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Modeling the influence of rheology on smooth rod coating systems, TAPPI Journal November 2022

ABSTRACT: Rod coating methods are of interest for the application of barrier coatings, especially at off-line facilities that may run at moderate speeds and narrow web widths. At lower line speeds and lower coating solids, it is difficult to achieve good coat weight control because of poor loading of the rod. While there is extensive literature available about blade and roll coating, there seems to be less reported on the rod loading of smooth rods to obtain various coat weights. Much of the work is around metering rods working on applicator rolls at high speeds that are associated with the metered size press, with a focus on ribbing instabilities. This work employs a simplified model, neglecting some complex features of rubber deformation and film split, to estimate the influence of the process parameters such as speed, rod diameter, viscosity, and rod loading on the coat weight obtained. As found in practice, at low speed and low viscosities, the coat weight-load curve is steep, leading to poor control of the coat weight and coat weight uniformity. If the viscosity is increased, the curve is modified, and control is possible with rod loading in a normal range. For shear thinning fluids described by the Carreau model, the power law index and other parameters need to be in the correct range to obtain the desired effect. Modeling predictions show a steeper dependence of coat weight with rod pressure when compared to pilot coater data. This may be caused by missing details in the mechanical loading of the rod related to tube pressure or from neglecting the impact of filter cake formation of the applied coating in the model.

Coatings for sustainable paper-based flexible packaging: Barrier properties and processability, TAPPI Journal November 2022

ABSTRACT: In this study, the use of waterborne barrier dispersions from trademarked BLUEWAVE Mechanical Dispersion Technology as thin coatings for paper-based flexible packaging was investigated. Prototypes were designed and examined for their performance in process, rheology, barrier, heat-seal/hot-tack, and coefficient of friction (CoF). Compositional details such as the type and amount of base resins and dispersants were found to significantly impact performances and were key to the development of new prototypes that deliver the performance profiles for implementation in paper-based flexible packaging applications.

Novel test method for measuring defects in barrier coatings, TAPPI Journal November 2022

ABSTRACT: In the last several years, activity to develop water-based barrier coatings (WBBCs) that meet challenging packaging performance requirements has increased dramatically. Cellulose-based packaging solutions can provide a more sustainable packaging option for replacing single-use plastic-based options like extrusion-based and laminated materials. An advantage of WBBCs is the opportunity to reduce the coating thickness applied, as long as the barrier requirements can be met. A challenge that must be overcome is the ability to maintain a defect and pin-hole-free coating layer after coating and drying to retain the barrier performance. Many formulation and coating parameters can affect the barrier coating layer quality; however, methods for detecting more subtle differences in these types of studies are not widely available. Work was carried out to develop a quantitative technique for detecting and measuring the quantity and size of defects in the barrier coating layer. A test method has been developed using a combination of dyed oil and image analysis to be able to characterize the imperfections in the coating surface. The use of dyed oil serves two purposes. First, it better simulates the types of materials, in this case, oils and grease, for which the barrier coating is expected to hold out. Second, it also provides contrast between the coating and failure points for testing. An image analysis technique is employed to characterize the number and size of the imperfections. For the former, it reduces the testing time required if a quality control or laboratory technician counts the dots. For the latter, it assists with judgment on the source of the root cause of the imperfection, such as base sheet defects, coating dispersion issues, or perhaps micro-blisters in the coating, as some examples.To show the benefit of this technique, several pilot coating studies were designed to see if the new technique could be utilized to detect differences in WBBC performance. Both process and chemical variables were evaluated. With refinement, it is believed this technique can be utilized in development work, as well as for a potential quality control technique for manufacturing of coated paper and paperboard products.

Common Mistakes in Root Cause Failure Analysis, Paper360º November/December 2022

The Mechanism of Bonding, TAPPI Journal September 2022

ABSTRACT: Three factors are involved in cellulose bonding--available area, contact, and hydrogen bonding.

Reliable Wet End Control in the Production Process, Paper360º September/October 2022

Fixing Just One Link Doesn’t Strengthen a Chain, Paper360º September/October 2022

Chromizing for near-drum corrosion protection, TAPPI JOURNAL, September 1999, Vol. 82(9)

Chromizing for near-drum corrosion protection, TAPPI JOURNAL, September 1999, Vol. 82(9)

On increasing wet-web strength with adhesive polymers, TAPPI JOURNAL February 2020

ABSTRACT: Fiber-fiber adhesion, called “bonding” in the old paper physics literature, is a critical component of the overall strength of dry paper. With freshly formed very wet pulp fiber webs, all evidence suggests there are no fiber-fiber crossings with significant adhesive joint strength. With water removal, a point will be reached where fiber-fiber adhesion starts to contribute to the overall wet-web strength.The literature reveals very few examples of polymers that increase fiber-fiber joint strength in freshly formed webs. Here, we summarize the literature and explain why it is so difficult to promote fiber-fiber wet adhesion with polymers. Nevertheless, ongoing research in areas as diverse as tissue engineering scaffolds and biomimetic adhesives gives clues to future developments. Advances in paper machine engineering have lessened the importance of wet-web strength. By contrast, a critical issue in many of the evolving nanocellulose technologies is the strength of objects first formed by aqueous processing, the green strength—the strength of wet bodies before drying. For exam-ple, 3-D printed nanocellulose objects and ultralow density cellulosic aerogels can be destroyed by capillary forces during drying. There is a need for adhesives that strengthen freshly formed, wet lignocellulosic joints.

Stiffness and strength properties of five paperboards and their moisture dependency, TAPPI Journal February 2020

ABSTRACT: Five commercial multiply folding boxboards made on the same paperboard machine have been analyzed. The paperboards were from the same product series but had different grammage (235, 255, 270, 315, 340 g/m2) and different bending stiffness. The paperboards are normally used to make packages, and because the bending stiffness and grammage varies, the performance of the packages will differ. Finite element simulations can be used to predict these differences, but for this to occur, the stiffness and strength properties need to be deter-mined. For efficient determination of the three-dimensional properties in the machine direction (MD), cross direction (CD), and Z direction (ZD), it is proposed that the paperboard should be characterized using in-plane tension, ZD-tension, shear strength profiles, and two-point bending. The proposed setups have been used to determine stiff-ness and strength properties at different relative humidity (20,% 50%, 70%, and 90% RH), and the mechanical proper-ties have been evaluated as a function of moisture ratio.There was a linear relation between mechanical properties and moisture ratio for each paperboard. When the data was normalized with respect to the standard climate (50% RH) and plotted as a function of moisture ratio, it was shown that the normalized mechanical properties for all paperboards coincided along one single line and could therefore be expressed as a linear function of moisture ratio and two constants.Consequently, it is possible to obtain the mechanical properties of a paperboard by knowing the structural properties for the preferred level of RH and the mechanical property for the standard climate (50% RH and 23°C).