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Flow rheology of light foams generated from aqueous solutions of polyvinyl alcohol, TAPPI Journal January 2023
ABSTRACT: Recent studies have shown that foam-assisted application of additives into a wet web has advantages over the conventional way of adding the chemicals into the pulp suspension before forming, e.g., increased mechanical retention as well as high dosage giving increased wet strength without impairing the sheet uniformity. To engineer processes utilizing this new technology, the complex flow behavior of applied foams must be quantified. At the minimum, the foam viscosity and the slip velocity at the solid surfaces need to be known to build practical models that can be used in analyzing and upscaling unit processes of the foam-assisted application.In this study, the rheological behavior was quantified for foams having polyvinyl alcohol (PVOH), a widely used strength additive chemical, as the surfactant. The foam density was varied between 100 g/L and 300 g/L, and the concentration of the PVOH solution was varied between 0.5% and 6.0% (w/w). The foams were generated with a commercial foam generator, and the rheological properties of the foams were measured by using a horizontal pipe bank. At the outlet from the generator, the volumetric flow rate, the absolute pressure, and the bubble size distribution of the foam were measured. In the measurement pipe section, the viscous pressure gradient and the slip velocity were measured, after which the foam was discharged to ambient air pressure. The viscosity and the dynamic surface tension of the PVOH solutions were quantified with commercial laboratory devices. In the viscosity analysis, the apparent shear rate was calculated from the volumetric flow rate, and the resulting apparent viscosity was translated to real material viscosity data by applying the Weissenberg-Rabinowitsch correction. The results indicated that PVOH foams can be described with high accuracy as shear-thinning power-law fluids where the detailed behavior depends on the foam density and the PVOH concentration. Slip flow, as usual, increased with increasing wall shear stress, but it was also dependent on the PVOH concentration, the air content, and the bubble size. For both the foam viscosity and the slip flow, a correlation was found that described the quantitative behavior of all the studied foams with good accuracy.
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New opportunities in the paper and nonwovens industries with foam-assisted web forming and chemical application, TAPPI Journal January 2023
ABSTRACT: Foam-assisted web forming and chemical application technologies have great potential to improve manufacturing efficiency and product quality in the paper and nonwovens industries. In this study, the benefits of foam forming and foam-assisted application of chemicals were demonstrated in a pilot machine trial. Uniform high-bulk webs of unrefined bleached softwood kraft pulp (BSKP) and viscose fibers were manufactured by foam forming. It was shown that foam formed low-grammage and high-bulk viscose fiber webs can be strengthened by foam-assisted application of latex onto the wet web. Correspondingly, foam-assisted application of carboxymethyl cellulose (CMC) and anionic polyacrylamide (A-PAM) improved the strength of the foam formed low-grammage and high-bulk BSKP web. Overall, the pilot machine results indicated that material cost savings could be achieved and a high-performance product could be manufactured with foam-based technologies.
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Editorial: The road to sustainable packaging: New research on aqueous barrier coating, TAPPI Journal November 2022
Authors: Joel C. Panek and Peter W. Hart | ABSTRACT: This TAPPI Journal Special Coating Issue looks at hot topic research being done in coatings for paper and paperboard. We can feel the “earth shifting” in paper and paper-board packaging due to the strong call by consumers and brand owners for more sustainable and environmentally friendly options. This is the first TAPPI Journal Special Coating Issue to highlight efforts within the paper coating community to produce more sustainable packaging.
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Improvements in oil and grease resistance (OGR) test methodology for waterborne barrier coatings, TAPPI Journal November 2022
ABSTRACT: Paper-based food packaging is becoming more popular due to consumer demands for sustainable packaging options. Waterborne paper coatings that provide performance properties (i.e., resistance to oil and grease) not inherent to paper and board substrates offer improved sustainability profiles over earlier paper treatment options, including fluorocarbon treatment and coating with extruded plastics. The continued development of new paper coating technologies requires re-evaluation of current test methods and development of new methods to ensure lab evaluations can serve as accurate predictors of real-world performance. This paper provides an overview of commonly used oil and grease resistance (OGR) test methods within the paper coatings industry, and then describes improvements and developments made to two key methods: the 3M Kit test and an internally developed oil breakthrough test. The combined use of these adapted methods provides a more efficient testing workflow and a more complete understanding of the OGR performance of barrier coatings.
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Editorial: Ravi Challa brings tissue, nonwovens, and operational expertise to TJ Editorial Board, TAPPI Journal September 2022
ABSTRACT: TAPPI and the TAPPI JOURNAL (TJ) editorial staff would like to welcome a new member to the TJ Editorial Board, Ravi Challa, Ph.D., who is Research & Development (R&D) manager for Suominen Corporation at the company’s Bethune, SC, facility. There, his primary focus is new product development on wetlaid nonwovens paper machines, from maintaining mature technologies and innovation to discovering patterns in paper machine shutdowns and executing nonwovens product development trials.
