Search

Value creation by converting pulp mill flue gas streams to green fuels, TAPPI Journal March 2023

ABSTRACT: Climate change mitigation induces strong growth in renewable electricity production, partly driven by shifts in environmental policies and regulation. Intermittent renewable electricity requires supporting systems in the form of sustainable hydrocarbon chemicals such as transportation fuels. Bulk chemical production fits well into a pulp mill environment, given their large volumes, stable operation, and ample supply of biomass-based carbon feed-stock in the form of flue gases. Until now, the utilization of the flue gases from conventional operation of a pulp mill has received little attention. Harnessing these flue gases into usable products could offer additional value to mill operators, while also diversifying their product portfolio. However, electricity-based fuels and products require extra energy in the conversion step and may not be commercially competitive with current fossil products under the current regulation. There might also be uncertainties about future commodity prices. Thus, the objective of this study is to estimate the economic competitiveness and the added value of selected side products that could be produced alongside conventional pulp and paper products. A typical modern pulp mill is modeled in different product configurations and operational environments, which allows testing of various development paths. This illustrates how the overall energy and mass balance of a pulp mill would react to changes in different final products and other parameters. The focus of the study is in synthetic methanol, which is produced from flue gases and excess resources from the mill, with minimal interference to the pulping process. The results aid in assessing the necessity and magnitude of a premium payment for subsidizing green alter-natives to replace current fossil fuels and chemicals. Additionally, the results function as an indicator of the development state of the pulp and paper industry in the turmoil of climate change regulation. The results indicate that power-to-X systems offer one more viable pathway alternative for broadening the product portfolio of the pulp and paper sector, as well as opening new flexibility measures and services to grid stabilization. Market conditions were found to have a significant impact on the perceived profitability.

Preparing prehydrolyzed kraft dissolving pulp via phosphotungstic acid prehydrolysis from grape branches, TAPPI Journal January 2022

ABSTRACT: Dissolving pulp was successful prepared via phosphotungstic acid (PTA) prehydrolysis kraft (PHK) cooking followed by an elementary chlorine-free (ECF) bleaching process from grape branches. The effects of prehydrolysis temperature, reaction time, and PTA concentration that potentially affect the quality of dissolving pulp product on chemical components of pulp were studied via an orthogonal experiment. The structure of lignin was activated during the PTA prehydrolysis phase, and lignin was easily removed during the following cooking process. Thus, relatively mild conditions (140°C, 100 min) can be used in the cooking process. During the prehydrolysis phase, temperature exhibited the most significant influence on the cellulose purity of the obtained pulp fiber, followed by reaction time and PTA concentration. The optimized prehydrolysis conditions were as follows: prehydrolysis temperature, 145°C; reaction time, 75 min; and PTA concentration, 1 wt%. Whether the excessively high prehydrolysis temperature or prolonging the reaction time did not favor the retention of long chain cellulose, the delignification selectivity for the cooking process could not be further improved by excessive PTA loading. Under these prehydrolysis conditions, 94.1% and 29.0% for a-cellulose content and total yield could be achieved after the given cooking and bleaching conditions, respectively. Moreover, the chemical structure and crystal form of cellulose were scarcely changed after PTA prehydrolysis, which could be confirmed by results from Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). PTA prehydrolysis could be considered as an alternative method for preparing PHK dissolving pulp under relatively mild cooking conditions.

Application of spruce wood flour as a cellulosic-based wood additive for recycled paper applications— A pilot paper machine study, TAPPI Journal October 2021

ABSTRACT: This study gives a first insight into the use of wood flour as a plant-based and cellulosic-based alter-native additive for newsprint and paperboard production using 100% recycled fibers as a raw material. The study compares four varieties of a spruce wood flour product serving as cellulosic-based additives at addition rates of 2%, 4%, and 6% during operation of a 12-in. laboratory pilot paper machine. Strength properties of the produced news-print and linerboard products were analyzed. Results suggested that spruce wood flour as a cellulosic-based additive represents a promising approach for improving physical properties of paper and linerboard products made from 100% recycled fiber content. This study shows that wood flour pretreated with a plant-based polysaccharide and untreated spruce wood flour product with a particle size range of 20 μm to 40 μm and 40 μm to 70 μm can increase the bulk and tensile properties in newsprint and linerboard applications.

Corrosion damage and in-service inspection of retractable sootblower lances in recovery boilers, TAPPI Journal October 2021

ABSTRACT: Several reports of accidents involving serious mechanical failures of sootblower lances in chemical recovery boilers are known in the pulp and paper industry. These accidents mainly consisted of detachment and ejection of the lance tip, or even of the entire lance, to the inside of the furnace, towards the opposite wall. At least one of these cases known to the author resulted in a smelt-water explosion in the boiler.In other events, appreciable damage or near-miss conditions have already been experienced. The risk of catastrophic consequences of the eventual detachment of the lance tip or the complete lance of a recovery boiler soot-blower has caught the attention of manufacturers, who have adjusted their quality procedures, but this risk also needs to be carefully considered by the technical staff at pulp mills and in industry committees.This paper briefly describes the failure mechanisms that prevailed in past accidents, while recommending inspection and quality control policies to be applied in order to prevent further occurrences of these dangerous and costly component failures. Digital radiography, in conjunction with other well known inspection techniques, appears to be an effective means to ensure the integrity of sootblower lances in chemical recovery boilers used in the pulp and paper industry.

