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Critical parameters for tall oil separation I: The importance of ration of fatty acids to rosin acids, TAPPI Journal September 2019
ABSTRACT: Tall oil is a valuable byproduct in chemical pulping of wood, and its fractions have a large spectrum of applications as chemical precursors, detergents, and fuel. High recovery of tall oil is important for the economic and environmental profile of chemical pulp mills. The purpose of this study was to investigate critical parameters of tall oil separation from black liquor. To investigate this in a controlled way, we developed a model test system using a “synthetic” black liquor (active cooking chemicals OH- and HS- ions), a complete process for soap skimming, and determination of recovered tall oil based on solvent extraction and colorimetric analysis, with good reproducibility. We used the developed system to study the effect of the ratio of fatty acids to rosin acids on tall oil separation. When high amounts of rosin acids were present, tall oil recovery was low, while high content of fatty acids above 60% significantly promoted tall oil separation. Therefore, manipulating the content of fatty acids in black liquor before the soap skimming step can significantly affect the tall oil solubility, and hence its separation. The findings open up chemical ways to improve the tall oil yield.
Journal articles
Magazine articles
A new technique for the measurement of show-through mottle of fine paper, TAPPI Journal September 2019
ABSTRACT: Mottling within print-through and show-through is caused by the variability of the local optical properties of the sheet. This mottling is visually disturbing and a mark of poor paper quality. The ability to predict print-through mottle of printed paper by measuring show-through mottle on the unprinted sheet would be a valuable asset for paper machine control.We examined the relationship between print-through mottle and show-through mottle. We worked with nine samples of 60 lb. uncoated fine paper (90 g/m2), from various North American paper companies, that were printed on an offset press, 400K (400% Black), on both sides. A show-through mottle instrumental determination technique was developed using an existing Fast Fourier Transform-based algorithm. The nine samples examined were ranked similarly by the visual evaluation of print-through mottle and by the instrumental determination of show-through mottle. We thus established that show-through on the unprinted sheet can be used as a reliable predictor of print-through, therefore saving time and money for papermakers. We also found a significant two-sidedness in show-through for some of the samples.
Journal articles
Magazine articles
Slot die coating of nanocellulose on paperboard, TAPPI Journal January 2018
Slot die coating of nanocellulose on paperboard, TAPPI Journal January 2018
Journal articles
Magazine articles
Discrete element method to predict coating failure mechanisms, TAPPI JOURNAL January 2018
Discrete element method to predict coating failure mechanisms, TAPPI JOURNAL January 2018
Journal articles
Magazine articles
Where RCM Fits in the Maintenance Program, Paper360º May/June 2018
Where RCM Fits in the Maintenance Program, Paper360º May/June 2018
Novel Method for Creating Biocides from Process Waters, 2012 PaperCon Conference
Novel Method for Creating Biocides from Process Waters, 2012 PaperCon Conference
Conference papers
Unique Compression Behavior of Foam-formed Sheets in Wet Pressing and Calendering, 19PaperCon
Unique Compression Behavior of Foam-formed Sheets in Wet Pressing and Calendering, 19PaperCon
Conference papers
Fundamental Understanding of Bound Water Removal in Paper Drying Process: Microscopic Approach, 19PaperCon
Fundamental Understanding of Bound Water Removal in Paper Drying Process: Microscopic Approach, 19PaperCon
Keys to Sustainability at Kingsport, 2008 PAPERCON Conference
Keys to Sustainability at Kingsport, 2008 PAPERCON Conference
Conference papers
Production of pulps with an extremely high fines content for use as strength agent, 18PaperCon
Production of pulps with an extremely high fines content for use as strength agent, 18PaperCon