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Fundamental molecular characterization and comparison of the O, D0, and E stage effluents from hardwood pulp bleaching, TAPPI Journal 2019
ABSTRACT: The present study characterized effluents from the O, D0, and E stages using nuclear magnetic reso-nance (NMR) and gel permeation chromatography (GPC) techniques to better understand the chemical nature of the dissolved organics formed from the bleaching of a high-yield hardwood kraft pulp. Understanding the structures and molecular weight distribution of these organics is the first step in developing methods to mitigate these contam-inates in the discharged effluents. The results indicated that the molecular weight distribution (MWD) of the dis-solved organics from oxygen delignification effluent is broader than those from D0 and E stage effluents. In addition, the O stage filtrate contained considerable amounts of lignin and xylan fragments, which showed its efficiency in removing such materials. The effluent from the D0 stage contained a lower amount of high molecular weight frag-ments and a higher amount of low molecular weight fragments versus the O-stage filtrate. Aromatic structures were nearly absent in the D0 stage filtrate, but the degraded organic material, presumably from oxidized lignin, contained olefinic (C=C) and carbonyl (C=O) functional groups. Furthermore, higher molecular weight fragments were detected in the E-stage effluent, presumably due to the extensive solubilization and removal of the oxidized lignin generated from the D0 pulp.
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Editorial: TAPPI Journal 2018 Best Research Paper delves deeper into press section rewet to address drying efficiency, TAPPI Journal March 2019
ABSTRACT: TAPPI and the TAPPI Journal (TJ) Editorial Board would like to congratulate the authors of the 2018 TAPPI Journal Best Research Paper Award: J. David “Dave” McDonald and Richard J. “Dick” Kerekes. Their paper, “Rewet in wet pressing of pa-per,” appeared on p. 479 of the September 2018 issue. This research was recognized by the Editorial Board for its in-novation, creativity, scientific merit, and clear expression of ideas.
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Editorial: New lignocellulosics address consumer expectations and industry prosperity, TAPPI JOURNAL February 2018
Editorial: New lignocellulosics address consumer expectations and industry prosperity, TAPPI JOURNAL February 2018
Journal articles
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Wet-end addition of nanofibrillated cellulose pretreated with cationic starch to achieve paper strength with less refining and higher bulk, TAPPI JOURNAL July 2018
Wet-end addition of nanofibrillated cellulose pretreated with cationic starch to achieve paper strength with less refining and higher bulk, TAPPI JOURNAL July 2018
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An effective method for determining the retention and distribution of cellulose nanofibrils in paper handsheets by dye labeling, TAPPI JOURNAL March 2018
An effective method for determining the retention and distribution of cellulose nanofibrils in paper handsheets by dye labeling, TAPPI JOURNAL March 2018
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A hundred years of corrosion in the pulp and paper industry, TAPPI JOURNAL May 2018
A hundred years of corrosion in the pulp and paper industry, TAPPI JOURNAL May 2018
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Factors affecting particulate removal efficiency of kraft recovery boiler electrostatic precipitators: a technical review, TAPPI JOURNAL May 2018
Factors affecting particulate removal efficiency of kraft recovery boiler electrostatic precipitators: a technical review, TAPPI JOURNAL May 2018
Journal articles
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Dry chip feedrate control using online chip moisture, TAPPI JOURNAL May 2018
Dry chip feedrate control using online chip moisture, TAPPI JOURNAL May 2018
Journal articles
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Laboratory method for determining the source of brightness loss at a southern United States bleached paperboard mill, TAPPI Journal October 2018
Laboratory method for determining the source of brightness loss at a southern United States bleached paperboard mill, TAPPI Journal October 2018
Journal articles
Magazine articles
Monitoring the free lime content in lime mud using zeta potential, TAPPI JOURANL April 2018
Monitoring the free lime content in lime mud using zeta potential, TAPPI JOURANL April 2018