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Magazine articles
Evaluation of folding effects on coating damage, TAPPI Journal November 2024
ABSTRACT: Barrier coatings on paperboard need to maintain integrity during converting and end-use for effective barrier performance. Folding is one of the most common deformations during converting; however, factors that affect damage during folding are not well defined. This is partly because methods to fold specimens and characterize damage are not standardized and the results are generally not transferable. In this work, we describe a method to fold paper specimens precisely and reproducibly. The keys to folding include using a defined geometry and controlled deformation. Multiple methods can be used to quantify damage; in this case, we use differences in permeability as a measure of how the coating becomes more open. Damage is sensitive to the degree of compression after the initial folding. Using a shim for support provides a defined amount of compression and minimizes the sensitivity to the applied pressure.
Journal articles
Magazine articles
Colloid chemical aspects of paper formation in the presence of nanofibrillated cellulose and cationic starch, TAPPI Journal September 2024
ABSTRACT: A series of experimental tests were carried out to examine colloidal-scale consequences of optionally treating nanofibrillated cellulose (NFC) with cationic starches of different charge density and dosage (0.5% or 2.0% by weight), adding that material to a furnish prepared from 100% recycled copy paper, and then subjecting the mixture to very different levels of hydrodynamic shear. Tests included optical microscopy, sediment volume tests, sediment velocity tests, and “percent fines” assessment by means of a fiber quality analyzer (FQA). In addition, the zeta potential and charge demand of the studied materials were evaluated. Optical imaging revealed that cationic starch treatment of the NFC tended to agglomerate it into multiparticle clusters, which sometimes could be mostly redispersed by hydrodynamic shear. Subsequent addition of the starch-treated NFC to the default furnish resulted in much of the colloidal material becoming attached to fibers. Subsequent shearing of the mixtures was at least partly effective in separating the clusters of NFC from the fiber surface, resulting in essentially a two-component mixture. Multiparticle NFC clusters coexisted with the fiber suspension, sometimes attached and sometimes not, depending on the details of treatments. Sediment volume tests showed that systems containing cationic starch-treated NFC tended to have a higher density after settling in comparison to untreated NFC; these findings are consistent with the cationic starch acting as a stabilizer on the solid surfaces, allowing them to slide past each other during the settling process. Application of intense hydrodynamic shear tended to result in denser sediment. Results of tests with the sediment velocity messurement and the FQA percent fines assessment did not correlate well with changes in test conditions considered in this study.
Journal articles
Editorial: Coating innovations for driving the next generation of sustainable packaging, TAPPI Journal November 2025
Welcome to the 2025 Special Coating Issue of TAPPI Journal. As we reflect on developments in 2025, the industry’s focus on sustainable packaging continues to sharpen, bringing several critical coating challenges and opportunities into view.
Journal articles
Influence of base sheet properties on barrier coating performance, TAPPI Journal November 2025
ABSTRACT: Paper packaging offers a sustainable alternative to standard plastic-based materials, particularly for food and beverage applications. With reduced fiber treatment options like fluorochemicals, uncoated base stock often provides little-to-no effective barrier against liquid water, oil/grease, or moisture transmission. Despite the lack of natural barrier performance, base sheet properties can significantly influence the efficiency of applied waterbased barrier coatings. In this study, various base stock properties, such as caliper, porosity, roughness, and ash content, are reported to influence the barrier performance of styrene-acrylic and a copolymer of styrene-butadiene/styrene-acrylate based barrier coatings. These findings will help paper and board producers design better, more cost-effective, purposebuilt substrates for barrier applications in the packaging industry.
Journal articles
A laboratory-scale automated vacuum-assisted device for coating of cellulose nanofibrils onto paper, TAPPI Journal November 2025
ABSTRACT: An automated vacuum-assisted coating system was developed to deposit cellulose nanofibril (CNF) layers onto paper substrates, simulating potential industrial geometries while allowing precise control of web speed (10•20 m/min), vacuum time (up to 30 s), and applicator gap (0.5•0.9 mm). Vacuum assistance makes it possible to obtain coat weights over 5 g/m2 in a single pass and increases solids after coating from less than 10% to over 28%• 30%, reducing drying demand by more than 60%. Coat weights were tuned from 6 to over 11 g/m² by varying suspension solids (0.4•0.6 wt%), line speed, and filtration length (20•40 mm), with strong agreement between experimental data and model predictions. Barrier testing showed Kit test values for double folded samples of 9•12 and Gurley air resistances above 4 × 104 s once coat weights exceeded 7 g/m². Comparable performance was achieved with lower fines content CNF (60%) by increasing coat weight, providing technical flexibility and cost advantages for industrial scale-up.
Journal articles
Designing paper and board barrier constructions for food contact applications, TAPPI Journal November 2025
ABSTRACT: This study examines the effect of multiple factors on barrier performance for purpose-built paper and paperboard constructions produced on an industrial pilot coater machine. Impacts from precoat latex chemistry, application method (flooded nip with bevel blade, jet with bevel blade, and pre-metered film coater, laboratory rod drawdown) and precoating calendering were studied in relation to resulting porosity, roughness, and barrier (liquid water, moisture, and oil). Results reveal a complex interaction between controllable and uncontrollable factors, offering insight for designing advanced barrier coatings on cellulosic substrates.
