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Magazine articles
Model development for real oxygen delignification processes, TAPPI Journal October 2024
ABSTRACT: Previous extensive work has been done on modeling the oxygen delignification process, based on how the basic parameters, i.e., temperature, kappa number, concentration of alkali, and concentration of oxygen, affect the delignification rate. However, these models are not used extensively to evaluate the performance of real processes, primarily because they have not been able to properly consider all the essential issues affecting delignification in practice. Such issues include the mass transfer and consumption of oxygen, which defines the concentration of dissolved oxygen in the process, and the effect of that concentration on the delignification rate. In this paper, a new way to model the oxygen delignification process is used in which these parameters, among other smaller matters, are taken into account. The basic model and its parameters were defined by the information obtained from the literature, delignification made in the laboratory tests, and mill processes and mill tests. An essential aspect of these studies was the information obtained from the oxygen concentration measured in the residual gas obtained from the top of the reactor. With the aid of this measurement, it was possible to define more accurately the consumption of oxygen and partial pressure of oxygen that define the concentration of dissolved oxygen in the reactor. Using mill experiments, a model was formed that predicts the operation of the oxygen delignification process. The model was used to show how much the process could be improved by optimizing the charge of the oxygen. The mill experiments also confirmed that mass transfer of oxygen is modeled correctly enough, except when the charge of oxygen is very low and/or the mixing is not efficient enough. In that case, there is variation in the concentration of oxygen in the process that should be taken into account in the modeling.
Magazine articles
Treatment efficiency of eucalypt kraft pulp bleaching effluents: influence of dissolved organic matter, SOLUTIONS! & TAPPI JOURNAL, April 2002 (128KB)
Treatment efficiency of eucalypt kraft pulp bleaching effluents: influence of dissolved organic matter, SOLUTIONS! & TAPPI JOURNAL, April 2002 (128KB)
Magazine articles
Barbara Dalpke: insights from a recent graduate, TAPPI JOURN
Barbara Dalpke: insights from a recent graduate, TAPPI JOURNAL, August 2002, Vol. 1(6) (144KB)
Magazine articles
Energy: recovering capital and cutting costs, TAPPI JOURNAL, November 2000, Vol. 83(11)
Energy: recovering capital and cutting costs, TAPPI JOURNAL, November 2000, Vol. 83(11)
Magazine articles
Reliability of stainless alloy equipment in chlorine dioxide bleaching, TAPPI JOURNAL, November 2000, Vol. 83(11)
Reliability of stainless alloy equipment in chlorine dioxide bleaching, TAPPI JOURNAL, November 2000, Vol. 83(11)
Magazine articles
What's new with tappi test methods?, TAPPI JOURNAL, September 2000, Vol. 83(9)
What's new with tappi test methods?, TAPPI JOURNAL, September 2000, Vol. 83(9)
Magazine articles
Laccase n-hydroxybenzotriazole full sequence bleaching with hydrogen peroxide and chlorine dioxide, TAPPI JOURNAL, September 2000, Vol. 83(9)
Laccase n-hydroxybenzotriazole full sequence bleaching with hydrogen peroxide and chlorine dioxide, TAPPI JOURNAL, September 2000, Vol. 83(9)
Magazine articles
Environmental issues continue to be a major industry concern, TAPPI JOURNAL, September 2000, Vol. 83(9)
Environmental issues continue to be a major industry concern, TAPPI JOURNAL, September 2000, Vol. 83(9)
Magazine articles
Taiwan holds first symposium on environmentally friendly and emerging technologies for a sustainable industry, TAPPI JOURNAL, September 2000, Vol. 83(9)
Taiwan holds first symposium on environmentally friendly and emerging technologies for a sustainable industry, TAPPI JOURNAL, September 2000, Vol. 83(9)
Journal articles
Magazine articles
Pulp and paper mills: The original biorefineries — past performance and limitations to future opportunities, TAPPI Journal October 2023
ABSTRACT: Pulp mills have been biorefineries since the invention of the Tomlinson recovery boiler. Unfortunately, the paper industry has done a poor job explaining that concept to the general public. A number of bioproducts in everyday use have been produced by pulp mills for several decades, and new products are routinely being developed. Modern research efforts over the last couple of decades have focused on producing even more products from pulp and paper mills through capacity enhancement and the development of value-added products and liquid transportation fuels to enhance paper mill profitability. Some of these efforts, often referred to as modern biorefineries, have focused so heavily on product development that they have ignored operating and process realities that limit the transformation of pulp and paper mills from the current limited number of bioproducts produced today to economic scale production of these value-added products. In this paper, several of these limitations are addressed. In addition, there are several supply chain, marketing, product quality, and economic realities limiting the value potential for these wholesale conversions of pulp mills into multiproduct modern biorefineries. Finally, the conservative nature and capital intensity of the pulp and paper industries provide a difficult hurdle for conversion to the modern biorefinery concept. These issues are also reviewed.