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Journal articles
Magazine articles
Open Access
Generlized stead-state model for chlorine dioxide brightning

Generlized stead-state model for chlorine dioxide brightning of hardwood kraft pulps, TAPPI JOURNAL May 2017

Journal articles
Magazine articles
Open Access
Impact of dissolved matter in the oxygen delignifcation stag

Impact of dissolved matter in the oxygen delignifcation stage, TAPPI JOURNAL May 2017

Journal articles
Magazine articles
Open Access
Guest Editorial: Paper and bioprocess engineering at SUNY-ES

Guest Editorial: Paper and bioprocess engineering at SUNY-ESF, TAPPI JOURNAL January 2012

Journal articles
Magazine articles
Open Access
Guest Editorial: J.Y. Zhu: Adapting and transforming the ind

Guest Editorial: J.Y. Zhu: Adapting and transforming the industry, TAPPI JOURNAL July 2012

Journal articles
Magazine articles
Open Access
Enzymatic treated viscose fibers functionalized by chitosan, TAPPI JOURNAL August 2018

Enzymatic treated viscose fibers functionalized by chitosan, TAPPI JOURNAL August 2018

Journal articles
Magazine articles
Open Access
Online measurement of bulk, tensile, brightness, and ovendry content of bleached chemithermomechanical pulp using visible and near infrared spectroscopy, TAPPI JOURNAL April 2018

Online measurement of bulk, tensile, brightness, and ovendry content of bleached chemithermomechanical pulp using visible and near infrared spectroscopy, TAPPI JOURNAL April 2018

Journal articles
Magazine articles
Open Access
On the nominal transverse shear strai to characterize the severity of creasing, TAPPI JOURNAL April 2018

On the nominal transverse shear strai to characterize the severity of creasing, TAPPI JOURNAL April 2018

Journal articles
Magazine articles
Open Access
Characterization of the redispersibility of cellulose nanocrystals by particle size analysis using dynamic light scattering, TAPPI Journal April 2019

ABSTRACT: Cellulose nanocrystals (CNCs), which are derived from the most abundant and inexhaustible natural polymer, cellulose, have received significant interest owing to their mechanical, optical, chemical, and rheological properties. In order to transport CNC products conveniently and efficiently, they are ideally dried and stored as pow-ders using freeze-drying or spray-drying technologies. The redispersibility of CNC powders is quite important for their end use; hence, a convenient method is required to characterize the redispersibility of CNC powders. In this paper, the possibility of characterizing the redispersibility of CNC powders by particle size analysis using dynamic light scattering (DLS) was investigated by comparing the results from transmission electron microscopy (TEM) and DLS. The particle size obtained with DLS approximately matched that obtained with TEM. Compared with TEM, DLS is a quick and convenient method to measure the particle size distribution of CNCs in water. Two kinds of dispersing methods, sonication and high-speed shearing, and two kinds of CNCs prepared by different methods, sulfuric acid hydrolysis and the TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) oxidization method, were used to study the redis-persibility of CNCs. Sonication was more efficient than the high-speed shearing method for nanoscale dispersion of CNC powders in water. CNCs prepared by sulfuric acid hydrolysis could be more easily redispersed in water than those prepared by TEMPO oxidation.

Journal articles
Magazine articles
Open Access
Kraft pulp bleaching with a P-stage catalyzed by both bicarbonate and TAED, TAPPI Journal July 2019

ABSTRACT: Peroxide bleaching of softwood and hardwood (eucalypt) kraft pulps was performed in solutions of sodium bicarbonate (NaHCO3), sodium carbonate (Na2CO3), and sodium hydroxide (NaOH). The conventional P stage (hydrogen peroxide + sodium hydroxide; H2O2 + NaOH) was the most effective brightening system without an additional activator. However, peroxide activation by bicarbonate anion (HCO3•) was obvious in all cases where NaHCO3 or Na2CO3 was used. When N,N,N’,N’-tetraacetylethylenediamine (TAED) was added to the bleaching sys-tem, Na2CO3 as the alkali source afforded equal or slightly higher bleached brightness compared to NaOH usage for both the softwood and hardwood pulps. This outcome is attributed to simultaneous peroxide activation by HCO3• and TAED. When applied to the eucalypt pulp, the H2O2/Na2CO3/TAED bleaching system also decreased the bright-ness loss due to thermal reversion.

Journal articles
Magazine articles
Open Access
Enhancement of processability, surface, and mechanical properties of paper based on rice straw pulp using biopolymers for packaging applications, TAPPI Journal July 2019

ABSTRACT: wo biopolymers, chitosan and oxidized starch, were used as wet-end additives to improve the strength properties of the paper because of their biodegradable and non-hazardous qualities. The present study reports the improvement in surface and strength properties of packaging-grade paper made with rice straw pulp using biopolymers, chitosan, oxidized starch, and surface sizing added at the wet end of the paper machine.Use of chitosan at all doses from 0.5 to 10 kg/ton enhanced important surface and strength properties of paper. The breaking length, tear index, burst index, ring crush strength, stretch, tensile energy absorption index, and Taber stiff-ness of the paper with 10 kg/ton of chitosan as a wet-end additive showed 22%, 14%, 20%, 59%, 16%, 44%, and 48% improvement, respectively, in comparison to control, (i.e, without its addition). The Cobb60 was also reduced by 45%, showing better resistance to water in comparison to rice straw paper alone. The effects of chitosan added at the wet end on the paper surface were investigated using Fourier transform infrared spectroscopy (FTIR). The use of 10 kg/ton of chitosan at the wet end reduced the color and total suspended solids in the back water of the papermak-ing system by 55% and 51%, respectively. Further enhancement in the surface and strength properties of paper was observed following surface sizing with oxidized starch.