Non-process elements in the lime cycle: New findings regarding NPE distribution and lime mud filterability, TAPPI Journal July 2026

ABSTRACT: Proper functioning of the recausticizing cycle is crucial for securing a stable white liquor supply for a pulp mill. Common runnability problems in the modern lime cycle, such as low filterability and poor dewatering of lime mud, high dead load, or ring formation in the lime kiln, are often caused by accumulation of non-process elements (NPEs). This project attempted to verify the traditional rules of thumb regarding the chemical behavior of NPEs: magnesium (Mg), aluminum (Al), silicon (Si), phosphorus (P), zinc (Zn), manganese (Mn), iron (Fe), copper (Cu), barium (Ba), cadmium (Cd), and lead (Pb) in the causticizing reaction, and to investigate the reasons behind poor lime mud filterability. First, a standardized method for measuring filterability of lime mud was developed. Next, a series of recausticizing experiments, followed by immediate filtration trials, was conducted using mill green liquors, laboratory-made synthetic green liquor, reburned lime/makeup mix, and extra NPE additions. It was found that sodium (Na), potassium (K), and sulfur (S) followed the liquid phase, as expected, while Mg, P, and Ba, but also Pb, Cu, and Cd, showed low solubility and accumulated in the lime mud. The Si and Al accumulated in the lime mud even though the soluble content in liquor was high, while the behavior of Mn, Fe, and Zn was more complex. Based on these results, tentative solubility limits for NPEs were suggested as a first estimate for the maximum possible concentrations of NPEs in mill white liquor. The causticization-filtration experiments revealed that overliming and high content of Mg in green liquor clearly led to lower filterability, but our addition of Si did not have such an effect. As differences in particle size and size distribution have a certain impact on the filtration resistance, the lime mud sedimentation behavior, combined with other characterization methods, might be used as an indication for the filterability. Finally, a list of recommendations for pulp mills was formulated that starts with establishing a comprehensive standard for a lime mud with good filterability. This standard can be used as a benchmark for comparison any time a lime cycle runnability problem is identified.

Black liquor spray properties in-furnace conditions for swirl cone nozzles, TAPPI Journal July 2026

ABSTRACT: Recovery boiler furnace operation is controlled for high chemical recovery, high steam production, and low emissions. Good control allows long runs with minimum cleaning without expensive shutdowns. An essential variable affecting boiler operation is black liquor spraying into the furnace. Poorly controlled black liquor spraying causes difficulties, e.g., in chemical recovery, fouling of heat transfer surfaces, and decreased energy production. A challenging measurement strategy with three different swirl cone nozzles . types A, C, and T . was carried out at a mill in the United States. Black liquor spray properties were measured under in-furnace conditions for flow rates of 2.0 L/s to 3.0 L/s. Three spraying temperatures of 119™‹C, 122™‹C, and 126™‹C, which were 2™‹C, 5™‹C, and 9™‹C above the boiling point (ƒ¢Te), were tested. These flow rates and temperatures are typical for industrial nozzle sizes with exit orifice sizes of 17 mm and 22 mm. An imaging method to measure droplet size in a highly challenging furnace environment was developed. Droplet volume median diameter (Dv50) for nozzles A, C, and T varied between 7 mm to 4 mm, 7 mm to 5 mm, and 8 mm to 6 mm, depending on the flow rate and temperature. The high number of droplets detected by the analysis program enabled data fitting into statistical correlations. The size and width parameters for the Rosin™]Rammer droplet size distribution function could be defined. The droplet size distribution was found to be surprisingly wide, probably because of swollen droplets. Spray velocity was measured in two locations, 5 cm from the nozzle and 1.8 m from the nozzle. Near the nozzle, the average velocity increased from 7.3 m/s to 13 m/s when the flow rate was increased from 2 L/s to 3 L/s. Increase of black liquor temperature increased spray velocity in most of the cases. At the distance of 1.8 m from the nozzle, average spray velocities varied between 4.0 m/s to 11 m/s, depending on nozzle geometry, flow rate, and temperature. The opening angles of the spray for nozzles A and C varied between 57™‹ to 78™‹. The opening angle of nozzle T with flow guide varied between 48™‹ to 56™‹. The highest penetration of the spray was estimated for nozzle T because of the narrow spray and large droplets.

