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Journal articles
The influence of precoating layers on the performance of water-based barrier coatings, TAPPI Journal January 2025
Cellulose nanofibrils (CNF) on paper have been demonstrated to be an effective barrier against oxygen and grease and have been shown to improve the barrier performance of dispersion-based barrier coatings. The potential to produce paper grades that have good oxygen, grease, and moisture barrier properties is clear, but a better understanding of the synergies between CNF, other coating layers, and water-based barrier coatings (WBBC) is needed to optimize these systems. Different coat weights of a commercial WBBC were applied to papers that have a range of different qualities and thicknesses of CNF precoating layers. The same WBBC was also applied to pigmented coated paper, with various types of pigments and latex levels. Samples were characterized in terms of grease resistance, water vapor transmission rate (WVTR), and oxygen transmission rate (OTR) before and after folding. The results were contrasted to cases where the WBBC was applied to the paper with no precoating layer. When the WBBC is applied on a CNF layer or the pigmented coating layer, the performance of the WBBC for the water vapor barrier improves a significant amount compared to when the WBBC is applied to the base paper with no precoating layer. This improvement likely comes from these precoating layers filling in the large paper pores, which leads to the WBBC forming a continuous layer at low coat weights. Folding decreases the moisture barrier performance to some degree, but the grease resistance is not influenced by folding when a CNF precoating layer is involved. Oxygen barrier properties are moderate for the CNF layer alone and are less than 5 cm3/m2/day when WBBC is coated on the CNF layer. This result likely comes from the barrier coating’s ability to repair defects in the CNF layer to stop the easy passage of oxygen in defect regions of the sample.
Magazine articles
Leveraging mill-wide big data sets for process and qualityimprovement in paperboard production, TAPPI Journal December 2024
Authors: Jianzhong Fu and Peter W. Hart | TAPPI J. 15(5): 309(2016) - ABSTRACT: The MWV mill in Covington, VA, USA, experienced a long term trend of increasing episodes of paper indents that resulted in significant quantities of internal rejects and production downtime. When traditional troubleshooting techniques failed to resolve the problem, big data analysis techniques were employed to help deter-mine root causes of this negative and increasingly frequent situation. Nearly 6000 operating variables were selected for a deep dive, multi-year analysis after reviewing mill-wide process logs and 60000+ PI tags (data points) collected from one of the major data historian systems at the MWV Covington mill. Nine billion data points were collected from November 2011 to August 2014. Strategies and methods were developed to format, clean, classify, and sort the various data sets to compensate for process lag time and to align timestamps, as well as to rank potential causes or indicators. GE Intelligent Platforms software was employed to develop decision trees for root cause analysis. Insights and possible correlations that were previously invisible or ignored were obtained across the mill, from pulp-ing, bleaching, and chemical recovery to the papermaking process. Several findings led the mill to revise selected process targets and to reconsider a step change in the drying process. These changes have exhibited significant impacts on the mill’s product quality, cost, and market performance. Mill-wide communications of the identified results helped transform the findings into executable actions. Several projects were initiated.
Journal articles
Magazine articles
Review of coating cracking and barrier integrity on paperboard substrates, TAPPI JournalDecember 2024
Authors: Joel C. Panek and Peter W. Hart | TAPPI J. 21(11): 589(2022) - ABSTRACT: Barrier packaging formats are major growth areas for the pulp and paper industry. It is technically challenging to maintain barrier properties during converting and end-use applications. Improved manufacturing capabilities and coating formulation knowledge will help maintain barrier integrity and enable growth of barrier products in challenging applications. These improvements will accelerate product development and commercialization, and allow faster response to product performance issues such as cracking. The literature on coating cracking provides knowledge mostly on the effects of coating formulations and to a lesser extent on substrate effects. Despite a large number of publications dedicated to coating failures, the approach to improve coating cracking remains empirical, and the transferability between studies and to real life applications has not been well established. Model development that successfully predicts commercial performance is in its infancy. However, some of these simplified models do a fairly good job predicting experimental data. The current work reviews the state of understanding as regards coating and barrier cracking and highlights the need for more research on cracking and barrier integrity.
Journal articles
Magazine articles
Application of ATR-IR measurements to predict the deinking efficiency of UV-cured inks, TAPPI Journal January 2022
ABSTRACT: In recent years, ultraviolet (UV)-curable ink has been developed and widely used in various printing applications. However, using UV-printed products (UV prints) in recovered paper recycling causes end-product dirt specks and quality issues. A new method was developed that can distinguish UV prints from other prints by means of attenuated total reflectance infrared (ATR-IR) spectroscopy. Application of this method could allow more efficient use of UV prints as raw materials for paper recycling.First, a mill trial was performed using UV prints alone as raw materials in a deinked pulp (DIP) process. Second, test prints were made with four types of UV inks: a conventional UV ink and three different highly-sensitive UV inks. Each print sample had four levels of four-color ink coverage patterns (100%, 75%, 50%, and 25%). Next, deinkability of all prints was evaluated by laboratory experiments. Finally, each print was measured using the ATR-IR method, and the relationship between the IR spectra and deinkability was investigated. Mill trial results showed that UV prints caused more than 20 times as many dirt specks as those printed with conventional oil-based ink. There were variations in recycling performance among UV prints taken from bales used for the mill trial. Lab tests clearly revealed that not all UV-printed products lead to dirt specks. In order to clarify the factors that affected deinkability of UV prints, the print samples were investigated by lab experiments. Key findings from lab experiments include: • The number of dirt specks larger than 250 µm in diameter increased as the ink coverage increased. • Higher ink coverage area showed stronger intensity of ATR-IR spectral bands associated with inks. These results indicate that deinkability of UV prints could be predicted by analysis of ATR-IR spectra. • Finally, the method was applied for assessment of recovered paper from commercial printing presses. It was confirmed that this method made it possible to distinguish easily deinkable UV prints from other UV prints. Based on these findings, we concluded that the ATR-IR method is applicable for inspection of incoming recovered paper.
