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Journal articles
Magazine articles
Open Access
Research on flame-retardant paper prepared by the method of in-pulp addition of ammonium polyphosphate, TAPPI Journal May 2023

ABSTRACT: At present, the production of flame-retardant paper usually uses the impregnation method of phosphorus-nitrogen flame retardants in paper. There are few reports on the application of an in-pulp addition method. In this paper, the solubility of ammonium polyphosphate (APP) and its effect on flame-retardant paper were investigated for use in an in-pulp addition method. It was found that APP particles were square, with an average particle size of 21.88 µm. The particle size decreased significantly after immersion in water at 25°C for 24 h. Furthermore, most of the APPs were dissolved after immersion in water at 90°C for 0.5 h, and the residuals agglomerated and their shape turned into an amorphous form. The APP possessed strong electronegativity and could partially ionize in water. The solubility of APP was 0.18 g/100 mL water at 25°C and increased quickly when the temperature was higher than 30°C. Therefore, APP should be added to the pulp at temperatures below 30°C. The tensile strength of the paper initially increased with the addition of APP, and it reached the maximum value when the APP content was 10% and then gradually decreased. The limiting oxygen index (LOI) value of the paper was 28.7% when the added amount of APP was 30% and cationic polyacrylamide (CPAM) was 0.08%, reaching the flame-retardant level.

Magazine articles
Open Access
On management: effective scheduling: a key management tool, TAPPI JOURNAL, April 1998, Vol. 81(4)

On management: effective scheduling: a key management tool, TAPPI JOURNAL, April 1998, Vol. 81(4)

Magazine articles
Open Access
Vision of the future, TAPPI JOURNAL, November 1996, Vol. 79(11)

Vision of the future, TAPPI JOURNAL, November 1996, Vol. 79(11)

Magazine articles
Open Access
Cedar river paper co. celebrates success of no. 2 linerboard machine, TAPPI JOURNAL, November 1996, Vol. 79(11)

Cedar river paper co. celebrates success of no. 2 linerboard machine, TAPPI JOURNAL, November 1996, Vol. 79(11)

Magazine articles
Open Access
Corrosion and protection of kraft digesters, TAPPI JOURNAL, October 1996, Vol. 79(10)

Corrosion and protection of kraft digesters, TAPPI JOURNAL, October 1996, Vol. 79(10)

Journal articles
Magazine articles
Open Access
Dynamic compression characteristics of fiber-reinforced shoe press belts, TAPPI Journal April 2025

ABSTRACT: Shoe press belts contribute significantly to the overall dewatering performance in the press section of a paper machine. Within the shoe press nip, the press belt faces a dynamic and multidimensional load that mainly leads to a compression of the structure. As this will cause a loss in void volume, knowledge of the dynamic compression characteristics of shoe press belts is crucial for optimized dewatering. A novel method was developed to examine the dynamic compression characteristics of grooved polyurethane press belts. Therefore, an experimental setup allowing realistic boundary conditions to test specimens was placed in a servo-hydraulic testing machine. Press belt specimens with different matrix material formulations and groove patterns were tested under varying load rates equivalent to different paper machine operational speeds. The results showed an evident sensitivity of the dynamic compression stiffness to the operational speed of the paper machine. This behavior was seen to be more sensitive to changes in the matrix material formulation than to adaptions of the groove pattern. As a result, the compression of the press belt within a shoe press nip is not only influenced by the peak pressure within the shoe press nip but also depends on the operational speed of the paper machine.

Journal articles
Magazine articles
Open Access
Study on the effect of aluminum diethyl phosphinate in synergy with ammonium polyphosphate on the flame retardancy of cellulose paper, TAPPI Journal April 2025

ABSTRACT: This paper involved the synergistic incorporation of ammonium polyphosphate (APP) and diethyl aluminum phosphinate (AlPi) as flame-retardant fillers for producing flame-retardant paper. The research revealed that APPs were square particles with a smooth surface, and their solubility was 0.29 g/100 mL at 20°C, which increased to 4.12 g/100 mL at 60°C. The surfaces of AlPis were rough and irregular. The solubility of AlPi was 0.023 g/100 mL at 20°C, and the solubility remained stable when the temperature increased. The addition of AlPi had a minor influence on the pulp beating degree. The tensile strength of kraft/APP/AlPi decreased with the increase of the AlPi addition. For a paper with 20 wt% APP and 0 wt% AlPi, the limiting oxygen index (LOI) value was 27.2%, and it burned completely at the eighth second during vertical combustion. When the AlPi additive content increased to 20 wt%, its LOI value increased to 32.2%, and the vertical combustion self-extinguished as soon as the flame was removed. Scanning electron microscopy (SEM) showed that the char residue of the kraft/APP/AlPi had a more complete fiber network structure than that of kraft/APP. The Raman spectroscopy indicated that the area ratio of the D (amorphous phase; disordered graphite vibration) band to the G (crystal phase; graphite carbon vibration) band (ID/ IG) ratio of kraft/APP/AlPi was lower than that of kraft/APP, meaning that the graphitization degree of the char residue of kraft/APP/AlPi was higher than that of kraft/APP, which indicated the kraft/APP/AlPi had better flame retardancy.