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Development of reinforced paper and mitigation of the challenges of raw material availability by utilizing Areca nut leaf, TAPPI Journal September 2022
ABSTRACT: Paper industries are facing a raw material crisis and searching for alternate raw materials that may be able to help mitigate the issue. Many industries use agro-waste as a raw material, irrespective of it having low bleachability and poor mechanical strength. Areca nut leaf (ANL) is a nonwood-based material that may be acceptable as an alternate source of raw material that contains 61.5% holocellulose and 13.6% lignin, which is comparable to other agro-wastes and hardwood pulps. Kraft anthraquinone pulping with 20% active alkali as sodium oxide (Na2O), 25% sulfidity, and 0.05% anthraquinone produced 15 kappa pulps with about 38.5% pulping yield. The bleachability of ANL pulp was good, and 83.5% ISO brightness could be achieved using the D0(EOP)D1 bleaching sequence. The ANL fiber has 33.8% better tensile, 54.5% better tear, and 15.2% better burst index than hardwood fiber. Similarly, 60.4% better tensile, 56.5% better tear, and 21.7% better burst index were observed in ANL than in wheat straw. Thus, the study revealed that Areca nut leaf can be used as an alternative raw material for papermaking, as well as to improve the physical property of paper products by blending it with inferior quality pulp.
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Economic and competitive potential of lignin-based thermoplastics using a multicriteria decision-making method, TAPPI Journal September 2022
ABSTRACT: As a result of new lignin extraction plants hatching and increasing volumes of technical lignin becoming available, a variety of lignin derivatives, including phenolic resins and polyurethane (PU) foams, are reaching the marketplace or being used as intermediate products in many industrial applications. In the spectrum of possible lignin derivatives, thermoplastics appear particularly attractive due to a symbiosis of market, policy, and technology drivers. To assess the preferredness for lignin-based thermoplastics, this paper adapted a risk-oriented methodology formerly applied to assess lignin usage in various applications (phenol-formaldehyde [PF] resins, PU foams, and carbon fiber applications) to the case of lignin-based thermoplastics using hydroxypropylated lignin (HPL) and miscible blends of lignin and polyethylene oxide (PEO). The HPL is considered for garbage bags and agricultural films applications, while lignin-PEO blends are used as replacement for acrylonitrile butadiene styrene (ABS) in applications such as automotive parts. In the methodology, two phased-implementation strategies were defined for each thermoplastic derivative, considering perspectives for profit maximization (90 metric tons/day integrated units) and revenue growth (350 metric tons/day overall capacity), which were considered for implementation within a softwood kraft pulping mill. A set of six criteria representative of the main economic and market competitiveness issues were employed, and their respective importance weights were obtained in a multicriteria decision-making (MCDM) panel.Early-stage techno-economic estimates were done as a basis for the calculation of decision criteria. Compared to product derivatives previously assessed, capital investment for thermoplastic strategies appeared marginally higher due to the required lignin modification steps (on average 30% higher at similar capacity, and 6% for higher-scale revenue diversification strategies). Higher operating costs were also observed due to increased chemical expenses for all thermoplastic strategies, which are ultimately balanced by revenues associated with targeted thermoplastic products, leading to greater annual margins and cash flow generation over the project lifetime for thermoplastic strategies compared to other product applications (58% to 66% higher on average, at similar scale). Benefits of improved economics were reflected in economic criteria, internal rate of return (IRR), and cash flow on capital employed (CFCE), as well as in the price competitiveness criterion, CPC. Overall, the combination of relatively high lignin content in the plastic formulation and the less costly modification method contributed to lignin-PEO strategies, gaining the top two rankings. Based on their overall scores, both strategies defined for HPL would also integrate the group of “preferred” strategies, but are outranked by strategies that consider lignin positioning on PU foam applications.
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Fiber-based characterization of pulp refining, TAPPI Journal September 2022
ABSTRACT: Fiber development in pulp refining can be characterized by three parameters: number of impacts on pulp, N; energy per impact, I, and bar force on fibers, F. These parameters enable comparisons of radically different refining conditions; determination of intensity for hardwoods and softwoods; assessment of effect of bar width on fiber shortening; and predictions of tensile strength increases.
Journal articles
Magazine articles
Editorial: Impacts from using recycled pizza boxes in furnish: TAPPI Journal’s runner-up to 2021 Best Research Paper, TAPPI Journal August 2022
ABSTRACT: The runner-up to the 2021 TAPPI Journal Best Research Paper was “Incorporation of post-consumer pizza boxes in the recover Fiber Stream: Impact of grease on finished product quality."
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Edge crush testing methods and box compression modeling, TAPPI Journal August 2022
ABSTRACT: While multiple test procedures have been developed to assess the inherent compressive strength of corrugated materials (edge crush test, ECT), limited work has explored the appropriateness of each in the context of box compression modeling. This study incorporates a variety of real-world samples, highlighting the varying challenges different ECT methods face in measuring the intrinsic compressive resistance of combined corrugated board. We examine each of these methods as inputs for different types of models, as well as discuss the propagation of measurement variation through the modeling effort. By highlighting the cases in which a given ECT method no longer proves to be an optimal parameter in box compression strength modeling, we explore how we might better measure this material property.