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Fundamental molecular characterization and comparison of the O, D0, and E stage effluents from hardwood pulp bleaching, TAPPI Journal 2019
ABSTRACT: The present study characterized effluents from the O, D0, and E stages using nuclear magnetic reso-nance (NMR) and gel permeation chromatography (GPC) techniques to better understand the chemical nature of the dissolved organics formed from the bleaching of a high-yield hardwood kraft pulp. Understanding the structures and molecular weight distribution of these organics is the first step in developing methods to mitigate these contam-inates in the discharged effluents. The results indicated that the molecular weight distribution (MWD) of the dis-solved organics from oxygen delignification effluent is broader than those from D0 and E stage effluents. In addition, the O stage filtrate contained considerable amounts of lignin and xylan fragments, which showed its efficiency in removing such materials. The effluent from the D0 stage contained a lower amount of high molecular weight frag-ments and a higher amount of low molecular weight fragments versus the O-stage filtrate. Aromatic structures were nearly absent in the D0 stage filtrate, but the degraded organic material, presumably from oxidized lignin, contained olefinic (C=C) and carbonyl (C=O) functional groups. Furthermore, higher molecular weight fragments were detected in the E-stage effluent, presumably due to the extensive solubilization and removal of the oxidized lignin generated from the D0 pulp.
Journal articles
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The sticky behavior of pulp and paper mill biosludge during drying, TAPPI Journal June 2019
ABSTRACT: Pulp and paper mill biosludge becomes sticky after being dried to a certain solids content. As bio-sludge becomes sticky, it agglomerates and adheres to the heat transfer surfaces of the dryer. This undesirable property can lower the dryer efficiency and cause the drying equipment to fail.A systematic study was conducted to examine the sticky behavior of biosludge. The stickiness was evaluated by measuring the adhesive force between a sludge cake and a stainless steel substrate, and the cohesive force between a sludge cake and a sludge substrate. The results show that: i) both adhesive and cohesive forces increase markedly as the solids content increases, reaching a maximum value at about 13% solids, and then decrease steadily at a high-er solids content; ii) cohesive force is stronger than adhesive force, implying that biosludge tends to agglomerate rather than adhere to smooth equipment surfaces; and iii) mixing wood fines or fly ash from a biomass boiler reduc-es the stickiness of the mixture. These findings may help mills improve the thermal efficiency of biosludge dryers and to turn biosludge into a more attractive fuel for burning in biomass boilers.
Journal articles
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Fabrication of cross-linked starch-based nanofibrous mat with optimized diameter, TAPPI JOURNAL June 2019
ABSTRACT: The design and synthesis of natural and synthetic polymer blends have received recent and wide attention. These new biomaterials exhibit progress in properties required in the field of medicine and healthcare. Herein, the aim of present study is to fabricate starch (ST)/polyacrylic acid (PAA) electrospun nanofibrous mat with a smooth and uniform morphology, lowest fiber diameter (below 100 nm) and the highest possible starch content. Starch itself is poor in process-ability, and its electrospinning could be quite a challenging process. To address this, we carried out the response surface methodology (RSM) technique for modelling the electrospinning process. In order to have ST/PAA nanofibers with the finest possible diameter, optimized processing parameters (applied volt-age, nozzle-collector distance and feed rate) obtained from RSM technique were applied. ST/PAA electrospun nano-fibers with an average diameter of 74±13 nm were successfully achieved via the electrospinning method for the first time. The structure, preparation and properties of the nanofibrous structure were discussed. Results indicated that drug loaded ST/PAA blend nanofibrous structure has a great potential to be used in controlled drug release systems.
Journal articles
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Large data set analysis to determine refiner plate total cost of ownership, TAPPI Journal June 2019
ABSTRACT: Efficient process data storage and its subsequent analysis are vital to the profitable operation of a paper mill. An evaluation of refiner plate performance was conducted for an integrated paper mill. Trials with two new plate patterns were compared with the incumbent pattern; the goal was to increase refiner plate life. Plate life increased with both new design patterns, and the mill selected one of the two new choices. However, addi-tional impacts to paper machine performance and mill maintenance costs were not considered in the selection deci-sion. A large data set analysis tool was used to identify unrealized savings of 1.5% with reduced fiber usage (basis weight) on the paper machine’s most prevalent grade. The large data analysis indicated that this unrealized benefit with the alternate plate design was not attainable with the chosen plate design.
Journal articles
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Editorial: TAPPI Journal 2018 Best Research Paper delves deeper into press section rewet to address drying efficiency, TAPPI Journal March 2019
ABSTRACT: TAPPI and the TAPPI Journal (TJ) Editorial Board would like to congratulate the authors of the 2018 TAPPI Journal Best Research Paper Award: J. David “Dave” McDonald and Richard J. “Dick” Kerekes. Their paper, “Rewet in wet pressing of pa-per,” appeared on p. 479 of the September 2018 issue. This research was recognized by the Editorial Board for its in-novation, creativity, scientific merit, and clear expression of ideas.
Journal articles
Magazine articles
A study of the softness of household tissues using a tissue softness analyzer and hand-felt panels, TAPPI Journal March 2019
ABSTRACT: This study applied the reciprocal matrix approach to deduce the correlation between hand-felt (HF) and tissue softness analyzer (TSA) instrumental measurements of tissue softness. The research was conducted in three phases, which are discussed separately. In the phase one study, results indicated that systematic collection of samples and preparation of test specimens were the foundation of successful tests. TSA-HF and tensile strength exhibited a strong negative correlation. In the future, same-unit physical properties can provide a basis for discuss-ing the commonality and complementary natures of hand-felt and TSA softness measurements. In phase two, through the reciprocal matrix approach, subjective softness assessments performed by humans were reliably quan-tified. The quantified values were further applied to a statistical analysis using the t-test to distinguish and train pro-fessional panelists. In phase three of HF panel test results, all independent panels were compared to one another under a uniform scale established by four standard samples. The calibrated HF panel values were incorporated with TSA-HF results to establish technical curves between the softness and tensile strength, which were helpful for onsite workers to carry out process controls.
Journal articles
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Automation Update: What Does the Future Hold?, Paper360º March/April 2019
Automation Update: What Does the Future Hold?, Paper360º March/April 2019
Journal articles
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North America’s First Tree-Free Pulp Mill, Paper360º March/April 2019
North America’s First Tree-Free Pulp Mill, Paper360º March/April 2019
Journal articles
Magazine articles
World BioEconomy Forum: Major Opportunities for the Pulp and Paper Industries, Paper360º March/April 2019
World BioEconomy Forum: Major Opportunities for the Pulp and Paper Industries, Paper360º March/April 2019
Journal articles
Magazine articles
Problems Solved: Tracking True for Success, Paper360º March/April 2019
Problems Solved: Tracking True for Success, Paper360º March/April 2019