Journal articles
Magazine articles
Open Access
Boiler retrofit improves efficiency and increases biomass firing rates, TAPPI Journal March 2021

ABSTRACT: Domtar’s fluff pulp mill in Plymouth, NC, USA, operates two biomass/hog fuel fired boilers (HFBs). For energy consolidation and reliability improvement, Domtar wanted to decommission the No. 1 HFB and refurbish/retrofit the No. 2 HFB. The No. 2 HFB was designed to burn pulverized coal and/or biomass on a traveling grate. The steaming capacity was 500,000 lb/h from coal and 400,000 lb/h from biomass. However, it had never sustained this design biomass steaming rate. As the sole power boiler, the No. 2 HFB would need to sustain 400,000 lb/h of biomass steam during peak loads. An extensive evaluation by a combustion and boiler technologies supplier was undertaken. The evaluation involved field testing, analysis, and computational fluid dynamics (CFD) modeling, and it identified several bottle-necks and deficiencies to achieving the No. 2 HFB’s biomass steam goal. These bottlenecks included an inadequate combustion system; insufficient heat capture; excessive combustion air temperature; inadequate sweetwater con-denser (SWC) capacity; and limited induced draft fan capacity.To address the identified deficiencies, various upgrades were engineered and implemented. These upgrades included modern pneumatic fuel distributors; a modern sidewall, interlaced overfire air (OFA) system; a new, larger economizer; modified feedwater piping to increase SWC capacity; replacement of the scrubber with a dry electrostatic precipitator; and upgraded boiler controls.With the deployment of these upgrades, the No. 2 HFB achieved the targeted biomass steaming rate of 400,000 lb/h, along with lowered stack gas and combustion air temperatures. All mandated emissions limit tests at 500,000 lb/h of steam with 400,000 lb/h of biomass steam were passed, and Domtar reports a 10% reduction in fuel firing rates, which represents significant fuel savings. In addition, the mill was able to decommission the No. 1 HFB, which has substantially lowered operating and maintenance costs.

Journal articles
Magazine articles
Open Access
The use of minerals in fiber-based packaging and pulp molding, TAPPI Journal January 2024

ABSTRACT: Minerals are widely used in the pulp and paper industry for aiding the processing, economics, and final quality of fiber-based products. Among these, calcium carbonate, talc, and kaolin are widely used as fillers, and these can have varying brightness, particle size distributions, and aspect ratios. For the molded fiber area, these minerals can raise the solids content of the pulp mixture and improve throughput and lower energy requirements for drying. Talc is also widely used as a process control agent, picking up pitch and stickies and improving productivity by lowering machine cleaning time.The replacement of single use plastic with fiber-based replacements is a global trend; however, it does come with some significant challenges, such as grease and moisture proofing. Previously, per- and polyfluoroalkyl substances (PFAS) have been used to provide functions such as water and grease repellency, but regulatory demands have seen its demise in the packaging industry. Therefore, water holdout is now generally achieved by addition of alkyl ketene dimer (AKD) sizing. Wax additives are being developed and tested as PFAS replacements for oil and grease resistance. Rather than strongly repelling lipids from the fiber surface, these PFAS alternatives restrict flow pathways and react with food oils to alter their flow characteristics to prevent penetration through the substrate. During studies incorporating both PFAS substitutes and minerals, no detrimental interactions were observed. This paper addresses the different needs of the molded fiber market by including mineral fillers in molded fiber articles and will be presented as a series of different case studies. In all studies, we show that the trends observed when mineral filler is added to molded fiber are broadly similar to those seen in conventional paper and paperboard applications. Mineral addition in all studies gave improvements in productivity and optical appearance. With its organophilic surface, hydrophobic talc had the additional advantage of pitch and sticky control, and although a small decrease in strength was always observed when filler was added, the final articles still retained sufficient strength for their particular application. This small strength reduction should be balanced against the productivity gains.

Journal articles
Magazine articles
Open Access
Alkyl ketene dimer (AKD) sized paper reversion due to oxidative photodegradation, TAPPI Journal January 2024

ABSTRACT: Alkyl ketene dimer (AKD) is a sizing agent used in papermaking to increase the resistance of paper-board towards water penetration. The acquired hydrophobic property of the paper can be reversed due to the instability of the sizing agent. It is broadly known that AKD size reversion is due to migration, poor orientation, masking, or hydrolysis of the sizing agent. Unfortunately, the environmental parameters that cause this chemical instability are not well understood. Thus, the conditions that initiate or catalyze AKD size reversion and the mechanisms of AKD size reversion under different environmental conditions need to be investigated. In this study, six different experimental setups were used to investigate how temperature, daylight, fluorescent light, oxygen, and ultraviolet (UV) light affect AKD size reversion. Cobb values and pyrolysis gas chromatography-mass spectrometry (py-GCMS) results show that AKD size reversion is due to the degradation of the chemical in the presence of light and oxygen; temperature variations were found to accelerate reversion in the presence of light and oxygen. The oxidative photodegradation mechanism of the sizing agent is explored, and a possible mechanism is proposed.