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Lignin-based resins for kraft paper applications, TAPPI Journal November 2019
ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.
Journal articles
Case Histories of Three Yankee Cracking Incidents Associated
Case Histories of Three Yankee Cracking Incidents Associated with Shell Edge Extensions, 1991 Engineering Conference Proceedings
Journal articles
Theoretical Drying Study of Single-Tier Versus Conventional
Theoretical Drying Study of Single-Tier Versus Conventional Two-Tiered Dryer Configurations, 1992 Engineering Conference Proceedings
Journal articles
Qualification of Welding Procedures for Duplex Stainless Ste
Qualification of Welding Procedures for Duplex Stainless Steels, 1999 Engineering Conference Proceedings
Journal articles
Steambox Comparator Experiments: Apparatus Validation and In
Steambox Comparator Experiments: Apparatus Validation and Investigation of Steambox Performance, 1999 Engineering Conference Proceedings
Journal articles
Magazine articles
Can carbon capture be a new revenue opportunity for the pulp and paper sector?, TAPPI Journal August 2021
ABSTRACT: Transition towards carbon neutrality will require application of negative carbon emission technologies (NETs). This creates a new opportunity for the industry in the near future. The pulp and paper industry already utilizes vast amounts of biomass and produces large amounts of biogenic carbon dioxide. The industry is well poised for the use of bioenergy with carbon capture and storage (BECCS), which is considered as one of the key NETs. If the captured carbon dioxide can be used to manufacture green fuels to replace fossil ones, then this will generate a huge additional market where pulp and paper mills are on the front line. The objective of this study is to evaluate future trends and policies affecting the pulp and paper industry and to describe how a carbon neutral or carbon negative pulp and paper production process can be viable. Such policies include, as examples, price of carbon dioxide allowances or support for green fuel production and BECCS implementation. It is known that profitability differs depending on mill type, performance, energy efficiency, or carbon dioxide intensity. The results give fresh understanding on the potential for investing in negative emission technologies. Carbon capture or green fuel production can be economical with an emission trade system, depending on electricity price, green fuel price, negative emission credit, and a mill’s emission profile. However, feasibility does not seem to evidently correlate with the performance, technical age, or the measured efficiency of the mill.
Journal articles
Use of enzymes for reduction in refining energy - laboratory
Use of enzymes for reduction in refining energy - laboratory studies, TAPPI JOURNAL, November 2006
Journal articles
Image analytical monitoring of paper quality - a feasibility
Image analytical monitoring of paper quality - a feasibility study, TAPPI JOURNAL, November 2006
Journal articles
Magazine articles
Editorial: 2018 TAPPI Journal features diverse content, TAPPI Journal November 2018
Editorial: 2018 TAPPI Journal features diverse content, TAPPI Journal November 2018
Journal articles
Magazine articles
Dielectric spectroscopic studies of biological material evolution and application to paper, TAPPI JOURNAL September 2018
Dielectric spectroscopic studies of biological material evolution and application to paper, TAPPI JOURNAL September 2018