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Fundamental molecular characterization and comparison of the O, D0, and E stage effluents from hardwood pulp bleaching, TAPPI Journal 2019
ABSTRACT: The present study characterized effluents from the O, D0, and E stages using nuclear magnetic reso-nance (NMR) and gel permeation chromatography (GPC) techniques to better understand the chemical nature of the dissolved organics formed from the bleaching of a high-yield hardwood kraft pulp. Understanding the structures and molecular weight distribution of these organics is the first step in developing methods to mitigate these contam-inates in the discharged effluents. The results indicated that the molecular weight distribution (MWD) of the dis-solved organics from oxygen delignification effluent is broader than those from D0 and E stage effluents. In addition, the O stage filtrate contained considerable amounts of lignin and xylan fragments, which showed its efficiency in removing such materials. The effluent from the D0 stage contained a lower amount of high molecular weight frag-ments and a higher amount of low molecular weight fragments versus the O-stage filtrate. Aromatic structures were nearly absent in the D0 stage filtrate, but the degraded organic material, presumably from oxidized lignin, contained olefinic (C=C) and carbonyl (C=O) functional groups. Furthermore, higher molecular weight fragments were detected in the E-stage effluent, presumably due to the extensive solubilization and removal of the oxidized lignin generated from the D0 pulp.
Journal articles
Magazine articles
A hundred years of corrosion in the pulp and paper industry, TAPPI JOURNAL May 2018
A hundred years of corrosion in the pulp and paper industry, TAPPI JOURNAL May 2018
Journal articles
Magazine articles
Laboratory method for determining the source of brightness loss at a southern United States bleached paperboard mill, TAPPI Journal October 2018
Laboratory method for determining the source of brightness loss at a southern United States bleached paperboard mill, TAPPI Journal October 2018
Journal articles
Improvement in the Fock test for determining the reactivity of dissolving pulp, TAPPI JOURNAL November 2013
Improvement in the Fock test for determining the reactivity of dissolving pulp, TAPPI JOURNAL November 2013
Journal articles
Magazine articles
TAPPI Journal Summaries, Paper360 May/June 2019
TAPPI Journal Summaries, Paper360 May/June 2019
Journal articles
Magazine articles
Slave Lake Pulp Generates Biogas, Saves Money, Paper360º November/December 2019
Slave Lake Pulp Generates Biogas, Saves Money, Paper360º November/December 2019
Journal articles
Correlation Between Nodule size and Residual Carbonate Content in Lime Kilns, TAPPI JOURNAL, April 2007
Correlation Between Nodule size and Residual Carbonate Content in Lime Kilns, TAPPI JOURNAL, April 2007
Journal articles
Dynamic Modeling of Pressurized Peroxide Stages With Application to Full Bleach Plant Simulation, TAPPI JOURNAL, February 2007
Dynamic Modeling of Pressurized Peroxide Stages With Application to Full Bleach Plant Simulation, TAPPI JOURNAL, February 2007
Journal articles
What is "Research and Development"?, Frontline Focus, Volume 3, Issue 11
Frontline Focus, November 2007
Journal articles
Inside this month's TAPPI Journal, Paper360° Spring Bonus Issue 2009
Around the Industry, Paper360º Spring Bonus Issue 2009