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Magazine articles
Cross-flow separation characteristics and piloting of graphene oxide nanofiltration membrane sheets and tubes for kraft black liquor concentration, TAPPI Journal September 2023
ABSTRACT: Dewatering of weak black liquor (WBL) in the kraft cycle by evaporation is highly energy intensive. Membranes are an attractive alternative for energy-efficient dewatering, but existing commercial polymeric or ceramic membranes are either degraded in BL or have high capital costs. Our recent works have demonstrated the engineering of graphene oxide (GO) nanofiltration membranes, their stability and promising performance in BL conditions, and preliminary scale-up into sheets and tubes. Here, we describe in detail the separation characteristics of GO membrane sheets and tubes under real BL conditions and crossflow operation. Recycle-mode piloting of a GO tubular membrane showed average “production flux” of 16 L/m2/h (LMH) and high rejections of lignin (98.3%), total solids (66%), and total organic carbon (83%), with no signs of irreversible fouling identified. A corresponding GO sheet membrane produced an average flux of ~25 LMH and maintained high lignin rejection of ~97% during a slipstream pilot at a kraft mill site using WBL with ~16 wt% total solids (TS). Finally, we piloted a Dow/DuPont XUS1808 polyamide composite reverse osmosis (RO) membrane for last-mile processing of the GO nanofiltration membrane permeate. The RO membrane showed a steady state flux of 19 LMH at 65 bar and produced ~0.02 wt% TS water product, which is highly suitable for reuse in pulp washing operations in the kraft process. The results have strong positive implications for the industrial application of GO membranes in BL concentration and other related applications.
Journal articles
Magazine articles
Extensive function of green synthesized titania nanoparticles: Photodegradation of Congo red, TAPPI Journal September 2023
ABSTRACT: Several extensive research studies have explored the advantages of green templates in the synthesis of structure and morphology-controlled photocatalytic nanomaterials. This paper compares the abilities of zingiber rhizome extract (ZE) and tapioca starch extracts (TS) in modifying the surface and optical properties of titania nanoparticles (TNP) synthesized by solgel technique. The synthesized nanocatalysts were characterized using various physicochemical techniques. While zingiber (ginger) extract effectively promotes the formation of dual anatase and rutile phases, tapioca extract supports formation of the single anatase phase of titania. These two extracts were examined for the degradation of Congo red in the presence of sunlight. The photomineralization and recyclability of catalysts were evaluated through total organic content analysis. The easy recovery and reusability of zingiber and tapioca biomasses, along with good control over the growth of nanoparticles, enable them to be implicit novel green templates in the successful synthesis of photoactive mesoporous nanotitania.
Magazine articles
A financial analysis of north american pulp and paper companies, TAPPI JOURNAL, July 2000, Vol. 83(7)
A financial analysis of north american pulp and paper companies, TAPPI JOURNAL, July 2000, Vol. 83(7)
Magazine articles
Global multi-pigment savvy from imerys, TAPPI JOURNAL, June 2000, Vol. 83(6)
Global multi-pigment savvy from imerys, TAPPI JOURNAL, June 2000, Vol. 83(6)
Magazine articles
Vendor, supplier, or partner, TAPPI JOURNAL, June 2000, Vol. 83(6)
Vendor, supplier, or partner, TAPPI JOURNAL, June 2000, Vol. 83(6)
Magazine articles
Managing technology - a critical contribution to competitiveness, TAPPI JOURNAL, June 2000, Vol. 83(6)
Managing technology - a critical contribution to competitiveness, TAPPI JOURNAL, June 2000, Vol. 83(6)
Magazine articles
Bay state paper company: a mill that reinvented itself, TAPPI JOURNAL, March 2000, Vol. 83(3)
Bay state paper company: a mill that reinvented itself, TAPPI JOURNAL, March 2000, Vol. 83(3)
Magazine articles
Technology utilization in mills, TAPPI JOURNAL, March 2000, Vol. 83(3)
Technology utilization in mills, TAPPI JOURNAL, March 2000, Vol. 83(3)
Magazine articles
Mount st. helens - 20 years of recovery, TAPPI JOURNAL, May 2000, Vol. 83(5)
Mount st. helens - 20 years of recovery, TAPPI JOURNAL, May 2000, Vol. 83(5)
Magazine articles
Imagine more in coatings, TAPPI JOURNAL, May 2000, Vol. 83(5)
Imagine more in coatings, TAPPI JOURNAL, May 2000, Vol. 83(5)