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Flow rheology of light foams generated from aqueous solutions of polyvinyl alcohol, TAPPI Journal January 2023
ABSTRACT: Recent studies have shown that foam-assisted application of additives into a wet web has advantages over the conventional way of adding the chemicals into the pulp suspension before forming, e.g., increased mechanical retention as well as high dosage giving increased wet strength without impairing the sheet uniformity. To engineer processes utilizing this new technology, the complex flow behavior of applied foams must be quantified. At the minimum, the foam viscosity and the slip velocity at the solid surfaces need to be known to build practical models that can be used in analyzing and upscaling unit processes of the foam-assisted application.In this study, the rheological behavior was quantified for foams having polyvinyl alcohol (PVOH), a widely used strength additive chemical, as the surfactant. The foam density was varied between 100 g/L and 300 g/L, and the concentration of the PVOH solution was varied between 0.5% and 6.0% (w/w). The foams were generated with a commercial foam generator, and the rheological properties of the foams were measured by using a horizontal pipe bank. At the outlet from the generator, the volumetric flow rate, the absolute pressure, and the bubble size distribution of the foam were measured. In the measurement pipe section, the viscous pressure gradient and the slip velocity were measured, after which the foam was discharged to ambient air pressure. The viscosity and the dynamic surface tension of the PVOH solutions were quantified with commercial laboratory devices. In the viscosity analysis, the apparent shear rate was calculated from the volumetric flow rate, and the resulting apparent viscosity was translated to real material viscosity data by applying the Weissenberg-Rabinowitsch correction. The results indicated that PVOH foams can be described with high accuracy as shear-thinning power-law fluids where the detailed behavior depends on the foam density and the PVOH concentration. Slip flow, as usual, increased with increasing wall shear stress, but it was also dependent on the PVOH concentration, the air content, and the bubble size. For both the foam viscosity and the slip flow, a correlation was found that described the quantitative behavior of all the studied foams with good accuracy.
Journal articles
Magazine articles
New opportunities in the paper and nonwovens industries with foam-assisted web forming and chemical application, TAPPI Journal January 2023
ABSTRACT: Foam-assisted web forming and chemical application technologies have great potential to improve manufacturing efficiency and product quality in the paper and nonwovens industries. In this study, the benefits of foam forming and foam-assisted application of chemicals were demonstrated in a pilot machine trial. Uniform high-bulk webs of unrefined bleached softwood kraft pulp (BSKP) and viscose fibers were manufactured by foam forming. It was shown that foam formed low-grammage and high-bulk viscose fiber webs can be strengthened by foam-assisted application of latex onto the wet web. Correspondingly, foam-assisted application of carboxymethyl cellulose (CMC) and anionic polyacrylamide (A-PAM) improved the strength of the foam formed low-grammage and high-bulk BSKP web. Overall, the pilot machine results indicated that material cost savings could be achieved and a high-performance product could be manufactured with foam-based technologies.
Journal articles
Magazine articles
Editor's Note: Recovery Boiler Insights, TAPPI JOURNAL Febru
Editor's Note: Recovery Boiler Insights, TAPPI JOURNAL February 2010
Magazine articles
Editor's Note: Bright future for coating at ACFS, TAPPI JOUR
Editor's Note: Bright future for coating at ACFS, TAPPI JOURNAL November 2010
Journal articles
Magazine articles
Guest Editorial: Terry Bliss: Editorial board member "extrem
Guest Editorial: Terry Bliss: Editorial board member "extreme", TAPPI JOURNAL May 2012
Magazine articles
How will integrated gasification impact kraft pulping and chemical recovery, TAPPI JOURNAL, September 1999, Vol. 82(9)
How will integrated gasification impact kraft pulping and chemical recovery, TAPPI JOURNAL, September 1999, Vol. 82(9)
Magazine articles
TAPPI view: a view to our future, TAPPI JOURNAL, September 1
TAPPI view: a view to our future, TAPPI JOURNAL, September 1999, Vol. 82(9)
Magazine articles
TAPPI view: renaissance for the millennium, TAPPI JOURNAL, S
TAPPI view: renaissance for the millennium, TAPPI JOURNAL, September 1999, Vol. 82(9)
Magazine articles
Toronto spotlight shines on tappi conference polymers, laminations, and coatings, TAPPI JOURNAL, January 1998, Vol. 81(1)
Toronto spotlight shines on tappi conference polymers, laminations, and coatings, TAPPI JOURNAL, January 1998, Vol. 81(1)
Magazine articles
Nonwovens division upbeat about industry's future and strategic alliances, TAPPI JOURNAL, July 1998, Vol. 81(7)
Nonwovens division upbeat about industry's future and strategic alliances, TAPPI JOURNAL, July 1998, Vol. 81(7)