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Journal articles
Paper strength factors in systems with nanofibrillated cellulose, cationic starch, colloidal silica, cationic acrylamide copolymer, and hydrodynamic shear, TAPPI Journal May 2025
ABSTRACT: Laboratory paper sheets were formed by first pretreating nanofibrillated cellulose (NFC) with cationic starch at the 5% level by mass. The treated NFC was then added to stock prepared from 100% recycled copy paper. The combined furnish was next optionally treated with a cationic retention aid (cPAM, 0.1%) and then colloidal silica (0.1% or 0.2%). Vacuum dewatering, fine-particle retention, and several paper properties were studied as a function of the colloidal silica level (zero, 1%, and 2%) and at different levels of shear stress applied just before forming the sheets. Dewatering and strength results were generally more favorable when using a medium charge cationic starch (~ 0.03 degree of substitution, DS) to pretreat the NFC rather than a high charge density cationic starch (~ 0.2 DS). In each case, the dewatering was further enhanced by subsequent treatments by cPAM (0.1% on whole furnish solids) and then even more with the final addition of colloidal silica (0.1% and 0.2% levels compared). However, the colloidal silica additions progressively hurt the tensile strength of the paper, especially in the case of the high charge cationic starch and at the higher level of colloidal silica. Though the dewatering performance was favorable, in such cases, the paper strength was not improved compared to paper made without any NFC. The fact that the systems involving cPAM treatment, and especially those involving both cPAM and colloidal silica, tended to reduce the resulting paper’s tensile strength supports a mechanism in which the additives result in the clustering of the NFC, possibly in multiparticle bunches. Evidence suggests that such bunches of clustered NFC particles, which are difficult to redisperse even at levels of hydrodynamic shear present in high-speed paper machine systems, are resistant to full integration into the sheet structure as the paper is being formed.
Journal articles
Research on an energy model for X-ray measurement of paper ash content using COMSOL, TAPPI Journal May 2025
ABSTRACT: Ash content is one of the critical quality parameters in papermaking production. Traditional 55Fe radioactive sources used for online ash content measurement have a short lifespan and high costs, while offline methods such as the combustion method or chemical analysis are time-consuming. Using an X-ray tube as the radiation source, continuous X-ray measurement offers advantages such as being rapid, non-destructive, and cost-effective. In this study, COMSOL software was employed to simulate the measurement process and establish an energy attenuation model for X-ray measurement of paper ash content. The model simulates the energy attenuation of X-rays before and after transmission through four materials: calcium carbonate (CaCO3), titanium dioxide (TiO2), wood-based plant fibers, and paper samples filled with CaCO3. The absorption coefficients of paper samples with varying ash content were investigated using the model and compared with experimental results obtained from continuous X-ray measurements. The results indicate that the proposed energy simulation model can reduce the measurement error of paper ash content by 1%, significantly enhancing the reliability and accuracy of ash content measurement.
Journal articles
Magazine articles
Boiler retrofit improves efficiency and increases biomass firing rates, TAPPI Journal March 2021
ABSTRACT: Domtar’s fluff pulp mill in Plymouth, NC, USA, operates two biomass/hog fuel fired boilers (HFBs). For energy consolidation and reliability improvement, Domtar wanted to decommission the No. 1 HFB and refurbish/retrofit the No. 2 HFB. The No. 2 HFB was designed to burn pulverized coal and/or biomass on a traveling grate. The steaming capacity was 500,000 lb/h from coal and 400,000 lb/h from biomass. However, it had never sustained this design biomass steaming rate. As the sole power boiler, the No. 2 HFB would need to sustain 400,000 lb/h of biomass steam during peak loads. An extensive evaluation by a combustion and boiler technologies supplier was undertaken. The evaluation involved field testing, analysis, and computational fluid dynamics (CFD) modeling, and it identified several bottle-necks and deficiencies to achieving the No. 2 HFB’s biomass steam goal. These bottlenecks included an inadequate combustion system; insufficient heat capture; excessive combustion air temperature; inadequate sweetwater con-denser (SWC) capacity; and limited induced draft fan capacity.To address the identified deficiencies, various upgrades were engineered and implemented. These upgrades included modern pneumatic fuel distributors; a modern sidewall, interlaced overfire air (OFA) system; a new, larger economizer; modified feedwater piping to increase SWC capacity; replacement of the scrubber with a dry electrostatic precipitator; and upgraded boiler controls.With the deployment of these upgrades, the No. 2 HFB achieved the targeted biomass steaming rate of 400,000 lb/h, along with lowered stack gas and combustion air temperatures. All mandated emissions limit tests at 500,000 lb/h of steam with 400,000 lb/h of biomass steam were passed, and Domtar reports a 10% reduction in fuel firing rates, which represents significant fuel savings. In addition, the mill was able to decommission the No. 1 HFB, which has substantially lowered operating and maintenance costs.