Boiler retrofit improves efficiency and increases biomass firing rates, TAPPI Journal March 2021

ABSTRACT: Domtar’s fluff pulp mill in Plymouth, NC, USA, operates two biomass/hog fuel fired boilers (HFBs). For energy consolidation and reliability improvement, Domtar wanted to decommission the No. 1 HFB and refurbish/retrofit the No. 2 HFB. The No. 2 HFB was designed to burn pulverized coal and/or biomass on a traveling grate. The steaming capacity was 500,000 lb/h from coal and 400,000 lb/h from biomass. However, it had never sustained this design biomass steaming rate. As the sole power boiler, the No. 2 HFB would need to sustain 400,000 lb/h of biomass steam during peak loads. An extensive evaluation by a combustion and boiler technologies supplier was undertaken. The evaluation involved field testing, analysis, and computational fluid dynamics (CFD) modeling, and it identified several bottle-necks and deficiencies to achieving the No. 2 HFB’s biomass steam goal. These bottlenecks included an inadequate combustion system; insufficient heat capture; excessive combustion air temperature; inadequate sweetwater con-denser (SWC) capacity; and limited induced draft fan capacity.To address the identified deficiencies, various upgrades were engineered and implemented. These upgrades included modern pneumatic fuel distributors; a modern sidewall, interlaced overfire air (OFA) system; a new, larger economizer; modified feedwater piping to increase SWC capacity; replacement of the scrubber with a dry electrostatic precipitator; and upgraded boiler controls.With the deployment of these upgrades, the No. 2 HFB achieved the targeted biomass steaming rate of 400,000 lb/h, along with lowered stack gas and combustion air temperatures. All mandated emissions limit tests at 500,000 lb/h of steam with 400,000 lb/h of biomass steam were passed, and Domtar reports a 10% reduction in fuel firing rates, which represents significant fuel savings. In addition, the mill was able to decommission the No. 1 HFB, which has substantially lowered operating and maintenance costs.

Commercially relevant water vapor barrier properties of high amylose starch acetates: Fact or fiction?, TAPPI Journal September 2021

ABSTRACT: Starches have recently regained attention as ecofriendly barrier materials due to the increased demand for sustainable packaging. They are easily processable by conventional plastics processing equipment and have been utilized for oil and grease barrier applications. While starches have excellent oxygen barrier properties and decent water barrier properties at low relative humidity (RH), they are moisture sensitive, as demonstrated by the deterioration of the barrier properties at higher RH values. Starch esters are chemically modified starches where the hydroxyl group of the starch has been substituted by other moieties such as acetates. This imparts hydrophobicity to starches and has been claimed as a good way of retaining water vapor barrier properties of starches, even at high RH conditions. We studied the water vapor barrier properties of one class of starch esters, i.e., high amylose starch acetates that were assumed to have good water vapor barrier properties. Our investigations found that with a high degree of substitution of hydroxyl groups, the modified starches did indeed show improvements in water vapor response as compared to pure high amylose starch films; however, the barrier properties were orders of magnitude lower than commercially used water vapor barriers like polyethylene. Even though these materials had improved water vapor barrier response, high amylose starch acetates are likely unsuitable as water vapor barriers by themselves, as implied by previous literature studies and patents.

Application of ATR-IR measurements to predict the deinking efficiency of UV-cured inks, TAPPI Journal January 2022

ABSTRACT: In recent years, ultraviolet (UV)-curable ink has been developed and widely used in various printing applications. However, using UV-printed products (UV prints) in recovered paper recycling causes end-product dirt specks and quality issues. A new method was developed that can distinguish UV prints from other prints by means of attenuated total reflectance infrared (ATR-IR) spectroscopy. Application of this method could allow more efficient use of UV prints as raw materials for paper recycling.First, a mill trial was performed using UV prints alone as raw materials in a deinked pulp (DIP) process. Second, test prints were made with four types of UV inks: a conventional UV ink and three different highly-sensitive UV inks. Each print sample had four levels of four-color ink coverage patterns (100%, 75%, 50%, and 25%). Next, deinkability of all prints was evaluated by laboratory experiments. Finally, each print was measured using the ATR-IR method, and the relationship between the IR spectra and deinkability was investigated. Mill trial results showed that UV prints caused more than 20 times as many dirt specks as those printed with conventional oil-based ink. There were variations in recycling performance among UV prints taken from bales used for the mill trial. Lab tests clearly revealed that not all UV-printed products lead to dirt specks. In order to clarify the factors that affected deinkability of UV prints, the print samples were investigated by lab experiments. Key findings from lab experiments include: œ The number of dirt specks larger than 250 µm in diameter increased as the ink coverage increased. œ Higher ink coverage area showed stronger intensity of ATR-IR spectral bands associated with inks. These results indicate that deinkability of UV prints could be predicted by analysis of ATR-IR spectra. œ Finally, the method was applied for assessment of recovered paper from commercial printing presses. It was confirmed that this method made it possible to distinguish easily deinkable UV prints from other UV prints. Based on these findings, we concluded that the ATR-IR method is applicable for inspection of incoming recovered paper.

The Impact Of Multiple Recycle Loops On The Yield And Properties Of Softwood Kraft 1 Fibers And Of Non-wood Fibers For Packaging, 2022PEERS/IBBC Conference (22PEE/22IBB)