Journal articles
Magazine articles
Determining operating variables that impact internal fiber bonding using Wedge statistical analysis
ABSTRACT: In this study, Wedge statistical analysis tools were used to collect, collate, clean up, plot, and analyze several years of operational data from a commercial paper machine. The z-direction tensile (ZDT) and Scott Bond tests were chosen as representative of fiber bond strength. After analyzing thousands of operational parameters, the ones with the most significant impact upon ZDT involved starch application method, starch penetration, and the amount of starch applied. Scott bond was found to be significantly impacted by formation and refining. Final calendering of the paper web has also shown an impact on internal fiber bonding.
Journal articles
Magazine articles
Control of malodorous gases emission from wet-end white water with hydrogen peroxide, TAPPI Journal October 2021
ABSTRACT: White water is highly recycled in the papermaking process so that its quality is easily deteriorated, thus producing lots of malodorous gases that are extremely harmful to human health and the environment. In this paper, the effect of hydrogen peroxide (H2O2) on the control of malodorous gases released from white water was investigated. The results showed that the released amount of total volatile organic compounds (TVOC) decreased gradually with the increase of H2O2 dosage. Specifically, the TVOC emission reached the minimum as the H2O2 dosage was 1.5 mmol/L, and meanwhile, the hydrogen sulfide (H2S) and ammonia (NH3) were almost completely removed. It was also found that pH had little effect on the release of TVOC as H2O2 was added, but it evidently affect-ed the release of H2S and NH3. When the pH value of the white water was changed to 4.0 or 9.0, the emission of TVOC decreased slightly, while both H2S and NH3 were completely removed in both cases. The ferrous ions (Fe2+) and the copper ions (Cu2+) were found to promote the generation of hydroxyl radicals (HO•) out of H2O2, enhancing its inhibition on the release of malodorous gases from white water. The Fe2+/H2O2 system and Cu2+/H2O2 system exhibited similar efficiency in inhibiting the TVOC releasing, whereas the Cu2+/H2O2 system showed better perfor-mance in removing H2S and NH3.
Journal articles
Magazine articles
Critical parameters for tall oil separation I: The importance of ration of fatty acids to rosin acids, TAPPI Journal September 2019
ABSTRACT: Tall oil is a valuable byproduct in chemical pulping of wood, and its fractions have a large spectrum of applications as chemical precursors, detergents, and fuel. High recovery of tall oil is important for the economic and environmental profile of chemical pulp mills. The purpose of this study was to investigate critical parameters of tall oil separation from black liquor. To investigate this in a controlled way, we developed a model test system using a “synthetic” black liquor (active cooking chemicals OH- and HS- ions), a complete process for soap skimming, and determination of recovered tall oil based on solvent extraction and colorimetric analysis, with good reproducibility. We used the developed system to study the effect of the ratio of fatty acids to rosin acids on tall oil separation. When high amounts of rosin acids were present, tall oil recovery was low, while high content of fatty acids above 60% significantly promoted tall oil separation. Therefore, manipulating the content of fatty acids in black liquor before the soap skimming step can significantly affect the tall oil solubility, and hence its separation. The findings open up chemical ways to improve the tall oil yield.
Journal articles
Magazine articles
A new technique for the measurement of show-through mottle of fine paper, TAPPI Journal September 2019
ABSTRACT: Mottling within print-through and show-through is caused by the variability of the local optical properties of the sheet. This mottling is visually disturbing and a mark of poor paper quality. The ability to predict print-through mottle of printed paper by measuring show-through mottle on the unprinted sheet would be a valuable asset for paper machine control.We examined the relationship between print-through mottle and show-through mottle. We worked with nine samples of 60 lb. uncoated fine paper (90 g/m2), from various North American paper companies, that were printed on an offset press, 400K (400% Black), on both sides. A show-through mottle instrumental determination technique was developed using an existing Fast Fourier Transform-based algorithm. The nine samples examined were ranked similarly by the visual evaluation of print-through mottle and by the instrumental determination of show-through mottle. We thus established that show-through on the unprinted sheet can be used as a reliable predictor of print-through, therefore saving time and money for papermakers. We also found a significant two-sidedness in show-through for some of the samples.
Journal articles
Magazine articles
Creasing severity and reverse-side cracking, TAPPI Journal April 2020
ABSTRACT: Crease cracking can be detrimental to the functionality and appearance of paperboard-based packaging. The effect of creasing severity on the degree of reverse-side crease cracking (bead-side of the crease) of paperboard was investigated. Samples were creased with a range of rule and channel geometries, and the cracking degree was quantified as the percent of cracked length relative to the total length of the crease. The cracking degree was typically below 5% at low crease penetration depths, but was exponentially higher beyond a critical penetration depth. A rule and channel combination with a wider clearance shifted the critical depth to larger values. The creasing severity parameter, termed the creasing draw, converged the cracking degree data from different rule and channel combinations to a single curve. The creasing draw was derived from the same analytical expres-sions as the transverse shear strain and quantifies the length of paper that is drawn into the channel during creasing. The critical draw is defined as the draw at which cracking becomes greater than 5%, which corresponds with the point at which cracking becomes exponential. The critical draw is a material/system parameter that defines the level below which cracking is minimal.
Journal articles
Editorial: Revisiting recycling forums past, TAPPI JOURNAL J
Editorial: Revisiting recycling forums past, TAPPI JOURNAL January 2016