Journal articles
Magazine articles
Tetraethyl orthosilicate-containing dispersion coating — water vapor and liquid water barrier properties, TAPPI Journal September 2021
ABSTRACT: An aqueous styrene-butadiene latex dispersion coating containing in-situ processed tetraethyl orthosilicate (TEOS) applied on paperboard demonstrated improved water barrier performance. Coatings containing TEOS equivalent to 0.8% silicon dioxide (SiO2; dry basis) exhibited water vapor performance of < 25 g/m2/day (23°C, 50% relative humidity [RH]) and liquid water barrier performance Cobb 1800 s of < 6 g/m2, when applied as a single-layer 18 g/m2 coating. Cobb 1800 s barrier performance was still good (< 11 g/m2) at coat weights of 7•10 g/m2. The use of filler materials such as kaolin improved the vapor barrier properties of the coating, but this was not critical to the liquid water barrier properties.
Journal articles
Magazine articles
Commercially relevant water vapor barrier properties of high amylose starch acetates: Fact or fiction?, TAPPI Journal September 2021
ABSTRACT: Starches have recently regained attention as ecofriendly barrier materials due to the increased demand for sustainable packaging. They are easily processable by conventional plastics processing equipment and have been utilized for oil and grease barrier applications. While starches have excellent oxygen barrier properties and decent water barrier properties at low relative humidity (RH), they are moisture sensitive, as demonstrated by the deterioration of the barrier properties at higher RH values. Starch esters are chemically modified starches where the hydroxyl group of the starch has been substituted by other moieties such as acetates. This imparts hydrophobicity to starches and has been claimed as a good way of retaining water vapor barrier properties of starches, even at high RH conditions. We studied the water vapor barrier properties of one class of starch esters, i.e., high amylose starch acetates that were assumed to have good water vapor barrier properties. Our investigations found that with a high degree of substitution of hydroxyl groups, the modified starches did indeed show improvements in water vapor response as compared to pure high amylose starch films; however, the barrier properties were orders of magnitude lower than commercially used water vapor barriers like polyethylene. Even though these materials had improved water vapor barrier response, high amylose starch acetates are likely unsuitable as water vapor barriers by themselves, as implied by previous literature studies and patents.
Journal articles
Corrosion of Carbon Steel Tubes in the Mid-Furnance of Kraft Recovery Boilers--Environmental Characterization, TAPPI JOURNAL April 2009
Corrosion of Carbon Steel Tubes in the Mid-Furnance of Kraft Recovery Boilers--Environmental Characterization, TAPPI JOURNAL April 2009
Journal articles
Magazine articles
Rewet in wet pressing of paper, TAPPI JOURNAL September 2018
Rewet in wet pressing of paper, TAPPI JOURNAL September 2018
Journal articles
Magazine articles
Upscaling of foam forming technology for pilot scale, TAPPI JOURNAL August 2019
ABSTRACT: The need for production cost savings and changes in the global paper and board industry during recent years have been constants. Changes in the global paper and board industry during past years have increased the need for more cost-efficient processes and production technologies. It is known that in paper and board production, foam typically leads to problems in the process rather than improvements in production efficiency. Foam forming technology, where foam is used as a carrier phase and a flowing medium, exploits the properties of dispersive foam. In this study, the possibility of applying foam forming technology to paper applications was investigated using a pilot scale paper forming environment modified for foam forming from conventional water forming. According to the results, the shape of jet-to-wire ratios was the same in both forming methods, but in the case of foam forming, the achieved scale of jet-to-wire ratio and MD/CD-ratio were wider and not behaving sensitively to shear changes in the forming section as a water forming process would. This kind of behavior would be beneficial when upscaling foam technology to the production scale. The dryness results after the forming section indicated the improvement in dewatering, especially when foam density was at the lowest level (i.e., air content was at the highest level). In addition, the dryness results after the pressing section indicated a faster increase in the dryness level as a function of foam density, with all density levels compared to the corresponding water formed sheets. According to the study, the bonding level of water- and foam-laid structures were at the same level when the highest wet pressing value was applied. The results of the study show that the strength loss often associated with foam forming can be compensat-ed for successfully through wet pressing.
Journal articles
Dispersion of pulp slurries using carboxymethylcellulose, TAPPI JOURNAL, October 2000, Vol. 83(10)
Dispersion of pulp slurries using carboxymethylcellulose, TAPPI JOURNAL, October 2000, Vol. 83(10)
Journal articles
The laboratory twin-former part 1: design and performance, TAPPI JOURNAL, October 2000, Vol. 83(10)
The laboratory twin-former part 1: design and performance, TAPPI JOURNAL, October 2000, Vol. 83(10)