Journal articles
A systems approach for process debottlenecking towards a sustainable pulp and paper industry, TAPPI Journal April 2026
ABSTRACT: Increasing the competitiveness of the pulp and paper industry requires an effective optimization of its existing assets in line with a long-term vision for process transformation, production upgrade, and product diversification. Currently, pulp production increase is one of the main sources of additional revenue for the kraft industry. Likewise, energy efficiency is often employed as a cost-effective approach to reduce operating costs, enhancing the possibilities to lower fossil fuel consumption and contributing to a low-carbon economy. On the other hand, reaching higher production targets and facilitating process transformation, such as biorefinery implementation, heavily depend on the status and performance of a mill’s current infrastructure; therefore, a system analysis is needed to assess the new production requirements, the bottlenecks, and the interactions across departments. In order to obtain practical improvement solutions, direct and indirect impacts on process performance and resource utilization should be considered. This work provides an overview of the key challenges that need to be addressed for production increase and energy efficiency improvement. The methodology starts by a scope analysis for debottlenecking and screening capacity limitations vs. mill targets, followed by their ranking (bottleneck ranking diagram). Benchmarking, gap analysis, and root-cause techniques are applied to diagnose system inefficiencies. This mill-wide debottlenecking assessment is then used to guide the selection of a long-term sustainable operation and design a portfolio of improvement projects by avoiding cross effects of the short-term projects on the long term. A case study of a kraft pulp mill is used to illustrate the proposed methodology.
Journal articles
Beyond the machine: Decoding process water microbes behind odor in papermaking, TAPPI Journal February 2026
ABSTRACT: Paper manufacturing processes create an ecosystem conducive to microbial growth, characterized by abundant water, nutrients, and optimal temperatures, fostering diverse microbial habitats. With the increased use of recycled fibers and greater water system closure, the industry now faces amplified microbiological challenges, particularly odor generation. These odor problems have raised community concerns, as shown by resident com-plaints, and have led to significant economic impacts, including costly lawsuits against major paper manufacturers. Based on earlier studies showing that microbes in papermaking systems can generate odor-causing volatile com-pounds, this study is guided by the hypothesis that recycle paper mill process water harbors odor-causing microbial communities and thus represents a primary source of malodor. To test this hypothesis, process water samples from commercial recycle paper mills were analyzed using high-throughput Illumina sequencing to characterize microbial communities in one complete analysis. The study results revealed fifteen major microbial populations, dominated mainly by the genus Pseudomonas. The identified microbes were further linked to prior literature to determine their functional roles in odor generation, including the production of haloanisoles (2-monochloroanisole, 2,4-dichloroanisole, 2,3,6-trichloroanisole, 2,4,6-tri-bromoanisole), geosmin, 2-methylisoborneol, and volatile organic sulfur compounds such as dimethyl polysulfides, hydrogen sulfide, and methylmercaptan. This study introduces a microbiological community-profiling approach that enables papermakers to assess whether process water represents a potential source of malodor. Earlier studies have not examined microbial com-munities in recycle paper mill process water specifically from the perspective of identifying malodor sources, nor have they integrated such findings with an extensive literature-based assessment. The findings of this study advance both science and practice by offering a method that can serve as an early diagnostic tool for papermakers, supporting effective future odor management and deepening understanding of microbial ecology in paper mill environments.
Journal articles
Effects of calcium on sodium salt scaling with the presence of resin acids and fatty acids, TAPPI Journal June 2026
ABSTRACT: Reintroducing tall oil soap or its related products into high dry solids black liquor has been found to reduce sodium salt scaling in falling film evaporators. Aside from resin acids and fatty acids, which are the likely scale inhibitors, calcium is reintroduced into black liquor because of the relatively high calcium content of tall oil soap. One concern is that this increase in calcium content might lead to the formation of additional calcium and sodium scales in evaporators. In this work, we investigated the relationship among trace amounts of calcium, sodium salts, resin acids, and fatty acids in a controlled system using a model salt solution and a benchtop setup. We studied the effects of the calcium carbonate addition and calcium carbonate scales on sodium salt scaling in the presence of resin acids and fatty acids. We found that some calcium carbonate is incorporated in the precipitated sodium crystals, and the suspended sodium crystals become larger and more compact with increasing calcium carbonate concentration. Experiments in the benchtop setup show that precipitating calcium carbonate scale on the heat exchanger does not lead to a higher rate of sodium salt scaling. The solubility of calcium carbonate is not affected by the addition of resin acids and fatty acids. These findings indicate that the reduction in sodium salt scaling through the addition of tall oil soap is primarily related to resin acids and fatty acids, rather than to calcium or to interactions between calcium and mixtures of resin and fatty acids.
Journal articles
Optimization of optical coverage of board surfaces with assessment of light scattering and absorption using mineral as a coating component, TAPPI Journal June 2026
ABSTRACT: One of the primary functions of mineral inclusion into paper or paperboard is to improve the optical performance of the substrate. A coating may be applied to a sheet in order to cover a dark base, to improve the sheet opacity, to give the correct smoothness and gloss, or to give a suitable surface on which to print. The brightness of a pigment has long been used as a guide for pigment choice in paper and board. However, the measured paper brightness is a function of color and light absorption (K) of the coating and base and the light scattering (S) within the sheet resulting from interfaces with different refractive index. The optical performance can be quantified by measuring the S&K coefficients as described by the Kubelka-Munk model/theory in a filled or coated paper sheet. In coating, this is often assessed as a function of coat weight, and the corresponding physical sheet properties are assessed at the same time; for example, the correct gloss, smoothness, point-to-point uniformity, and printability. The optical performance in the sheet is often not directly related to the pigment brightness, but is largely a function of the particle packing within the sheet and coating layer. In the first and second main sections of this work, respectively, we show how S&K calculations from the Kubelka- Munk equations can be used in coated sheets to determine the optical performance and how this can be used as a predictive tool for the final sheet performance. This is presented for base sheets with different starting brightness. The third section of this work focuses on how mineral combinations in coatings can be used to improve the light scattering and consequently the optical performance of the board. We include theoretical considerations and then finally share a case study for improvement on the optical properties of recycled board.