (VOCs), hydrogen sulfide (H2S), and ammonia (NH3) during pulping and papermaking has caused certain harm to the air environment and human health. This paper investigated the influencing factors of odor emission from wet-end white water during the production of bobbin paper in a papermaking mill using old corrugated containers (OCC) as raw material. The concentration of malodorous gases emitted from wet-end white water was determined with pump-suction gas detectors. The results indicated that low temperature could limit the release of malodorous gases from white water. Specifically, no total volatile organic compounds (TVOC), H2S, and NH3 was detected at a temperature of 15°C. The concentrations of malodorous gases were slightly increased when temperature increased to 25°C. When temperature was 55°C, the released concentrations of TVOC, H2S, and NH3 were 22.3 mg/m3, 5.91 mg/m3, and 2.78 mg/m3, respectively. Therefore, the content of malodorous gases significantly increased with the temperature increase. The stirring of white water accelerated the release of malodorous gases, and the release rate sped up as the stirring speed increased. However, the total amount of malodorous gases released were basically the same as the static state. Furthermore, the higher the concentration of white water, the greater the amount of malodorous gases released. The pH had little influence on the TVOC release, whereas it significantly affected the release of H2S and NH3. With the increase of pH value, the released amount of H2S and NH3 gradually decreased. When pH reached 9.0, the release amount of H2S and NH3 was almost zero, proving that an alkaline condition inhibits the release of H2S and NH3.
Journal articles
ABSTRACT: Laboratory experiments with bleached kraft furnish were carried out to quantify the effects of major differences in electrical conductivity of papermaking process water (due to the addition of sodium sulfate) on the performance of various paperm
ABSTRACT: Laboratory experiments with bleached kraft furnish were carried out to quantify the effects of major differences in electrical conductivity of papermaking process water (due to the addition of sodium sulfate) on the performance of various papermaking additives. Batches of refined pulp were prepared with conductivity levels of 168 (tap water), 1000, and 10,000 ìS/cm. The absolute values of the calculated zeta potential, in various cases, were shown to decrease with increasing logarithm of electrical conductivity. The performance of retention aid systems, including cationic polyacrylamide (cPAM), were not adversely affected by increased salinity, even up to an electrical conductivity level of 10,000 ìS/cm. In fact, treatment involving sequential addition of cPAM and colloidal silica showed superior retention of mineral filler at the highest conductivity level. Likewise, combinations of papermaking additives that promote the dewatering of paper continued to perform well in furnish prepared with increasing salinity. The ability of various chemical systems to induce flocculation among papermaking fibers decreased moderately at the highest level of salinity considered.
Journal articles
ABSTRACT: Water hardness, which can be defined as the concentration of calcium and magnesium ions, is known to vary greatly depending on geographical locations. Laboratory tests were carried out to evaluate effects of large differences in water hardness o
ABSTRACT: Water hardness, which can be defined as the concentration of calcium and magnesium ions, is known to vary greatly depending on geographical locations. Laboratory tests were carried out to evaluate effects of large differences in water hardness on the performance of certain wet-end additives to the paper machine process. Tests were carried out at hardness levels of 25, 125, and 225 ppm (as calcium carbonate equivalents). Increased water hardness was found to have a generally negative effect on the performance of a cationic acrylamide- type retention aid, although the extent of performance loss depended on experimental details. Likewise, rates of dewatering in systems containing cationic retention aid were adversely affected by increasing hardness, though the effects were not statistically significant in all cases considered. The tendency of bridge-forming flocculants (cationic retention aid or sequential addition of a cationic additive and then anionic retention aid) fell slightly with increasing water hardness.
Journal articles
Assessing lignin content in Nordic hardwood and softwood species using models based on near-infrared (NIR) spectral data and partial least squares regression (PLSR), TAPPI Journal September 2025
ABSTRACT: Continuous kraft cooking digesters face challenges affecting product quality, making it valuable to improve control through advanced techniques like near-infrared (NIR) spectroscopy, model predictive control, and machine learning models. The primary goal of this study was to use NIR spectra to predict the amount of lignin in hardwood and softwood samples. This study investigated the correlation of NIR derivative spectra with the amounts of lignin relative to other constituents, namely cellulose, hemicellulose, and water, in wood chip samples of varying chip sizes and shapes from six Nordic wood species. It employed partial least squares regression (PLSR) on the NIR data to construct a model that predicted the lignin fraction and the relative fraction of acid-soluble lignin. When trained on a group of five wood species, the model achieved a satisfactory predictive ability, striking a balance between a wide range of lignin content and a consistent chemical environment. The accuracy increased further when the model was restricted only to spruce and pine, reflecting the benefits of a more homogenous dataset. Additionally, the optimal number of latent variables was identified as two, indicating that three distinct chemical components — cellulose, lignin and water — can be effectively differentiated using NIR.
Journal articles
Colloidal silica and its effects during formation of paper sheets in the presence of nanofibrillated cellulose, cationic starch, and cationic acrylamide copolymer, TAPPI Journal May 2025
ABSTRACT: This work considered effects of colloidal silica addition during laboratory preparation of paper sheets containing nanofibrillated cellulose (NFC) that had been pretreated with cationic starch. The emphasis was on process performance issues, including dewatering rates, fine particle retention, and the extent of fiber flocculation. In addition, micrographs were obtained to show what was happening to the NFC upon treatments with cationic starch and subsequent application of hydrodynamic shear. Contrasting results were obtained, depending on the charge density of the cationic starch. Pretreatment of the NFC with a high charge density cationic starch (degree of substitution 0.2) resulted in strong interactions with the colloidal silica, enhancing the dewatering rate and contributing to fine-particle retention. The medium charge cationic starch pretreatment led to effects suggesting a bridging mechanism of action, and subsequent colloidal silica had no significant effect on dewatering. Treatment of that system with a high level of colloidal silica (0.2%) resulted in lower retention. In general, the final colloidal silica treatments tended to decrease the level of flocculation in the suspensions, giving more uniform handsheets. Mechanisms, some of them related to the clustering and dispersion of cationic starch-treated NFC, were proposed to account for the observed effects.