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The Art of Wastewater: Industrial IoT for Environmental Strategies, Paper360º May/June 2024
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Making a Difference: Meet our 2024 Award Winners, Paper360º May/June 2024
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Highest Paper Quality Right from the Start, Paper360º May/June 2024
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Unlocking Profit Potential: How US Pulp Mills Can Capitalize on Carbon Capture, Paper360º May/June 2024
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Orifice geometry as a tool for evaluating extensional flow resistance of barrier coating colors, TAPPI Journal November 2024
ABSTRACT: Knowledge of extensional flow behavior of coating colors can be beneficial for improving runnability and eliminating defects in various coating processes. The current work evaluates the use of an orifice geometry attached to a commercial capillary viscometer as a tool to obtain extensional flow properties of barrier coating dispersions. By measuring the pressure drop across the orifice as a function of flow velocity, the method presents the flow resistance as Euler number at industrially relevant high deformation rates. The results agree with the earlier results obtained with a capillary entrance pressure loss technique. The type of polymer additive is shown to control the extensional flow resistance, with high molecular weight linear flexible polymers such as polyethylene oxide (PEO) and polyvinyl alcohol (PVOH) having highest impact. The orifice method offers advantages over other approaches, including the need for only a small sample amount, ease of measurement, and access to high deformation rates.
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Experimental investigations into fold cracking of double coated barrier dispersion coatings, TAPPI Journal November 2024
ABSTRACT: The trend for replacing single-use plastics with fiber-based barrier coated board packaging has prompted a significant amount of research. There are many proposed ways of providing suitable packaging for applications like food service. Among these are dispersion coated barriers on board, as well as laminated boards that can be produced using conventional polyethylene (PE) or new biodegradable plastics. Minerals have also been shown to be suitable additives to these coatings for improving barrier performance through surface chemistry and by increasing the tortuosity of the pathway through the barrier layer. They also improve the cost effectiveness of the layer by lowering the material cost and raising the solids content, and by improving hold out of the functional layers, leading to a reduction in the amount of barrier coating needed to meet a given performance requirement. Minerals can also aid in the barrier handling in terms of rheology and reduced “stickiness,” as well as blocking of the films. When incorporated as fillers into extruded films, improved adhesion of the film to the board has been reported. One of the remaining challenges is the potential for cracking at the fold during converting and the loss of barrier performance that this can lead to. In this work, we systematically looked at the impact of mineral type and level in a dispersion coating. We assessed the differences in performance resulting from different coating application methods for the precoat layer by looking at the cracking tendency and loss of barrier functionality after folding for both the precoat alone and the final double coated sheets. Barrier results include moisture vapor transmission rate (MVTR), viscous vegetable oil, and the fluid blue stain in industrial methylated spirits (IMS) and Cobb water absorption, both before and after folding.
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Editorial: Concentrated content: TAPPI Journal special issues create research visibility, TAPPI Journal September 2024
You may have noticed that TAPPI Journal often brings readers special focused issues from time to time. Over the years, these issues have covered a range of topics, including wet-end technology, recovery cycle, foam forming, coating, additives, biorefinery, nanotechnology, lignin, pulping, recycling, university research, and more.
Journal articles
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Control of continuous digester kappa number using generalized model predictive control, TAPPI Journal September 2024
ABSTRACT: Kappa number variability at the digester impacts pulp yield, physical strength properties, and lignin content for downstream delignification processing. Regulation of the digester kappa number is therefore of great importance to the pulp and paper industry. In this work, an industrial application of model-based predictive control (MPC), based on generalized prediction control, was developed for kappa number feedback control and applied to a dual vessel continuous digester located in Western Canada. The problem was complicated by the need to apply heat at multiple locations in the cook. In this study, the problem was reduced from a multiple to a single input system by identifying three potential single variable permutations for temperature adjustment. In the end, a coordinated approach to the heaters was adopted. The process was perturbed and modeled as a simple first order plus dead time model and implemented in generalized predictive control (GPC). The GPC was then configured to be equivalent to Dahlin’s controller, which reduced tuning parameterization to a single closed loop time constant. The controller was then tuned based on robustness towards a worst-case dead time mismatch of 50%. The control held the mean value of the kappa number close to the setpoint, and a 40% reduction in the kappa number’s standard deviation was achieved. Different kappa number trials were run, and the average fiberline yield for each period was evaluated. Trial results suggested yield gains of 0.3%•0.5% were possible for each 1 kappa number target increase.
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Effects of hydrodynamic shear during formation of paper sheets with the addition of nanofibrillated cellulose, cationic starch, and cationic retention aid, TAPPI Journal September 2024
ABSTRACT: Laboratory tests were conducted to evaluate effects of hydrodynamic shear levels on papermaking process variables and paper handsheet properties. The furnish was from 100% recycled copy paper, to which was added nanofibrillated cellulose (NFC) at the 5% level following its optional pretreatment with cationic starch. A cationic copolymer of acrylamide (cPAM) was used as the retention aid. Different levels of hydrodynamic shear were applied both after mixing the NFC with the cationic starch (pre-shearing) or after all the furnish components had been combined (final shearing). The presence or absence of pre-shearing was found to have little effect on the measured outcomes. By contrast, increasing final shear hurt filler retention and made the resulting paper more uniform. However, the final shear level did not have a significant effect on the tensile strength of the resulting handsheets. Medium-charge density cationic starch, used in pretreating the NFC, consistently gave greater strength in comparison to a high-charge cationic starch. The significance of these findings is that though the relatively high hydrodynamic shear levels associated with modern paper machines can have some beneficial effects, they do not necessarily overcome all challenges associated with wet-end addition of nanocellulose in combination with other additives.
Journal articles
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Flocculation of fiber suspensions studied by Rheo-OCT, TAPPI Journal September 2024
ABSTRACT: When dealing with papermaking fiber suspensions, particle flocculation takes place even before the paper web is formed. The particle flocculation depends on several aspects, including particle mass concentration (consistency), particle collisions, electrochemical interactions promoted by chemical additives, etc. Due to its importance, fiber suspension flocculation has been studied for a long time in papermaking, and several methods have been developed for this purpose. The traditional techniques include, for example, focused beam reflectance microscopy (FBRM) and high-speed video imaging (HSVI). Recently, a new optical method, optical coherence tomography (OCT), has emerged for flocculation analysis. The advantages of OCT are the possibility to study opaque suspensions, its micron-llevel resolution, and its high data acquisition speed. The OCT measurements can be combined with rheological (Rheo) measurements, allowing simultaneous measurement of both the time evolution of the floc size and the suspension viscosity. In this work, we used this approach, Rheo-OCT, to study the flocculation of suspensions of various papermaking furnishes. We analyzed the time evolution of the floc size and the fiber suspension viscosity when the studied papermaking suspensions were treated with highly refined furnish (HRF) — a furnish that contained a significant amount of micofibrillated cellulose (MFC)-type fibrils — and/or chemical additives. Such studies can lead to a better understanding of the impact of flocculation on the produced paper web in terms of qualities like formation, drainage potential, and strength behavior.