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Lignin-based resins for kraft paper applications, TAPPI Journal November 2019
ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.
Journal articles
Magazine articles
7 Water Waste Reduction Strategies to Improve Pump Reliability/Black Liquor Processing, Paper360º November/December 2019
7 Water Waste Reduction Strategies to Improve Pump Reliability/Black Liquor Processing, Paper360º November/December 2019
Journal articles
Magazine articles
To Canfor, Pulp is Much More than a Commodity, Paper360º September/October 2019
To Canfor, Pulp is Much More than a Commodity, Paper360º September/October 2019
Journal articles
Magazine articles
TAPPI Journal Summaries, Paper360º January/February 2017
TAPPI Journal Summaries, Paper360º January/February 2017
Journal articles
Magazine articles
Riding the Rails, Paper360º, July/August 2017
Riding the Rails, Paper360º, July/August 2017
Journal articles
Magazine articles
Paper Chemistry: What’s New, What’s Next, Paper360º March/
Paper Chemistry: What’s New, What’s Next, Paper360º March/April 2017
Journal articles
Magazine articles
The PPI Top 100, Paper360º September/October 2017
The PPI Top 100, Paper360º September/October 2017
Journal articles
Magazine articles
TAPPI JOURNAL Summaries, Paper360º September/October 2017
TAPPI JOURNAL Summaries, Paper360º September/October 2017
Journal articles
Fundamental study on developing wood powder as an additive of paperboard, TAPPI JOURNAL November 2014
Fundamental study on developing wood powder as an additive of paperboard, TAPPI JOURNAL November 2014
Stora Enso Goes Mobile!: Efficiencies delivered to the operations at pulp and paper mills using mobile technology, PaperCon 2014
Stora Enso Goes Mobile!: Efficiencies delivered to the operations at pulp and paper mills using mobile technology, PaperCon 2014