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Tetraethyl orthosilicate-containing dispersion coating — water vapor and liquid water barrier properties, TAPPI Journal September 2021
ABSTRACT: An aqueous styrene-butadiene latex dispersion coating containing in-situ processed tetraethyl orthosilicate (TEOS) applied on paperboard demonstrated improved water barrier performance. Coatings containing TEOS equivalent to 0.8% silicon dioxide (SiO2; dry basis) exhibited water vapor performance of < 25 g/m2/day (23°C, 50% relative humidity [RH]) and liquid water barrier performance Cobb 1800 s of < 6 g/m2, when applied as a single-layer 18 g/m2 coating. Cobb 1800 s barrier performance was still good (< 11 g/m2) at coat weights of 7–10 g/m2. The use of filler materials such as kaolin improved the vapor barrier properties of the coating, but this was not critical to the liquid water barrier properties.
Journal articles
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Considerations in managing wastewater odor at pulp and paper operations, TAPPI Journal March 2022
ABSTRACT: Many pulp and paper mills are, at least periodically, faced with the release of odors that can migrate offsite and be considered a nuisance by nearby residents. At chemical pulp mills, perceptible odors associated with reduced sulfur compounds (RSCs) are common, many of which are highly perceptible owing to their low odor thresholds. As releases of RSCs and other odorous substances from production processes are progressively controlled, the proportional contribution from wastewater treatment systems to areal odors can increase. This review paper summarizes important fundamentals of odor generation, source identification, and control. Common odorous substances are identified, and mechanisms for their generation are summarized. Approaches for measuring odorous substances are detailed to enable more effective management, and various odor control strategies are discussed.
Journal articles
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Root cause analysis of cationic polymer additive efficiency decline in virgin and recycle containerboard mills, TAPPI Journal January 2020
ABSTRACT: It is well known that retention, drainage and strength polymers struggle to perform (if at all) in virgin containerboard mills. In-depth studies have been undertaken in this area for more than seven years, investigating the issue from all directions. A key finding of this work is that soluble lignin is detrimental to chemical efficiency. A strong correlation exists between decreased chemical efficiency and high soluble lignin. Both recycled systems and virgin systems have been studied, and this correlation holds true regardless of furnish. The primary area of concern is virgin container-board, because these mills tend to have the highest lignin levels. Some highly closed recycled mills can also build elevated lignin levels that can negatively affect chemical efficiency.
Journal articles
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Contrasting underlying mechanisms of different barrier coating types, TAPPI Journal January 2018
Contrasting underlying mechanisms of different barrier coating types, TAPPI Journal January 2018
Journal articles
Magazine articles
Numerical analysis of slot die coating of nanocellulosic materials, TAPPI Journal November 2020
ABSTRACT: Nanocellulosic coatings as a food packaging material are of commercial interest due to their nontoxic nature, renewability, and excellent barrier properties. Complex shear-thinning rheology poses challenges in designing and sizing equipment to pump, mix, and process the suspension and actual coating process. This study aims to determine the effectiveness of computational fluid dynamics (CFD) in predicting nanocellulosic suspension flow in light of existing rheological data. We employ and compare three distinct rheological models to characterize the rheology and flow of nanocellulose suspensions through a slot die coater, where the model parame-ters are established from existing slot rheometry measurements. A volume-of-fluid (VoF) based finite volume meth-od is employed to simulate the flow in a slot die operated in an unconventional metering mode. Results with the Casson model predict the presence of unyielded regions in the flow, which was not captured using the power law model. These stagnation regions will incur coatability issues stemming from flow intermittencies and lead to poten-tial defects in the coating layer, including fracture. The results suggest that a rheological model that includes yield stress should be considered while modeling such flows. A need for better rheological data to model nanocellulosic flows, especially at high consistencies and shear rates, is also highlighted.
Journal articles
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Development of converging-diverging multi-jet nozzles for molten smelt shattering in kraft recovery boilers, TAPPI Journal March 2021
ABSTRACT: The effective shattering of molten smelt is highly desired in recovery boiler systems. Ideally, shatter jet nozzle designs should: i) generate high shattering energy; ii) create a wide coverage; and iii) minimize steam consumption. This study proposes a novel converging-diverging multi-jet nozzle design to achieve these goals. A laboratory setup was established, and the nozzle performance was evaluated by generating jet pressure profiles from the measurement of a pitot tube array. The results show that the shatter jet strength is greater with a large throat diameter, high inlet pressure, and a short distance between the nozzle exit and impingement position. Increasing the number of orifices generates a wider jet coverage, and the distance between the orifices should be limited to avoid the formation of a low-pressure region between the orifices. The study also demonstrates that an optimized converging-diverging multi-jet nozzle significantly outperformed a conventional shatter jet nozzle by achieving higher energy and wider coverage while consuming less steam.
Journal articles
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Quantification of vegetable oil in recycled paper, TAPPI JOURNAL September 2020
ABSTRACT: Vegetable soybean oil is commonly used in cooking foods that are packaged in takeaway paper-board containers. Vegetable oil is hydrophobic, and in sufficiently high concentration, could interfere with interfiber bonding and result in paper strength loss. In order to quantify the effect of oil on the resulting paperboard strength, it is necessary to quantify the oil content in paper. A lab method was evaluated to determine the soybean oil content in paper. Handsheets were made with pulps previously treated with different proportions of vegetable oil. Pyrolysis gas chromatography-mass spectrometry (pyGCMS) was used to quantify the amount of oil left in the handsheets. The results revealed a strong correlation between the amount of oil applied to the initial pulp and the amount of oil left in the handsheets.In addition, the effect of vegetable oils on paper strength may be affected by the cooking process. Vegetable oil is known to degrade over time in the presence of oxygen, light, and temperature. The vegetable oil was put in an oven to imitate the oil lifecycle during a typical pizza cooking process. The cooked oil was then left at room temperature and not protected from air (oxygen) or from normal daylight. The heated, then cooled, oil was stored over a period of 13 weeks. During this time, samples of the aged oil were tested as part of a time-based degradation study of the cooked and cooled oil.
Journal articles
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Chemical addition to wet webs using foam application, TAPPI Journal January 2023
ABSTRACT: In papermaking, the conventional way to add chemicals to the web is to dose them into the fiber stock and form the paper afterwards. However, in many cases, adding chemicals directly to the stock is challenging. For example, strength aids tend to increase flocculation in the stock, which limits the addition amounts of those aids. The need for better performance of paper (and paperboard) products has given rise to the need for functionalization of paper. Adding such functional chemicals to the stock is usually rather inefficient. Hence, novel methods are needed to add chemicals to the paper bulk. One such method is dosing chemicals to the wet web via foam application. In this study, we built a laboratory-scale sheetfed dynamic foam application device and utilized it to study addition of starch to wet bleached chemithermomechanical pulp (BCTMP) paper handsheets. The impact of parameters such as vacuum level, the amount of added chemical, and the viscosity of the foaming liquid on the penetration of starch into the wet web was explored. Starch penetration into wet webs was measured via iodine-potassium iodide staining, followed by image analysis. According to our results, controlling the viscosity of the foaming liquid gives the best possibility to control the penetration.
Journal articles
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Dielectric spectroscopic studies of biological material evolution and application to paper, TAPPI JOURNAL September 2018
Dielectric spectroscopic studies of biological material evolution and application to paper, TAPPI JOURNAL September 2018
Journal articles
Magazine articles
Discrete element method to predict coating failure mechanisms, TAPPI JOURNAL January 2018
Discrete element method to predict coating failure mechanisms, TAPPI JOURNAL January 2018